Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Les Webinaires Matériaux : En préparation du congrès « Matériaux 2026 »
Aurélie CAYLA (ENSAIT, GEMTEX)
Professeure en chimie des matériaux depuis 2020, sa carrière est consacrée à l’élaboration, à la formulation et à la compréhension de la mise en forme des polymères sous forme filamentaire, ainsi qu’à leurs caractérisations associées.
Ses recherches récentes portent sur l’élaboration de filaments à partir de ressources biosourcés et/ou biodégradables dans des procédés de plasturgie des thermoplastiques (extrusion/filage), mais également des procédés en voie solvant de polymères naturels (voie humide). Ses activités s’intègrent dans divers domaines d’applications qui entrainent une variabilité de propriétés à développer à l’échelle du filament (antibactérien, ignifuge, conducteur d’électricité…). lire plus…
Polymères PEG imprimables en 3D : une nouvelle architecture bottlebrush pour hydrogels et élastomères hautement extensibles
Des chercheurs ont développé une nouvelle génération de matériaux polymères imprimables en 3D à partir de réseaux de polyéthylène glycol dont l’architecture moléculaire a été entièrement repensée pour surmonter la rigidité intrinsèque des PEG réticulés de manière classique. Leur approche s’appuie sur la conception dite bottlebrush pliable, dans laquelle un squelette polymère central porte de nombreuses chaînes latérales flexibles capables de se replier et de se déployer, stockant ainsi une réserve de longueur interne qui confère au réseau une extensibilité exceptionnelle sans rupture de cohésion. En initiant la polymérisation par exposition brève aux UV, l’équipe obtient des hydrogels et élastomères sans solvant dont la micro-organisation reste contrôlable via la géométrie du champ lumineux, permettant de fabriquer des architectures complexes, souples ou rigides, tout en préservant une grande déformabilité. Cette stratégie permet au PEG, déjà largement utilisé en biomédecine, d’adopter des propriétés mécaniques compatibles avec des structures plus volumineuses ou fonctionnelles, notamment des échafaudages dynamiques pour organes artificiels ou des matrices de délivrance thérapeutique. De plus, la biocompatibilité constatée ouvre la voie à des interfaces intracorporelles stables, tandis que la combinaison possible du PEG avec d’autres motifs chimiques laisse entrevoir une large palette de formulations. L’étude met également en avant le potentiel de ces réseaux pour les électrolytes polymères solides, où la synergie entre conductivité et grande extensibilité représente un atout pour les dispositifs de stockage d’énergie de nouvelle génération.
https://www.eurekalert.org/news-releases/1106291
Polymère pour une administration sans aiguille de l’insuline
Une équipe de chercheurs de Zhejiang University a mis au point une nouvelle architecture polymère capable de franchir la barrière cutanée intacte et de transporter l’insuline dans la circulation systémique, ouvrant une voie inédite vers l’administration sans aiguille. Le polymère, désigné poly[2-(N‑oxide‑N,N‑dimethylamino)ethyl methacrylate] (OP), exploite une bascule de charge : à la surface de la peau, où le pH est légèrement acide, il se charge positivement et interagit électrostatiquement avec les lipides négativement chargés de la couche cornée, ce qui lui permet de s’insérer entre les lipides et d’amorcer sa traversée de la peau. En pénétrant plus profondément vers un environnement neutre, OP passe en état zwitterionique neutre global, réduisant ses interactions avec les matrices lipidiques et facilitant ainsi sa diffusion vers les couches sous-cutanées et la circulation sanguine. Lorsqu’il est lié à l’insuline, ce système a permis chez des animaux diabétiques un abaissement de la glycémie comparable à une injection tout en ne provoquant pas d’irritation cutanée ni de dommages structuraux après des applications répétées. Cette avancée promet non seulement d’améliorer la qualité de vie des patients en réduisant la dépendance aux injections, mais elle ouvre également la voie à l’administration transdermique d’autres biomolécules de poids moléculaire élevé — peptides, protéines thérapeutiques — tout en incitant à repenser les architectures polymères et les interfaces biomédicales pour l’intérieur du corps.
