Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Un thermodurcissable recyclable innovant à base de dihydrofuran
Des chercheurs de l’Université Cornell ont mis au point une alternative recyclable aux plastiques thermodurcissables traditionnels, matériaux réputés pour leur résistance et leur durabilité mais dont la structure réticulée empêche leur réutilisation, ces derniers étant majoritairement incinérés ou mis en décharge. En se fondant sur le dihydrofuran (DHF), un monomère issu de ressources biologiques, l’équipe dirigée par Brett Fors a élaboré un procédé en deux étapes de polymérisation permettant d’obtenir un matériau croisé à la fois robuste et facilement décomposable, capable d’être chimiquement recyclé en ses composants initiaux ou de se dégrader naturellement en substances bénignes. Le nouveau matériau, dont les propriétés s’apparente à celles du polyuréthane haute densité et du caoutchouc éthylène-propylène utilisés dans des applications variées telles que les pneumatiques, les prothèses ou encore les équipements sportifs, ouvre ainsi la voie à une économie circulaire pour des produits historiquement non recyclables. En outre, les chercheurs envisagent d’étendre les potentialités de ce polymère à des domaines comme l’impression 3D, tout en expérimentant l’incorporation de monomères supplémentaires pour enrichir ses caractéristiques, illustrant ainsi une réorientation stratégique de la conception des polymères vers une approche intégrant durabilité et circularité dans un contexte de transition environnementale.
https://scitechdaily.com/cornell-researchers-create-first-of-its-kind-durable-and-recyclable-plastic/
Cristal 2DPANI à haute conductivité : avancées en transport de charge dans les polymères conducteurs
Une équipe internationale de chercheurs a synthétisé un cristal multilamellaire de polyaniline bidimensionnelle (2DPANI) doté d’un transport de charge métallique hors-plan, marquant une avancée significative dans le domaine des polymères conducteurs. Réalisé par une polymérisation 2D dirigée par topologie sur une monocouche de tensioactif anionique à la surface de l’eau, ce cristal présente une taille de domaine comprise entre 130 et 160 μm² et une épaisseur variant de quelques dizaines à plusieurs centaines de nanomètres. Sa structure se caractérise par des réseaux π colonnaires avec un espacement inter-couches de 3,59 Å et des réseaux rhomboédriques formés par des chaînes de polyaniline entrelacées, facilitant une forte conjugaison in-plane ainsi qu’un couplage électronique inter-couches, comme le confirment la spectroscopie de résonance paramagnétique électronique et des calculs de première approche. Le polymère affiche une conductivité de type Drude avec une conductivité en courant continu d’environ 200 S/cm, tout en révélant une anisotropie dans le transport de charge, l’in-plane atteignant environ 16 S/cm contre environ 7 S/cm hors-plan. Notablement, des dispositifs verticaux montrent une conductivité accrue à basse température, caractéristique d’un transport métallique hors-plan. Cette percée permet de contourner les obstacles traditionnels liés au transport de charge entre chaînes polymériques et ouvre de nouvelles perspectives pour la conception d’électrodes, le blindage électromagnétique ou encore le développement de capteurs. Publiée dans Nature, l’étude regroupe les travaux du NIMTE de l’Académie chinoise des sciences, de TU Dresden, du Max Planck Institute of Microstructure Physics et de CIC nanoGUNE BRTA, avec le soutien de la National Natural Science Foundation of China et de la Excellent Youth Foundation of Zhejiang Province.
Retour aux polymères fossiles : réorientation des politiques d’emballage
L’arrêté exécutif récemment annoncé par le président Trump constitue une réaction directe à la stratégie adoptée par l’administration Biden, laquelle envisageait de supprimer progressivement l’utilisation des plastiques à usage unique dans les opérations fédérales, en favorisant notamment le déploiement de pailles en papier. Dans ce contexte, le chef de l’État a exprimé sa volonté de mettre fin à cette transition en affirmant que les alternatives en papier étaient inefficaces, positionnant ainsi le plastique comme matériau de référence pour une large gamme d’applications industrielles. Cette décision, relayée sur les réseaux sociaux, trouve un écho favorable auprès de la Plastics Industry Association, dont le président et CEO souligne les avantages intrinsèques des polymères fossiles en termes de durabilité, de performance et de fiabilité, tout en insistant sur la compatibilité de ces matériaux avec les exigences d’un usage étendu. Par ailleurs, l’initiative de l’administration Biden, datant de juillet 2024 et visant à éliminer l’usage des plastiques dans les services de restauration et l’ensemble des opérations fédérales d’ici 2035, se heurte à des critiques nourries par une insatisfaction générale envers les pailles en papier, souvent décriées pour leur manque de robustesse et leur potentiel de contamination par des substances persistantes telles que les PFAS. Simultanément, l’émergence de solutions innovantes basées sur des polymères biodégradables issus de ressources renouvelables souligne les enjeux technologiques et industriels actuels pour concilier performance matérielle et impératifs environnementaux, bien que la viabilité de ces alternatives reste à démontrer pleinement dans un marché en mutation constante.
