Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
PEPR Recyclage – Recyclage Plastique : Mécanique VS. Chimique
Dans le cadre du PEPR Recyclage, les lieux-totems ont pour objectif de créer des initiatives et des actions d’animation scientifiques, d’interactions avec les entreprises, les collectivités, les associations mais aussi de formation en collaboration avec les établissements accueillantes et leurs équipes pédagogiques.
l’Institut Charles Sadron ICS de Strasbourg vous invite à une conférence et table ronde où plusieurs experts et industriels partageront leurs savoirs et expériences sur le thème « recyclage plastique : mécanique vs. chimique ». lire plus…
EUPOC 2026: Important Update on Starting Date and Deadlines Remind
Dear Colleagues,
Gently reminding you of the upcoming EUPOC 2026 – Designing New Polymers by Combining High-Throughput and Artificial Intelligence Tools we would like to inform you of an important update regarding the start of the conference.
The new date is Monday, May 18, 2026, with registration starting at 2:00 PM, followed by the scientific program at 3:30 PM. The conference will end on Thursday, May 21, at lunchtime. lire plus…
Synergie des filières éthylène et chlore pour la décarbonation des matrices thermoplastiques
Une analyse sectorielle récente met en lumière la reconfiguration stratégique des voies de synthèse des polymères chlorés, dictée par l’impératif de décarbonation croisée des filières éthylène et chlore. Historiquement, l’élaboration de matrices telles que le polychlorure de vinyle repose sur une succession d’étapes hautement énergivores, associant le vapocraquage endothermique d’hydrocarbures à l’électrolyse halo-alcaline. Afin de pallier cette vulnérabilité environnementale, l’ingénierie macromoléculaire s’oriente vers l’électrification des réacteurs de craquage et l’intégration de précurseurs biosourcés. Or, la substitution des intrants fossiles par de l’éthylène d’origine renouvelable exige un contrôle rigoureux de la cinétique de polymérisation radicalaire pour garantir une architecture macromoléculaire exempte de défauts topologiques. Parallèlement, l’optimisation des cellules d’électrolyse à membrane modère la consommation électrique inhérente à la génération du chlore gazeux, indispensable à la fonctionnalisation covalente du squelette aliphatique. Cette halogénation confère au réseau amorphe une inertie chimique exceptionnelle et une résistance intrinsèque à la propagation de flamme. Toutefois, la pérennité de ces chaînes de valeur interconnectées se heurte à une forte inertie infrastructurelle, imposant une adaptation graduelle des procédés de mise en œuvre. À l’inverse des approches ségréguées, la synergie technologique de ces deux briques fondamentales permet de préserver la processabilité à l’état fondu et l’intégrité thermomécanique du matériau final. La maîtrise de ces nouveaux paradigmes de synthèse ouvre des débouchés industriels majeurs, offrant une voie de rupture pour pérenniser la fabrication de plastiques de grande diffusion tout en massifiant leur décarbonation structurelle.
Techniques de l’Ingénieur Synthèse du pentasilacyclopentadiénide et caractérisation de l’aromaticité des architectures siliciées
Des investigations récentes mettent en évidence la synthèse d’une architecture moléculaire historiquement jugée irréalisable, le pentasilacyclopentadiénide, un analogue entièrement silicié de l’anion cyclopentadiényle. Afin de contourner la propension intrinsèque du silicium à privilégier les liaisons covalentes simples au détriment des interactions pi, l’ingénierie chimique s’appuie sur l’intégration stratégique de substituants aryles périphériques extrêmement volumineux. Or, cet encombrement stérique majeur, intimement couplé à l’action coordinatrice et stabilisatrice d’un cation lithium, orchestre la formation d’un squelette pentagonal stable. Parallèlement, ce réseau homonucléaire déploie une délocalisation cyclique ininterrompue de ses électrons, satisfaisant rigoureusement aux critères fondamentaux de l’aromaticité. Bien que la topologie de l’édifice apparaisse macroscopiquement plane, l’investigation spectroscopique révèle un équilibre conformationnel ultrarapide entre de multiples isomères transitoires non plans. Cette dynamique structurale inédite bouscule la dichotomie classique entre résonance électronique et équilibre thermodynamique. À l’inverse des matrices carbonées traditionnelles, le caractère hautement métallique du silicium induit une rétention électronique atténuée, insufflant au composé une flexibilité et une réactivité physico-chimiques singulières. La maîtrise absolue de ce nouveau paradigme de liaison ouvre des débouchés industriels cruciaux pour la chimie de coordination. Cette rupture conceptuelle offre une plateforme robuste pour la conception de catalyseurs organométalliques d’avant-garde, promettant d’optimiser drastiquement la synthèse de polymères complexes et le développement de matériaux optoélectroniques aux performances étendues.