IA et surfaces de membranes poreuses pour une filtration par affinité chimique
Une équipe a développé un matériau de membrane ultrafiltrante novateur capable de trier des molécules de taille identique mais de nature chimique différente grâce à une architecture de pores fonctionnalisés. Le procédé repose sur l’auto-assemblage de micelles de copolymères à blocs chimiquement distincts, mélangés puis transformés en films poreux dont la surface interne présente des motifs chimiques variés selon les micelles utilisées. L’identification et l’optimisation de cette organisation complexe ont été rendues possibles par l’usage de techniques d’imagerie par microscopie électronique couplées à un algorithme d’apprentissage automatique, tandis que des simulations moléculaires ont permis d’éclairer les règles gouvernant l’auto-assemblage ; cette approche révèle comment la chimie des pores — et non seulement leur taille — peut être programmée. Du point de vue moléculaire, l’architecture repose sur la juxtaposition sélective de domaines fonctionnels dans les parois de pores, ce qui modifie l’affinité des molécules entrantes et permet de discriminer celles qui présentent des groupements de surface différents. Cette avancée ouvre des perspectives technologiques importantes : produire par des procédés industriels existants des membranes ultrafiltrantes capables de séparer selon l’affinité chimique, ce qui pourrait révolutionner des secteurs tels que la bio-pharmacie, le traitement de l’eau, voire les capteurs et revêtements intelligents.
https://phys.org/news/2025-11-machine-membranes-chemical-affinity.html
Conversion catalytique innovante du polyéthylène téréphtalate (PET) en composés valorisés
Une innovation récente révèle qu’une équipe a développé un procédé de recyclage chimique efficace du PET, en exploitant un système catalytique à base de chlorure de fer (III) associé à une amine et d’alcools comme agents de transestérification. Le procédé vise à couper sélectivement les liaisons ester caractéristiques du PET (bouteilles, déchets textiles), afin de produire des diesters de téréphtalate tels que le diméthyl téréphtalate, avec des rendements très élevés. Cette architecture catalytique abandonne l’usage d’acides ou de bases fortes, réduit la température d’opération et utilise un métal abondant, ce qui constitue une avancée sur les procédés classiques exigeant conditions sévères et matériaux coûteux. Le mécanisme s’appuie sur l’activation des esters intermédiaires par le fer et l’amine, suivie d’une substitution par l’alcool pour générer le diester, tandis que le matériau polymère initial est converti directement en matière première chimique de haut grade. L’intérêt technologique est double : d’une part, ce recyclage dit « chimique » permet une boucle circulaire des polyesters industriels, et d’autre part, il ouvre la voie à des filières ayant un potentiel industriel élevé en termes de valorisation de déchets plastiques. Cette méthode pourrait à terme réduire la dépendance aux ressources vierges et favoriser le développement de structures polymères régénérables à l’échelle industrielle.
https://phys.org/news/2025-11-pet-recycling-iron-catalyst-alcohols.html
40 ans d’innovation et de passion pour les polymères au LCPO
Depuis sa création en 1985, le LCPO a affirmé son positionnement à l’interface de la chimie macromoléculaire et des matériaux innovants, en mobilisant des architectures polymères conçues pour des applications allant de l’énergie aux matériaux pour le vivant. L’équipe du laboratoire explore des procédés de synthèse sobres et verts — incluant la chimie des polymères organiques, les formulations avancées et les caractérisations fines — pour générer des polymères ou copolymères dotés de propriétés fonctionnelles (conductivité, recyclabilité, biocompatibilité, dynamisme moléculaire). Sur le plan technologique, le LCPO a développé des partenariats industriels (notamment pour l’aéronautique ou les cosmétiques) et déposé plus de soixante brevets ces dernières années, ce qui témoigne de sa double orientation vers l’excellence académique et les usages applicatifs. Les architectures moléculaires conçues y sont souvent modifiées pour introduire des fonctions actives, des motifs réactifs ou des segments biosourcés, offrant ainsi des matériaux polymères « sur-mesure » dont les propriétés — mécanique, thermique, surface, recyclage — sont optimisées. Cette vision conduit à des solutions technologiques capables de répondre aux grands enjeux du XXIᵉ siècle : transition énergétique, économie circulaire, santé et bien-être, voire électronique souple. Ainsi, le LCPO incarne un laboratoire de recherche sur les polymères qui conjugue rigueur scientifique, stratégie d’innovation et mise en œuvre industrielle.
https://www.aquitaine.cnrs.fr/fr/cnrsinfo/40-ans-dinnovation-et-de-passion-pour-les-polymeres-au-lcpo
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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lrccp
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
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hutchinson
http://www.hutchinson.com/fr
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LPMC
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cnrs
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https://www-ics.u-strasbg.fr/
arkema
http://www.coatex.com
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