https://www.plasticstoday.com/legislation-regulations/back-to-plastic-says-trump
Innovation dans la séparation du CO₂ : partenariat Arkema et OOYOO
Arkema et OOYOO ont uni leurs expertises pour développer des membranes de séparation du CO₂ innovantes, destinées à réduire les émissions de gaz à effet de serre et à contribuer à la transition vers une économie carboneutre. Dans ce partenariat, Arkema met à profit son savoir-faire en synthèse polymère et en conception de matériaux de haute performance, notamment à travers ses élastomères Pebax® dotés d’une technologie de canaux moléculaires sur mesure qui assure une sélectivité élevée, une stabilité chimique et une résistance mécanique optimisée. Parallèlement, la start-up OOYOO exploite une technologie propriétaire de membranes, caractérisée par un encombrement réduit et une efficacité économique notable, pour concevoir des solutions permettant la séparation, la récupération et la valorisation du CO₂. Formulé par le biais d’un protocole d’accord, ce partenariat vise à accélérer l’amélioration des performances et la réduction des coûts de production des membranes, en intégrant également des résines complémentaires telles que le polyimide, le PEKK et le PVDF. L’objectif est de fournir des dispositifs modulables adaptés aux exigences industrielles de la capture du CO₂, lequel, une fois isolé et purifié, pourra être converti en divers produits chimiques industriels comme les carbonates, les engrais, la glace carbonique ou encore les carburants. Cette synergie technologique illustre l’importance stratégique de l’innovation polymère et des solutions de séparation des gaz dans un contexte de pressions réglementaires et environnementales croissantes, tout en répondant aux défis économiques liés à l’optimisation des procédés industriels dans un marché en pleine mutation.
Précurseur de nylon biodégradable par photosynthèse artificielle
Des chercheurs de l’Université métropolitaine d’Osaka, dirigés par le professeur Yutaka Amao, ont récemment mis au point une méthode innovante alliant photosynthèse artificielle et biocatalyse pour synthétiser un précurseur de nylon biodégradable, susceptible de remplacer les matériaux conventionnels issus des hydrocarbures fossiles. S’appuyant sur une approche antérieure basée sur l’utilisation de l’acide L-lactique pour la production de plastiques biodégradables de type polyester, l’équipe a exploité le potentiel de l’acide aminé L-alanine, dont la structure rappelle celle du lactique, pour générer des précurseurs de nylon à faible impact environnemental. La démarche repose sur un système photoréducteur intégrant un colorant et un catalyseur, auquel est associé le biocatalyseur L-alanine déshydrogénase, permettant d’associer l’ammoniac et le pyruvate afin de produire du L-alanine sous l’impulsion de l’énergie solaire. En outre, ce procédé novateur, qui exploite directement l’énergie solaire et s’inspire des mécanismes de la photosynthèse naturelle, pourrait réduire significativement l’empreinte carbone de la production du nylon tout en ouvrant de nouvelles perspectives industrielles. Les résultats, publiés dans Sustainable Energy & Fuels, démontrent le potentiel de cette technologie pour développer des matériaux polymériques biodégradables qui allient performance technique et respect de l’environnement, tout en posant les bases d’une transition vers des procédés de fabrication reposant sur des ressources renouvelables et durables.
Membrane de nanofiltration végétale : innovation durable sans matériaux fossiles ni solvants toxiques
Des ingénieurs chimistes de l’Université de Bath ont développé une membrane de nanofiltration entièrement basée sur des matériaux végétaux, éliminant ainsi l’usage de produits dérivés des combustibles fossiles et de solvants toxiques, en s’appuyant sur la cellulose et la lignine, deux ressources renouvelables. Conçue sous forme de membrane polyelectrolytique (PEM), cette technologie, détaillée dans ACS Sustainable Chemistry & Engineering, a démontré son efficacité à filtrer des colorants d’eau de divers poids moléculaires, simulant ainsi le comportement de filtres destinés à traiter une gamme variée de polluants dans les applications de purification et de traitement des eaux usées. Selon Dr Olawumi Sadare, cette avancée permet de répondre aux exigences environnementales et réglementaires européennes en limitant l’utilisation de solvants toxiques et de polymères fluorés, tout en offrant la possibilité de contrôler l’épaisseur de la membrane pour ajuster sa perméabilité et sa sélectivité. La membrane a également prouvé sa robustesse en maintenant d’excellentes performances après trente jours d’immersion, positionnant cette approche comme une alternative prometteuse aux membranes conventionnelles, dont la fabrication repose sur des solvants organiques nocifs et des matériaux non recyclables, contribuant ainsi à la réduction de l’empreinte carbone des procédés de séparation chimique, responsables de 10 à 15 % de la consommation énergétique mondiale. L’équipe de recherche, qui envisage par ailleurs la commercialisation de cette technologie et des applications futures dans l’élimination des PFAS, met ainsi en lumière une démarche intégrée de développement durable dans le domaine des membranes de filtration.
https://phys.org/news/2025-02-sustainable-based-membrane-fossil-fuel.html
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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ICS
https://www-ics.u-strasbg.fr/
Logo-ChemSuD
http://www.ispa.asso.fr
arkema
http://www.coatex.com
Waters_logo_stacked_K_web-NEW
http://www.waters.com
lrccp
http://www.ispa.asso.fr
LPMC
http://www.ispa.asso.fr
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
cnrs
http://www.ispa.asso.fr
hutchinson
http://www.hutchinson.com/fr
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