Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Renforcement structurel des granulats recyclés via une matrice époxy réticulée
Une étude récente met en lumière une stratégie avancée de valorisation des granulats de béton recyclés, visant à surmonter les limitations inhérentes à leur porosité élevée et à la friabilité de leurs interfaces. En imprégnant ces matériaux granulaires d’un système polymère thermodurcissable de type époxy, le procédé permet de générer un réseau réticulé tridimensionnel qui pénètre profondément les microfissures et scelle la surface des particules. Cette modification physico-chimique favorise une interaction intime entre les chaînes macromoléculaires du polymère et les hydrates de la matrice cimentaire, consolidant ainsi la zone de transition interfaciale (ITZ), traditionnellement considérée comme le maillon faible des composites cimentaires. L’analyse microscopique révèle une densification marquée de la microstructure et une réduction significative des défauts interstitiels, ce qui se traduit macroscopiquement par une augmentation notable de la résistance à la compression et à la traction, dépassant parfois celle des bétons à granulats naturels. Au-delà de la simple restauration des propriétés mécaniques, cette hybridation organo-minérale ouvre la voie à une ingénierie circulaire des matériaux de construction, rendant viable l’intégration massive de déchets inertes dans des structures porteuses durables.
Ingénierie de réseaux polyimines macrocycliques pour la séparation moléculaire en milieu hypersalin
Une nouvelle stratégie de synthèse macromoléculaire permet désormais de contourner le compromis historique entre perméabilité et sélectivité inhérent aux membranes de nanofiltration conventionnelles. En mobilisant des calixarènes tétra-fonctionnalisés comme briques élémentaires rigides, des chercheurs ont élaboré des nanofilms de polyimine via un procédé de polymérisation interfaciale assistée par diffusion unidirectionnelle sur un substrat hydrogel. Cette approche sophistiquée orchestre la cinétique réactionnelle de condensation de type base de Schiff, aboutissant à la formation d’une architecture réticulée lâche mais mécaniquement robuste, parsemée de cavités supramoléculaires interconnectées. La structure poreuse résultante, riche en sites actifs et dotée d’une topologie tridimensionnelle contorsionnée, favorise un transport hydrique rapide grâce à des canaux hydrophobes intrinsèques, tout en exerçant une discrimination stricte des solutés organiques par exclusion stérique et répulsion électrostatique, laissant transiter librement les ions inorganiques. Ce design innovant, qui s’affranchit des densités de réticulation excessive typiques des polyamides, ouvre des perspectives industrielles majeures pour le traitement des effluents complexes, notamment pour la récupération de ressources et la purification éco-efficiente des eaux usées à forte charge saline.
Ateliers Prospective 2026 : 17 Mars 2026
Polymères pour batteries Metal ion
Date :Réservez la date !
Les batteries métal-ion hautes performances sont de plus en plus présentes dans notre quotidien, la filière européenne doit répondre à des critères de qualité, de sécurité, de durabilité, de performance et de production efficace et compétitive. L’enjeu est de taille dans un contexte où un accroissement du marché de 252 à 431 Mds de dollars US est attendu entre 2025 et 2030, (véhicules électriques, intégration des énergies renouvelables, stockage).
Bien que représentant un pourcentage assez faible de la masse totale, les polymères y jouent un rôle déterminant, comme des liants polymères, les séparateurs entre les électrodes permettant le transport des ions. Peu d’équipes de polyméristes sont actuellement impliquées en France dans ce domaine, alors que les challenges sont importants et les compétences présentes. Participer à cet atelier est une opportunité pour améliorer ses connaissances et faire naître des idées neuves, objets de futures recherches, à l’interface entre un besoin bien identifié et des compétences.
