Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Une avancée vers des capsules intelligentes : vers des vésicules Janus prévisibles et performantes
Des chimistes bordelais ont développé une méthode prédictive basée sur la théorie de Flory-Huggins pour concevoir des vésicules Janus, des nano-capsules à deux faces aux propriétés distinctes. En mélangeant deux copolymères amphiphiles ayant la même portion hydrophile mais des blocs hydrophobes incompatibles, ils ont réussi à induire un auto-assemblage compartimenté, conduisant à la formation de vésicules asymétriques avec un rendement supérieur à 90 %. L’approche permet même d’établir un diagramme de phase prévisionnel, contrôlant la morphologie des vésicules en fonction de la composition, de la taille des blocs hydrophobes et de la température. Ces capsules, hautement stables et homogènes grâce à un procédé d’extrusion, ouvrent des perspectives innovantes dans la nanomédecine (délivrance ciblée de médicaments, micro-robots auto-propulsés) et la conception de matériaux intelligents.
KIT crée le Carbon Cycle Lab pour accélérer le recyclage chimique des plastiques
Des chercheurs du Karlsruhe Institute of Technology (KIT) ont lancé le Carbon Cycle Lab (CCLab), une plateforme de recherche destinée à transformer les déchets plastiques, y compris ceux non recyclables actuellement, en matières premières chimiques pour une économie circulaire. S’appuyant sur les enseignements du projet bioliq®, qui a démontré la conversion de résidus biologiques en carburants, le CCLab étend désormais ces technologies à l’échelle pilote pour le recyclage chimique des plastiques. L’objectif est de fermer le cycle du carbone en synthétisant de nouveaux plastiques à partir de déchets, tout en éliminant ou en séparant les substances nocives. Selon le professeur Dieter Stapf, ce développement, soutenu par la Helmholtz Association et financé par le gouvernement allemand, vise à réduire la dépendance aux combustibles fossiles et à répondre aux exigences croissantes de recyclage imposées par l’Union européenne.
Comment mieux recycler le plastique : le défi de POLYREC
Créé en juillet 2024 au sein de la plateforme technologique PTICM de l’Institut Chevreul, le pôle POLYREC se consacre au développement de procédés innovants pour améliorer la qualité des plastiques recyclés et les réintroduire efficacement dans le cycle de production. Face à une production mondiale de plastique en forte croissance – où moins de 10 % des 460 millions de tonnes annuelles sont recyclées – POLYREC explore à la fois le recyclage mécanique et chimique.
Pour le recyclage mécanique, l’équipe étudie notamment la dépollution par CO₂ supercritique, un procédé qui, grâce à ses propriétés intermédiaires entre liquide et gaz, permet d’extraire les contaminants sans résidus de solvant, avec des taux de décontamination atteignant jusqu’à 98 % en continu. Dans le cas des matériaux thermodurcissables ou des élastomères, inadaptés au recyclage mécanique, POLYREC s’oriente vers la pyrolyse catalytique, qui dégrade les polymères en produits valorisables pour l’industrie chimique et énergétique.
Par ailleurs, l’équipe travaille sur l’optimisation de ces procédés en vue de réduire l’énergie nécessaire, en abaissant notamment les températures de pyrolyse par des approches d’intelligence artificielle, et en répondant aux exigences réglementaires pour les matériaux en contact alimentaire.
PEPPr : vers une conception de polymères HDPE plus durable grâce au machine learning
Des chercheurs de l’Université de Cornell ont développé un modèle de machine learning, baptisé PEPPr (PolyEthylene Property PRedictor), capable de prédire et d’optimiser les propriétés des polymères HDPE en se basant sur leur distribution de poids moléculaire. En entraînant le modèle sur une bibliothèque de plus de 150 échantillons de polyéthylène aux caractéristiques variées, l’équipe peut désormais estimer des paramètres cruciaux tels que la viscosité à l’état fondu, la résistance et la ténacité. PEPPr permet également, en mode inverse, d’identifier la composition d’un échantillon idéal pour atteindre des propriétés cibles spécifiques, ouvrant ainsi la voie à la conception de matériaux sur mesure pour des applications aussi diverses que la fabrication de sacs plastiques ou de kayaks. Cette approche innovante vise non seulement à réduire la quantité de matière nécessaire – et donc la consommation d’énergie – mais aussi à améliorer la qualité des matériaux recyclés, rendant le recyclage du HDPE plus compétitif face à la production de plastique vierge. Ce travail représente une avancée majeure vers une conception plus intelligente et durable des polymères, avec des retombées potentielles pour une économie circulaire dans le secteur des plastiques.
De la pollution à la polymérisation : une bactérie transforme le méthane en plastique biodégradable
Des chercheurs ont exploité la capacité de la bactérie Methylocystis suflitae, consommatrice de méthane, pour produire des polyhydroxyalcanoates (PHA), un plastique biodégradable, offrant ainsi une double solution aux enjeux climatiques et de durabilité. Grâce à une analyse génomique, ils ont identifié quatre gènes codant pour la PHA synthase, et des modélisations avancées ont démontré que les enzymes interagissent de manière optimale avec l’hydroxybutyrate et l’hydroxydodécanoate. En optimisant les conditions de fermentation, l’équipe a atteint un taux de production de 11,90 mg/L/h, malgré la faible solubilité du méthane, aboutissant à un plastique de qualité commerciale avec un point de fusion de 188 °C. Ce procédé novateur transforme le méthane, un puissant gaz à effet de serre, en matière première écologique, ouvrant la voie à une production industrielle scalable de bioplastiques qui pourrait contribuer significativement à la réduction de la pollution plastique.
Une méthode bio-sourcée pour des polyuréthanes sans produits chimiques toxiques
Des chercheurs de l’Université de Californie – San Diego ont développé une nouvelle voie synthétique permettant de produire des diisocyanates aromatiques entièrement issus de D-galactose, contournant ainsi l’utilisation de phosgène et d’autres réactifs toxiques. Ce procédé, qui ne nécessite ni métaux de transition ni conditions extrêmes, permet la fabrication de thermoplastiques polyuréthanes présentant des propriétés mécaniques équivalentes à celles des matériaux d’origine pétrolière. L’innovation ouvre la voie à la production de polyuréthanes 100 % renouvelables, offrant une alternative durable et sécurisée pour divers secteurs industriels.
https://phys.org/news/2025-03-bio-based-method-polyurethane-toxic.html
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.
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Les partenaires
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lrccp
http://www.ispa.asso.fr
cnrs
http://www.ispa.asso.fr
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
LPMC
http://www.ispa.asso.fr
hutchinson
http://www.hutchinson.com/fr
Logo-ChemSuD
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
arkema
http://www.coatex.com
ICS
https://www-ics.u-strasbg.fr/
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