Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Procédé lumineux pour une dépolymérisation intégrale des plastiques
Des chercheurs ont mis au point une méthode innovante qui permet de décomposer des plastiques résistants, comme le Plexiglass, en leurs monomères d’origine. En exposant ce type de plastique à une lumière violette dans un solvant à base de dichlorobenzène, des radicaux chlorés sont générés et initient le processus de dépolymérisation. Contrairement aux procédés mécaniques traditionnels qui altèrent la qualité du plastique recyclé, cette approche chimique permet de récupérer intégralement les monomères, ouvrant la voie à une réutilisation sans perte de performance.
Une bactérie thermophile révolutionne le recyclage du PET
Des chercheurs, menés par le Qingdao Institute of Bioenergy and Bioprocess Technology (CAS) en collaboration avec Nanjing Tech University et Greifswald University, ont mis au point une approche innovante de dépolymérisation du PET en utilisant une bactérie thermophile, Clostridium thermocellum, génétiquement modifiée. En intégrant directement l’enzyme LCC dans le chromosome de la bactérie et en optimisant les conditions de réaction – notamment par l’ajout de variantes enzymatiques, de modules hydrophobes et un contrôle précis du pH – ils ont atteint un taux de conversion impressionnant d’environ 97 % du PET prétraité en acide téréphtalique (TPA). Ce procédé, qui minimise l’accumulation de l’intermédiaire MHET, représente une solution écologique prometteuse pour transformer le PET en ses monomères de départ, facilitant ainsi une réutilisation de haute qualité et soutenant une économie circulaire. De plus, la capacité naturelle de C. thermocellum à dégrader la cellulose ouvre des perspectives pour traiter des déchets mixtes, notamment des textiles contenant du coton et du PET.
https://phys.org/news/2025-02-thermophilic-bacterium-high-conversion-plastic.html
FOIM : Un procédé de moussage thermique innovant pour une transformation sécurisée
Des chercheurs du Fraunhofer IAP ont mis au point une nouvelle technologie, baptisée FOIM, qui permet de transformer un film en polyuréthane à mémoire de forme en mousse, uniquement par l’application de chaleur, et ce, sans recourir aux isocyanates. En chauffant le film à 60 °C, celui-ci passe d’une épaisseur de 2,5 mm à une mousse de 40 mm d’épaisseur – soit une expansion multipliée par 16. Ce procédé isocyanate-free réduit considérablement les risques pour la santé en milieu industriel tout en optimisant la logistique grâce à un volume réduit lors du transport et du stockage des semi-produits. Par ailleurs, les propriétés du matériau, telles que la flexibilité, la transparence, la densité et la conductivité thermique, peuvent être ajustées pour répondre à divers besoins industriels, allant de l’automobile et la construction à l’emballage et aux applications médicales.
https://phys.org/news/2025-02-polyurethane-memory-foil-foam.html
Un cheminement orchestré vers l’origine de la vie
Dans une étude publiée dans Nature Chemistry, des chercheurs de l’Université hébraïque de Jérusalem et du Georgia Institute of Technology ont démontré que des mélanges chimiques complexes peuvent évoluer de manière prévisible sous l’influence de cycles humides-sèches, imitant les fluctuations environnementales de la Terre primitive. En soumettant des molécules organiques à ces cycles, l’équipe a observé que ces systèmes ne se stabilisent pas dans un état d’équilibre, mais continuent à s’organiser grâce à des voies sélectives qui limitent la complexité incontrôlée, tout en montrant une synchronisation des dynamiques de population entre différentes espèces moléculaires. Ces découvertes apportent de nouvelles perspectives sur la manière dont les conditions naturelles ont pu guider la formation des précurseurs de la vie, suggérant que l’évolution chimique prébiotique était moins chaotique qu’on ne le pensait et offrant ainsi des pistes innovantes pour la conception de systèmes moléculaires dans des domaines tels que la synthèse de matériaux et la biotechnologie.
Adhésif dégradable : une révolution pour le recyclage des emballages plastiques
Une équipe du Département de Chimie de l’Université de Reading a mis au point un nouvel adhésif polymère qui se décompose facilement lorsqu’il est traité avec des solutions basiques ou alcalines. Ce nouveau matériau, conçu pour coller fermement les étiquettes sur les bouteilles et autres emballages pendant leur utilisation, permet de retirer complètement les résidus d’adhésif lors du processus de recyclage. Publié dans Macromolecules (DOI: 10.1021/acs.macromol.4c02775), ce procédé innovant repose sur l’intégration d’unités sulfonyle éthyl uréthane dans une polyuréthane, agissant comme un interrupteur chimique déclenché par un environnement basique, réduisant jusqu’à 65 % la force d’adhérence. En facilitant l’élimination des étiquettes, cette technologie améliore la qualité des plastiques recyclés et pourrait transformer la gestion des déchets dans de nombreux secteurs industriels, allant des emballages alimentaires aux appareils électroniques.
https://phys.org/news/2025-02-plastic-bottles-easier-recycle-degradable.html
Polymère 2D à conduction métallique : une percée en électroplasturgie
Une équipe internationale, regroupant notamment des chercheurs de la TU Dresden et du Max Planck Institute, a synthétisé une forme ordonnée de polyaniline bidimensionnelle (2DPANI) qui présente des propriétés conductrices exceptionnelles. Ce matériau innovant offre une conductivité anisotrope de 16 S/cm dans le plan et de 7 S/cm en travers des couches, avec des mesures en courant continu atteignant jusqu’à 200 S/cm. Ces résultats témoignent d’un comportement de transport de charge typiquement métallique, notamment par conduction tridimensionnelle, et ouvrent ainsi de nouvelles perspectives pour le développement d’électroniques organiques, le blindage électromagnétique et la technologie des capteurs. Selon Thomas Heine, responsable de la chimie théorique à la TU Dresden, cette avancée représente une percée fondamentale dans la recherche sur les polymères conducteurs, en permettant de remplacer les métaux par des alternatives organiques performantes.
https://omnexus.specialchem.com/news/industry-news/polymer-with-metal-like-conductivity-000236333
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.
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Les partenaires
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arkema
http://www.coatex.com
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
LPMC
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http://www.waters.com
ICS
https://www-ics.u-strasbg.fr/
hutchinson
http://www.hutchinson.com/fr
cnrs
http://www.ispa.asso.fr
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http://www.ispa.asso.fr
Logo-ChemSuD
http://www.ispa.asso.fr
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