Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Une seule encre, deux structures : l’impression 3D multi-phase qui réinvente les polymères
Une équipe de chercheurs a conçu une approche inédite de fabrication additive multi-matériaux où un seul mélange monomère permet de produire, selon la température et l’intensité lumineuse d’impression, des polymères amorphes ou semi-cristallins aux propriétés radicalement différentes. En jouant sur la phase liquide cristalline du monomère pendant la photopolymérisation, il devient possible de programmer la microstructure du matériau sans changer de formulation : à température modérée, la phase ordonnée se fige en un polymère rigide et opaque ; à température plus élevée, la phase isotrope donne un matériau souple et transparent. Ce contrôle fin de la cristallinité, pixel par pixel, ouvre la voie à des pièces où la mécanique, l’optique et la mémoire de forme peuvent être localement ajustées. Cette méthode supprime la nécessité de multiples résines ou de changements de cuve, simplifiant la fabrication de composites fonctionnels directement en impression 3D. Les applications envisagées vont des matériaux à mémoire thermique et systèmes de stockage d’information par changement d’opacité, jusqu’à la création de micro-dispositifs adaptatifs. En transformant un paramètre de procédé – la température – en outil de conception moléculaire, cette innovation démontre que l’impression 3D peut devenir un moyen de structurer la matière à l’échelle de la phase, ouvrant une nouvelle ère pour la fabrication polymère programmable.
Nature Un guide stratégique pour optimiser les centres de tri américains et renforcer l’économie circulaire
Le Center for the Circular Economy de Closed Loop Partners, en partenariat avec American Beverage, publie un guide de référence visant à améliorer l’efficacité des centres de tri des déchets recyclables aux États-Unis. Intitulé Materials Recovery Facilities: Effective Operation, Design and Management in Theory and in Practice, ce manuel synthétise les retours d’expérience d’exploitants, de fabricants d’équipements et d’experts afin d’aider les installations à accroître leurs taux de récupération, la qualité des matières triées et la résilience opérationnelle. Dans un contexte de transition vers la responsabilité élargie des producteurs, l’initiative cherche à uniformiser les bonnes pratiques et à soutenir la modernisation des infrastructures clés du recyclage. Le rapport met en avant des solutions concrètes issues d’essais sur site, comme l’intégration de technologies capables de trier films et plastiques flexibles, traditionnellement considérés comme des contaminants, permettant ainsi d’augmenter significativement les volumes valorisés. En favorisant la coopération entre industriels, collectivités et acteurs de la chaîne de valeur, ce document se positionne comme un outil de gouvernance technique et stratégique pour faire évoluer la filière vers une circularité réelle des matériaux. Cette démarche marque une étape importante pour l’industrie du recyclage américaine, qui cherche à conjuguer innovation, conformité réglementaire et rentabilité au service d’une économie plus résiliente et durable.
https://www.plasticstoday.com/packaging/a-guide-to-better-recycling-operations-in-the-us
Polymérisation 1,1 de l’acétylène : une avancée majeure dans la chimie des alcynes par carboboration cadmiée itérative
Cette étude présente une percée conceptuelle dans la chimie des polymères à base d’alcynes avec la mise au point d’une polymérisation 1,1 de l’acétylène réalisée par un processus itératif de 1,1-carboboration catalysé par le cadmium. Contrairement aux polymérisations 1,2 bien connues, cette approche exploite la réorganisation contrôlée du triple lien carbone–carbone pour construire un squelette de type dendralène, révélant une topologie tridimensionnelle et un système π croisé inédit. L’innovation repose sur la capacité du catalyseur cadmié à orchestrer la succession des étapes de carboboration sans favoriser la voie concurrente 1,2, grâce à un équilibre subtil entre acidité de Lewis et stabilité du lien C–B. Le procédé, utilisant l’acétylène gazeux comme équivalent de vinylidène, atteint une économie d’atome et d’étape remarquable tout en tolérant un large éventail de fonctions organiques. Les polymères obtenus se distinguent par leurs propriétés physiques atypiques, notamment leur instabilité thermique et leur caractère explosif à l’état solide, conséquence directe de leur conjugaison incomplète et de leur structure spiralée prédite par calculs quantiques. Cette avancée dépasse la simple prouesse synthétique : elle inaugure une voie entièrement nouvelle pour l’élaboration de polymères croisés dérivés d’alcynes simples, offrant des perspectives prometteuses pour la conception de matériaux fonctionnels hautement réactifs et potentiellement modulables, à condition que leur manipulation soit sécurisée par un contrôle rigoureux des conditions expérimentales.