Formulation de films biocomposites biodégradables à base de caséinate de calcium et de nanoargiles pour l’emballage alimentaire
Des investigations récentes mettent en évidence l’élaboration d’une nouvelle architecture macromoléculaire hybride, spécifiquement conçue pour pallier la persistance environnementale des plastiques à usage unique. L’ingénierie de cette matrice repose sur la formulation d’un film biocomposite combinant du caséinate de calcium, un dérivé protéique lacté, avec un réseau d’amidon modifié. Or, la cohésion structurale de ce système biosourcé est drastiquement exaltée par la dispersion homogène de nanoparticules de bentonite. Parallèlement, l’intégration stratégique de glycérol et d’alcool polyvinylique module la plasticité du réseau, inhibant la rigidification prématurée pour conférer au produit fini une extensibilité et une résilience mécanique strictement analogues à celles des thermoplastiques conventionnels. À l’inverse des emballages polymériques pétrosourcés, ce nanocomposite démontre une susceptibilité hydrolytique et enzymatique exceptionnelle. En conditions d’enfouissement standard, la synergie entre l’humidité et l’activité de la microflore tellurique déclenche un clivage rapide des liaisons peptidiques et glycosidiques. Cette dynamique de dépolymérisation assure une minéralisation intégrale de la structure sur une très courte période. Toutefois, la structuration confinée par les feuillets de nanoargile préserve une fonctionnalité barrière optimale durant la phase d’usage. La maîtrise fine de ces interactions interfaciales entre protéines, polysaccharides et charges inorganiques ouvre des débouchés industriels cruciaux. Ce procédé de formulation offre ainsi une solution de rupture mature pour le conditionnement alimentaire durable, garantissant une circularité absolue de la matière sans générer de résidus microplastiques récalcitrants.
Électrosynthèse d’éthylène par électro-réduction de gaz de synthèse issu de déchets plastiques
Des chercheurs ont mis au point une architecture d’électrolyseur innovante permettant la conversion directe du gaz de synthèse, généré par la décomposition de résidus plastiques, en éthylène. Afin de contourner les limites thermodynamiques des procédés de vapocraquage traditionnels, cette cellule électrochimique sépare stériquement l’alimentation gazeuse : le monoxyde de carbone est acheminé et réduit à la cathode, tandis que l’apport en hydrogène s’opère à l’anode. Or, le cœur de ce dispositif repose sur l’intégration d’un ionomère spécifique, le polyacrylate de sodium, dont la topologie macromoléculaire orchestre un microenvironnement chimique optimal. Cette matrice polymère facilite le transport ionique et la cinétique réactionnelle sans exiger la présence d’une phase aqueuse liquide continue. Parallèlement, cette configuration interfaciale abaisse drastiquement la tension d’activation aux bornes de la cellule, conférant au système une efficacité énergétique nettement supérieure aux méthodes antérieures d’électro-réduction du dioxyde de carbone. L’atténuation des surtensions limite fondamentalement les réactions compétitives, exaltant ainsi la sélectivité vers la formation de l’oléfine cible. À l’inverse des filières pétrochimiques conventionnelles, cette dynamique réactionnelle déploie une résilience remarquable face à l’intermittence des flux électriques, s’hybridant parfaitement avec les sources d’énergie renouvelable. La maîtrise de cette conversion électrocatalytique ouvre des débouchés industriels cruciaux pour l’économie circulaire, offrant une stratégie de rupture pour boucler le cycle de vie des polymères de grande diffusion tout en décarbonant massivement la fabrication des futures matrices thermoplastiques.
https://scitechdaily.com/breakthrough-device-could-slash-ethylenes-massive-carbon-footprint/
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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cnrs
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ICS
https://www-ics.u-strasbg.fr/
lrccp
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http://www.waters.com
arkema
http://www.coatex.com
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LPMC
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http://www.hutchinson.com/fr
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