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Résilience et circularité : le pivot stratégique de la plasturgie européenne
Une analyse sectorielle récente met en lumière la dichotomie frappante de l’industrie européenne des polymères qui, bien que fragilisée par une chute drastique de sa production et une perte de compétitivité historique face aux géants asiatiques et américains, accélère paradoxalement sa transition technologique vers une économie circulaire décarbonée. Pour endiguer cette érosion systémique, les industriels opèrent un pivot stratégique majeur en substituant progressivement les charges d’alimentation fossiles traditionnelles par des sources de carbone alternatives, qu’elles soient bio-sourcées, issues du captage de CO2 ou de matières recyclées. Au cœur de cette reconfiguration, l’innovation ne se limite plus à la synthèse de nouveaux matériaux, mais intègre désormais le déploiement de procédés de valorisation chimique sophistiqués – tels que la dépolymérisation avancée – permettant de traiter des gisements de déchets hétérogènes inaccessibles au recyclage mécanique conventionnel et de restituer des propriétés physico-chimiques strictement équivalentes au grade vierge. Parallèlement, cette quête de haute performance environnementale vise à minimiser l’empreinte carbone globale du cycle de vie des résines, transformant la contrainte réglementaire en levier d’innovation. En définitive, la pérennité de ce nouveau modèle industriel repose impérativement sur l’harmonisation des critères de fin de statut de déchet et la mise en place d’un cadre législatif technologique neutre, seuls garants d’une réindustrialisation durable capable de sécuriser l’autonomie stratégique de l’Europe dans la chaîne de valeur critique des matériaux avancés.
L’Usine Nouvelle Instabilité tribologique aux interfaces triphasiques : quand les microbulles érodent la matière
Une étude récente bouleverse les certitudes sur la stabilité chimique des contenants alimentaires en révélant un mécanisme d’érosion interfaciale insoupçonné, capable de générer des microplastiques sans apport énergétique externe. Ce phénomène repose sur la dynamique complexe de la ligne triple de contact entre la surface hydrophobe du polymère, le liquide et les microbulles de gaz naturellement présentes dans l’eau du robinet. Lors des phases de nucléation et de croissance sur les défauts de surface micrométriques, les bulles exercent des contraintes de cisaillement localisées intenses, induites par le déséquilibre des tensions superficielles. Cette sollicitation mécanique répétée entraîne un fluage progressif des chaînes macromoléculaires amorphes, qui s’accumulent sous forme de bourrelets circulaires périphériques avant de se fracturer sous l’effet de la fatigue. Contrairement aux modes de dégradation classiques par abrasion mécanique ou photo-oxydation UV, cette fragmentation « froide » produit des particules de morphologie annulaire spécifique, témoignant d’une extraction de matière pilotée par la physique des interfaces. Cette découverte majeure force l’industrie à repenser la topographie de surface des résines thermoplastiques pour limiter les sites de nucléation et préserver l’intégrité sanitaire des fluides, redéfinissant ainsi les cahiers des charges pour les grades polymères en contact alimentaire.
https://phys.org/news/2026-01-microbubbles-microplastics.html
Optimisation dynamique du recyclage par solvant via le couplage synergique de l’intelligence artificielle et de la thermodynamique des polymères
Un consortium de recherche a récemment initié un programme collaboratif d’envergure visant à lever les verrous technologiques du recyclage des flux de déchets plastiques complexes, tels que les emballages multicouches, en hybridant l’ingénierie des procédés par solvant avec des algorithmes d’apprentissage automatique avancés. Cette approche novatrice s’attaque à la limitation majeure des unités de recyclage conventionnelles, à savoir leur incapacité à gérer la variabilité intrinsèque de la charge d’alimentation, en déployant un « jumeau numérique » capable de modéliser en temps réel les interactions soluté-solvant et de prédire les paramètres de dissolution optimaux. Contrairement aux procédés statiques qui subissent les fluctuations de composition, ce système adaptatif reconfigure dynamiquement les conditions opératoires — incluant la température et la cinétique de mélange — pour garantir une sélectivité thermodynamique maximale et une extraction spécifique des chaînes macromoléculaires cibles. En intégrant ces boucles de rétroaction prédictives, le procédé assure non seulement un rendement significatif mais permet surtout de recouvrer des résines présentant une pureté et des propriétés physico-chimiques strictement comparables aux grades vierges, tout en rationalisant la consommation énergétique globale. Cette convergence entre la science des données et la chimie macromoléculaire ouvre la voie à une industrialisation flexible du recyclage tertiaire, transformant des gisements de déchets hétérogènes en matières premières circulaires de haute technicité. lire plus…
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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