Le réseau

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L'organisation

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La structure de veille et de réflexion prospective

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Actualités

 

Des polyesters fluorés recyclables pour des plastiques plus performants

Des chercheurs de l’Université de Bayreuth ont mis au point une nouvelle classe de polyesters dégradables enrichis en fluor, capables d’allier performances mécaniques accrues et recyclabilité chimique. Grâce à l’intégration sélective d’atomes de fluor, ces plastiques présentent une polymérisation plus rapide, des chaînes plus longues et une meilleure robustesse. Mieux encore, le fluor incorporé peut être récupéré lors du recyclage, offrant un modèle circulaire innovant. Cette approche moléculaire fine, illustrant la puissance de la chimie de précision, permet d’adapter les propriétés des matériaux aux besoins industriels tout en répondant aux enjeux environnementaux.

https://phys.org/news/2025-10-recyclable-fluorine-properties-degradable-polyester.html

Percée pour des polymères auto-réparants ultrarésistants à la fatigue

Des chercheurs chinois ont mis au point un composite auto-réparant associant des feuillets bidimensionnels de MXène à une matrice de polyuréthane supramoléculaire, capable de concilier rigidité, résistance à la fatigue et réparabilité rapide — un triptyque rarement atteint dans les matériaux polymères. En reproduisant la structuration multi-échelle des tissus biologiques, le matériau intègre une phase dure continue nanométrique et un réseau tridimensionnel de MXène interconnecté obtenu par auto-assemblage via des liaisons hydrogène médiées par l’acide phytique. Cette organisation hiérarchique dissipe les contraintes sur plusieurs niveaux, limitant la propagation des fissures de fatigue tout en conférant un module d’Young élevé et une stabilité thermomécanique jusqu’à 70 °C. Les simulations de dynamique moléculaire montrent que la densité d’énergie cohésive élevée et la robustesse des liaisons supramoléculaires préservent l’intégrité du réseau sous sollicitations cycliques. Grâce aux propriétés photothermiques du MXène, la réparation des dommages peut être activée par irradiation infrarouge proche, rétablissant en une minute les performances mécaniques initiales. Cette conception multi-échelle dépasse les limites classiques du compromis entre élasticité et endurance, offrant un modèle général pour des polymères bio-inspirés à comportement adaptatif. Ces matériaux ouvrent des perspectives concrètes dans les domaines de la robotique souple, des prothèses biomécaniques et des structures composites intelligentes, où résistance mécanique, durabilité et réparabilité doivent désormais coexister.

Une enzyme ancestrale au service d’un éthylène biosourcé

Des chercheurs de l’Université d’État de l’Ohio ont franchi une étape cruciale vers une alternative durable à la production d’éthylène, une molécule-clé pour la fabrication de plastiques. Leur étude, publiée dans Nature Catalysis, révèle la structure et le fonctionnement d’une enzyme bactérienne, la methylthio-alkane réductase (MAR), capable de produire de l’éthylène à partir de composés soufrés organiques. Proche cousine des enzymes de type nitrogenase impliquées dans la fixation de l’azote, MAR se distingue par un complexe métal-soufre sophistiqué, mis en évidence grâce à la cryo-microscopie électronique. En dévoilant les mécanismes moléculaires de cette transformation biochimique, les chercheurs ouvrent la voie à une production d’éthylène non fossile, via ingénierie enzymatique, en exploitant la chimie du vivant pour construire les matériaux de demain.
https://www.eurekalert.org/news-releases/1103874

Une lumière sur l’invisible : des canaux à l’échelle angström créés par l’eau UV

Des chercheurs chinois ont mis au point une méthode ingénieuse pour sculpter des canaux minuscules — de l’ordre de l’angström — dans des membranes polymères, grâce à l’action combinée de l’eau et de la lumière ultraviolette. Ce processus, baptisé « UV-water » (UV-W), repose sur la génération de radicaux hydroxyles très réactifs capables de sectionner les chaînes polymères de l’intérieur, ouvrant ainsi des passages ultra-fins pour une séparation ionique d’une précision inédite. En ajustant le temps d’exposition UV, les chercheurs contrôlent la taille et la chimie de ces pores, capables de filtrer finement les ions selon leur charge, comme séparer le lithium du magnésium. Cette technologie pourrait transformer les procédés de dessalement, d’extraction de métaux critiques ou encore d’alimentation en énergie propre, en associant chimie radicalaire et ingénierie membranaire avec une finesse atomique.
https://www.eurekalert.org/news-releases/1103981

Une seule molécule, deux polarités : une avancée dans l’électronique organique

Des chercheurs sud-coréens ont réussi à transformer un polymère conducteur de type p en un matériau de type n, simplement en ajustant la concentration d’un dopant, l’or(III) chlorure. Cette découverte, publiée dans Advanced Materials, dévoile comment une simple modification chimique induit une réorganisation structurale de la chaîne polymère, modifiant ses propriétés électroniques. Grâce à cette percée, un seul polymère peut remplir les deux rôles essentiels dans une diode, simplifiant la fabrication des dispositifs électroniques souples comme les écrans étirables ou la peau électronique. Une avancée qui illustre l’importance de la chimie de précision pour concevoir l’électronique du futur.

https://www.eurekalert.org/news-releases/1104133

Polyuréthane hydrodispersible à cristallisation retardée : une voie verte vers des élastomères ultra-performants

Des chercheurs chinois ont mis au point un polyuréthane hydrodispersible (WPUE) dont les performances mécaniques rivalisent avec celles des polyuréthanes thermoplastiques classiques (TPUE), tout en étant synthétisé en milieu aqueux, sans solvants organiques volatils. Ce matériau, doté d’une ténacité record de 0,96 GJ/m³ et d’une résistance à la traction de 81,8 MPa, doit ses propriétés exceptionnelles à un mécanisme inédit baptisé « réponse de cristallisation retardée » (Delayed Crystallization Response, DCR). Conçu à partir de monomères symétriques favorisant une biphase dynamique et hiérarchisée, le WPUE reste amorphe lors des premières déformations : les domaines durs se fragmentent et se mêlent aux segments mous sans rupture. À partir d’un taux d’allongement élevé (λ ≈ 20), l’alignement coopératif des chaînes déclenche une co-cristallisation simultanée des deux phases, renforçant drastiquement la résistance et la dissipation d’énergie. Les liaisons hydrogène réversibles jouent un rôle central en absorbant les contraintes et en guidant l’auto-organisation structurale. Cette architecture confère au matériau transparence, élasticité extrême et stabilité thermique jusqu’à 250 °C. La stratégie DCR offre un nouveau paradigme pour les polymères auto-renforçants, conciliant durabilité, performance mécanique et compatibilité environnementale. En démontrant qu’un procédé à base d’eau peut surpasser les élastomères issus de solvants, cette étude ouvre la voie à une génération d’élastomères durables à haute valeur ajoutée pour les domaines de la protection, de la robotique souple et du design industriel responsable.

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Adhérez au GFP

Devenez un membre et découvrez les avantages d’un abonnement GFP.

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Sections locales GFP

Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.

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