Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Plasma atmosphérique pour l’activation des polymères fluorés et non fluorés : vers une adhésion optimisée et écologique
Des chercheurs ont comparé la modification de surface de deux polymères emblématiques — le polyéthylène (PE) et le polytétrafluoroéthylène (PTFE) — à l’aide d’un plasma d’air à barrière diélectrique de surface (SDBD), une technologie atmosphérique capable d’activer chimiquement les surfaces sans altérer le matériau en profondeur. Ce traitement génère des espèces réactives d’oxygène et d’azote qui greffent des groupes fonctionnels polaires tout en augmentant la rugosité microscopique des surfaces. Les analyses spectroscopiques et de mouillabilité révèlent que, si les deux polymères deviennent plus hydrophiles, le PTFE présente une activation bien plus marquée grâce à un mécanisme combinant défluoration partielle et oxydation, là où le PE subit surtout une simple oxydation de surface. Cette transformation chimique favorise la création de liaisons adhésives plus fortes et durables, confirmée par des tests mécaniques d’adhérence. L’approche SDBD offre ainsi une méthode propre, économique et sans solvants pour améliorer la compatibilité de matériaux difficiles à coller, tout en permettant un contrôle précis des propriétés de surface. Ces avancées ouvrent la voie à de nouvelles stratégies de fonctionnalisation des polymères fluorés dans les domaines des dispositifs biomédicaux, des composites haute performance et des revêtements techniques, tout en réduisant l’impact environnemental des traitements chimiques traditionnels.
Nature Hydrogels photo-redox : la lumière au service de l’oxydoréduction et du mouvement de la matière
Des chercheurs ont conçu un hydrogel polymère capable de traduire un signal lumineux en transformation chimique et mécanique, ouvrant une voie inédite vers des matériaux actifs à commande optique. Le cœur de cette innovation réside dans un interrupteur moléculaire bisthioxanthylidène intégré à la matrice, dont la conformation et le potentiel redox varient sous irradiation. Cette architecture permet à la lumière de contrôler avec une extrême précision les réactions d’oxydation locales, provoquant des changements réversibles de couleur, de fluorescence et de volume sans nécessiter de catalyseur externe. En modulant ces effets, il devient possible de générer des motifs, d’induire des courbures ou de texturer la surface du gel à la demande. L’ensemble fonctionne en milieu aqueux et conserve une stabilité remarquable, illustrant la convergence entre chimie de la lumière, ingénierie macromoléculaire et matériaux bio-inspirés. En associant la finesse du contrôle photochimique à la robustesse des processus redox, cette approche inaugure une nouvelle génération d’hydrogels « intelligents » capables de réagir, se modeler ou s’animer sous un simple faisceau lumineux.
Nature L’Oréal-UNESCO Pour les Femmes et la Science : 34 jeunes talents françaises récompensées
La Fondation L’Oréal et l’UNESCO ont dévoilé le palmarès 2025 du programme « Pour les Femmes et la Science – Jeunes Talents France », qui distingue 34 doctorantes et post-doctorantes issues de 64 universités et 62 nationalités. Sous la présidence de la professeure Françoise Combes, Présidente de l’Académie des sciences, le jury a salué l’excellence et la diversité d’une recherche portée par des femmes qui façonnent l’avenir scientifique. Le cru 2025 illustre une science durable et inclusive, où l’innovation technologique dialogue avec les enjeux sociétaux. Parmi les lauréates, Manon Pujol explore le recyclage enzymatique du polystyrène, Marion Négrier transforme les déchets textiles en matériaux biodégradables, Léa Chocron développe des solutions moléculaires pour stocker l’énergie solaire, et Bianca Marin Moreno mobilise l’intelligence artificielle pour la transition énergétique. D’autres avancent la recherche biomédicale, environnementale ou astrophysique, de la détection des ondes gravitationnelles à la compréhension du développement embryonnaire. En soutenant ces scientifiques à un moment clé de leur carrière, la Fondation L’Oréal affirme son engagement pour l’égalité des chances en science et pour une recherche « plus juste, représentative et durable ». Véritable vitrine du génie féminin français, cette promotion 2025 montre que l’excellence scientifique se conjugue résolument au féminin.
https://www.fondationloreal.com/s
L’intelligence artificielle au service des lubrifiants extrêmes
Des chercheurs iraniens ont développé un modèle d’apprentissage automatique capable de prédire avec une précision inédite la viscosité des huiles perfluoropolyéthers (PFPE), des lubrifiants utilisés dans les environnements extrêmes de l’aéronautique, de l’électronique ou du spatial. Ces polymères fluorés, prisés pour leur stabilité thermique et chimique, sont essentiels au bon fonctionnement d’équipements soumis à de fortes contraintes.
