Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Ingénierie de nanocomposites hybrides ternaires PVA-ZnO-graphène pour la détection hygrométrique haute performance
Une étude récente met en lumière le potentiel d’une architecture macromoléculaire hybride associant l’alcool polyvinylique (PVA), l’oxyde de zinc et le graphène pour la conception de capteurs d’humidité destinés aux environnements critiques. Cette approche repose sur l’élaboration d’un nanocomposite ternaire via une mise en œuvre par voie solvant, assurant une dispersion homogène des charges inorganiques et carbonées au sein de la matrice polymère semi-cristalline. Les modélisations par la théorie de la fonctionnelle de la densité (DFT), corroborées par des caractérisations structurales fines, démontrent que l’incorporation synergique du graphène et de l’oxyde métallique induit une redistribution majeure des densités électroniques et une contraction significative de la bande interdite. Ce couplage physico-chimique exacerbe la polarisation de surface et multiplie les sites d’adsorption hydrophiles — notamment via les lacunes d’oxygène et les liaisons hydrogène intermoléculaires — facilitant ainsi la physisorption spontanée et le transfert de charge immédiat au contact des molécules d’eau. En résultante, ce matériau composite présente une stabilité thermodynamique supérieure, une conductivité électrique accrue et une réactivité de surface exceptionnelle, positionnant cette technologie comme une solution robuste pour le monitoring environnemental de précision dans le secteur aérospatial.
https://www.nature.com/articles/s41598-026-35026-2
Programme Ateliers Prospective 2026 : Polymères pour batteries Metal ion
Les batteries métal-ion hautes performances sont de plus en plus présentes dans notre quotidien, la filière européenne doit répondre à des critères de qualité, de sécurité, de durabilité, de performance et de production efficace et compétitive. L’enjeu est de taille dans un contexte où un accroissement du marché de 252 à 431 Mds de dollars US est attendu entre 2025 et 2030, (véhicules électriques, intégration des énergies renouvelables, stockage).
Bien que représentant un pourcentage assez faible de la masse totale, les polymères y jouent un rôle déterminant, comme des liants polymères, les séparateurs entre les électrodes permettant le transport des ions. Peu d’équipes de polyméristes sont actuellement impliquées en France dans ce domaine, alors que les challenges sont importants et les compétences présentes. Participer à cet atelier est une opportunité pour améliorer ses connaissances et faire naître des idées neuves, objets de futures recherches, à l’interface entre un besoin bien identifié et des compétences. lire plus…
Le « compleximer », plastique ionique remodelable comme le verre et tenace comme un polymère
Des chercheurs ont mis au jour une classe de matériaux polymères qui déjoue un principe empirique des solides vitreux, selon lequel une mise en forme aisée s’accompagne généralement d’une fragilisation. Le matériau, baptisé « compleximer », se travaille à chaud par déformation et remodelage à la manière du verre, tout en conservant une résistance aux chocs typique des plastiques, et il se prête en outre à une réparation simple par réactivation thermique. Cette combinaison provient d’une architecture supramoléculaire inhabituelle : au lieu d’être « verrouillées » par des liaisons covalentes de réticulation, les chaînes sont associées par des forces attractives à plus longue portée, issues de l’assemblage électrostatique entre segments porteurs de charges opposées, analogues à des micro-aimants. La comparaison avec d’autres systèmes chargés, notamment des familles proches des liquides ioniques, suggère l’existence d’un régime de relaxation et de vitrification distinct, où l’espacement interchaînes et le volume libre effectif deviennent des paramètres structurants ; une hypothèse avancée est que ces attractions moins contraintes laissent davantage d’espace entre chaînes qu’un réseau covalent classique, ce qui reconfigure la relation entre cinétique de relaxation et ténacité. Au-delà de l’enjeu fondamental, cette approche ouvre des débouchés industriels vers des pièces facilement formables, réparables et potentiellement plus durables, avec une marge de manœuvre pour développer des variantes biosourcées.