Membranes anioniques sélectives de nouvelle génération obtenues par polymérisation interfaciale in situ
Des chercheurs ont mis au point une méthode de polymérisation interfaciale in situ (ISIP) pour fabriquer des membranes polymères sélectives aux anions monovalents (MAPM) capables de combiner flux élevé, sélectivité et stabilité, un défi majeur dans les technologies d’électrodialyse. Cette approche permet de créer, en une seule étape, une fine couche polyamide intégrée au polymère de base, contenant des groupes amines et carboxyliques agissant comme canaux ioniques et sites de régulation électrostatique. Le réseau partiellement réticulé obtenu favorise la conduction rapide des anions faiblement hydratés comme Cl⁻, Br⁻ et NO₃⁻, tout en repoussant les ions fortement hydratés tels que SO₄²⁻ et F⁻. Cette structuration moléculaire précise contrôle la dynamique d’hydratation et minimise la résistance ionique, assurant un transport sélectif tout en conservant une haute perméabilité. Les simulations moléculaires et les mesures électrocinétiques révèlent que la distribution des charges à la surface du polymère crée des chemins de migration préférentiels pour les ions monovalents, traduisant un équilibre inédit entre sélectivité, flux et durabilité. Les membranes ainsi produites offrent un fonctionnement stable, une sélectivité remarquable et une fabrication évolutive à faible coût, ouvrant la voie à une nouvelle génération de matériaux de séparation électrochimiques pour le traitement durable des eaux, la désalinisation et la récupération sélective d’ions dans les procédés industriels et énergétiques.
Nature L’intelligence artificielle, moteur incontournable de la compétitivité manufacturière
Lors du salon MD&M Midwest, Ryan Frederick, directeur de Transform Labs, a appelé les industriels à intégrer sans délai l’intelligence artificielle dans leurs stratégies opérationnelles, affirmant qu’elle constitue une évolution économique majeure comparable à celle d’Internet ou de la révolution mobile. Selon lui, l’IA n’est plus une option mais une nécessité macroéconomique, conditionnant la productivité future et la viabilité des modèles sociaux. Plutôt que d’attendre une maturité technologique hypothétique, il préconise des expérimentations progressives visant à automatiser les systèmes, processus et flux de production, afin de générer des gains d’efficacité tangibles. Cette approche d’« intelligent automation » transforme l’IA en levier structurel de performance industrielle plutôt qu’en simple outil d’assistance individuelle. Pour les ingénieurs, elle offre des capacités d’analyse et de conception augmentées, détectant faiblesses et incohérences à des stades précoces du développement produit. Frederick insiste sur l’urgence d’agir : les entreprises qui différeront leur adoption risquent d’être distancées par des concurrents plus agiles. Il en appelle à un leadership lucide et courageux, capable de dépasser les réticences face à l’automatisation pour faire de l’IA un pilier d’adaptation économique. Cette transition marque une étape décisive vers une industrie manufacturière fondée sur la réactivité, l’efficience et la durabilité compétitive.
Polymères polyoléfiniques pour sièges automobiles : vers une recyclabilité intégrale et des intérieurs durables
Lors du salon K 2025, Dow a présenté une avancée majeure pour la circularité automobile en introduisant des matériaux à base de polyoléfines destinés aux sièges, combinant performance mécanique, recyclabilité et allègement. Le premier développement, issu de la technologie Infinair 3D Loop, repose sur un élastomère polyoléfinique formé d’un réseau tridimensionnel de filaments fondus et solidifiés par refroidissement aqueux. Initialement conçue pour les matelas, cette structure confère aux coussins de siège une résilience durable et une perméabilité totale à l’air, tout en permettant un recyclage mécanique complet en fin de vie. En collaboration avec Lear, cette technologie commercialisée sous le nom FlexAir offre une alternative au polyuréthane conventionnel, réduisant significativement les émissions de CO₂, la masse des sièges et les composés organiques volatils. Le second matériau, Evoair POE Leather, propose une alternative synthétique au cuir à base de polyoléfine, plus légère, inodore, stable en couleur et résistante aux conditions climatiques, tout en éliminant l’usage d’origine animale. Utilisé notamment pour les housses et les protections d’airbags, ce matériau associe confort sensoriel et durabilité environnementale. Ensemble, ces innovations illustrent la capacité des polyoléfines à redéfinir les standards de durabilité dans l’industrie automobile en intégrant recyclabilité, performances techniques et exigences esthétiques dans une approche globale de conception circulaire.
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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arkema
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