Plutôt que de recourir à des mesures expérimentales longues et coûteuses, l’équipe a entraîné quatre modèles d’intelligence artificielle à partir de données de température, densité et longueur moyenne de chaîne polymère. Le modèle de régression par processus gaussiens (GPR) s’est distingué avec une précision quasi parfaite (R² = 0,999), surpassant largement les corrélations empiriques classiques comme celles de Vogel-Fulcher-Tamman.
Au-delà de la performance prédictive, le modèle a su reproduire les lois physiques gouvernant le comportement des PFPE : une viscosité qui augmente avec la densité et diminue avec la température. En réduisant la dépendance aux essais expérimentaux, cette approche ouvre la voie à une conception plus rapide et plus durable de lubrifiants haute performance, indispensables aux technologies de pointe.
Nature Un bioplastique de bambou aussi résistant que le plastique pétrosourcé, mais biodégradable en 50 jours
Une équipe chinoise dirigée par Haipeng Yu et Dawei Zhao a mis au point un bioplastique issu du bambou combinant haute performance mécanique et biodégradabilité rapide, selon une étude publiée dans Nature Communications. Contrairement aux composites habituels à base de fibres de bambou dispersées dans une matrice polymère non dégradable, cette approche dissout la cellulose du bambou à l’échelle moléculaire grâce à un solvant alcoolique non toxique, puis la restructure en un réseau polymérique dense et orienté. Cette organisation confère au matériau une résistance à la traction de 110 MPa et une énergie de rupture de 80 kJ·m⁻³, supérieures à celles du polystyrène ou de l’acide polylactique, tout en conservant une bonne stabilité thermique et une grande aptitude au moulage. Surtout, le matériau se dégrade totalement dans le sol en moins de deux mois, ou peut être recyclé en boucle fermée sans perte notable de propriétés (90 % de la résistance initiale conservée). Ce procédé de « façonnage moléculaire » ouvre la voie à une nouvelle génération de bioplastiques biosourcés, durables et performants, susceptibles de remplacer les polymères pétrosourcés dans des applications structurelles ou techniques, marquant une avancée majeure vers une économie plastique réellement circulaire et biodégradable.
https://phys.org/news/2025-10-bamboo-based-plastic-biodegrade-quickly.html
Architectures polymères « slippery » imprimées en 3D pour manipulations liquides multifonctions
Les auteurs présentent une plateforme de fabrication numérique qui intègre, en une chaîne photo-induite, la création de matériaux multiphasiques et le greffage de brosses PDMS pour produire des interfaces solides–liquides stables au sein de micro- et macro-architectures polymères. Deux familles complémentaires sont combinées : (i) des réseaux acrylates nanoporeux issus de séparations de phase sous photopolymérisation, ensuite imprégnés d’un lubrifiant silicone et fonctionnalisés, qui offrent une faible fraction solide en contact et une bonne définition de motifs ; (ii) des organogels PDMS transparents et flexibles, obtenus par photo-réticulation de formulations contenant le lubrifiant, assurant une rétention durable et une compatibilité avec l’impression DLP. Cette approche unifiée permet la texturation numérique de la mouillabilité (motifs et gradients anisotropes), l’empreinte UV-NIL de microcavités pilotant l’évaporation et l’agrégation particulaire, et l’impression 3D monolithique de « SlipChips » où des canaux asymétriques guident des gouttes sans apport énergétique externe. Les surfaces obtenues conjuguent anti-adhérence (liquides, glace), anti-salissure, transparence et confinement capillaire localisé, tout en restant compatibles avec des procédés à grande échelle (roll-to-plate, DLP). Au-delà de l’état de l’art centré sur des géométries planes, cette synthèse matière-procédé élargit le champ des interfaces infusées—du codage de textures mouillantes aux microdispositifs biomédicaux—tout en pointant des axes d’optimisation (résolution verticale et intégrité mécanique des résines photocurables) pour la montée en complexité des architectures.
Nature Lorem ipsum dolor sit amet, consectetur adipiscing elit. Sed posuere tincidunt quam sit amet viverra. Nam in consequat nulla. Nunc rhoncus orci vitae arcu sagittis, in auctor nibh posuere. Donec ut nulla id enim tempor feugiat.
Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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cnrs
http://www.ispa.asso.fr
arkema
http://www.coatex.com
Logo-ChemSuD
http://www.ispa.asso.fr
hutchinson
http://www.hutchinson.com/fr
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
LPMC
http://www.ispa.asso.fr
ICS
https://www-ics.u-strasbg.fr/
lrccp
http://www.ispa.asso.fr
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