https://phys.org/news/2026-02-compleximer-plastic-glass-impact-resistance.html
Coût sociétal des PFAS et accélération de la substitution vers des grades sans fluorés persistants
Une étude récente met en lumière l’ampleur du fardeau sanitaire et environnemental associé aux substances per- et polyfluoroalkylées (PFAS), dont l’inertie et la persistance prolongée déplacent la charge financière vers l’ensemble de la collectivité. En s’appuyant sur des données actualisées et une méthodologie affinée, l’analyse propose une estimation volontairement prudente, car elle ne couvre qu’un nombre restreint de PFAS déjà encadrés parmi une famille beaucoup plus vaste ; l’impact réel est donc vraisemblablement sous-apprécié. Les coûts identifiés proviennent de trajectoires d’exposition menant à des pathologies, de la dépollution de sols et d’eaux contaminés, ainsi que de perturbations de services écosystémiques essentiels. Or, du fait d’une rémanence sur de longues durées dans l’organisme et l’environnement, l’inaction ancre ces dépenses dans le temps, tandis qu’une réduction des rejets à la source apparaît nettement plus efficiente que le seul traitement aval des eaux, jugé particulièrement onéreux. Le rapport souligne aussi la vulnérabilité spécifique des nouveau-nés, des enfants, des riverains de sites contaminés et des travailleurs exposés, et inscrit ces constats dans une trajectoire de durcissement progressif : interdictions ciblées (PFOS, PFOA, PFHxS), restriction de PFHxA dans divers produits de consommation, encadrement des mousses anti-incendie, surveillance des PFAS dans l’eau potable et évaluation d’une restriction plus générale. Cette lecture pousse l’industrie à accélérer la reformulation des revêtements et traitements de surface, et à sécuriser des alternatives « PFAS-free » sans compromis fonctionnel.
Modèles d’apprentissage pour anticiper les propriétés des plastiques et accélérer la mise au point des formulations
Des travaux récents mettent en lumière la montée en puissance d’une ingénierie des matériaux plastiques pilotée par les données, où l’apprentissage automatique est mobilisé pour relier composition et conditions de transformation aux propriétés d’usage, afin d’orienter plus tôt les choix de formulation. Le projet décrit vise le développement de modèles prédictifs capables d’anticiper des comportements mécaniques, thermiques ou physiques à partir d’informations issues des procédés, avec l’ambition de réduire la dépendance aux campagnes d’essais itératives et d’augmenter la robustesse des décisions en phase amont. Dans cette logique, des données industrielles de mise en œuvre — notamment issues d’opérations de moulage par injection de polypropylène pour des applications automobiles — alimentent l’entraînement et l’interprétation des modèles, tandis qu’un partenaire spécialisé en IA contribue à la transposition méthodologique vers des environnements de production. Parallèlement, l’accent est mis sur un outil conçu pour rendre ces approches accessibles sans compétences de programmation, ce qui abaisse le seuil d’adoption et favorise la traçabilité des choix matière/procédé ; à l’inverse d’une optimisation purement empirique, la démarche revendique une validation en conditions réelles. Au-delà du gain de temps et de matière, l’approche entend limiter les formulations inefficaces et l’usage d’additifs potentiellement dangereux, ouvrant une voie directement industrialisable vers des développements plus sobres, plus sûrs et plus compétitifs.
Polymères conjugués bidimensionnels DPP–vinylène à mobilité de charge élevée
Une étude récente met en lumière une stratégie de conception « donneur–accepteur » visant à lever le verrou du transport de charge dans les polymères conjugués bidimensionnels, souvent pénalisés par une conjugaison intraplanaire incomplète et des chemins de conduction trop désordonnés. Guidés par des calculs de structure électronique, les auteurs élaborent des réseaux 2D de type poly(arylene vinylène) où des motifs thiényle-benzodithiophène électrodonneurs alternent avec des unités diketopyrrolopyrrole fortement électroattractrices, reliées par des liaisons trans-vinylène choisies pour maximiser le recouvrement orbitalaire. La synthèse procède par polycondensation aldolique en phase solide, sous catalyse basique et sans solvant, ce qui favorise une croissance réticulée en feuillets cristallins ; des interactions faibles, notamment des liaisons hydrogène entre hydrogènes vinyliques et oxygènes carbonylés, verrouillent la planéité du squelette et stabilisent l’empilement. Les caractérisations structurales en diffraction des poudres et RMN du solide confirment l’architecture ordonnée, tandis que la spectroscopie térahertz révèle une diffusion des porteurs ralentie à l’échelle sub-picoseconde et une mobilité remarquable à température ambiante, cohérente avec un transport majoritairement intrafeuillet. Cette approche ouvre des perspectives concrètes pour des semiconducteurs organiques 2D robustes, adaptés aux dispositifs (opto)électroniques et à l’ingénierie de films fonctionnels à l’échelle industrielle.
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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arkema
http://www.coatex.com
hutchinson
http://www.hutchinson.com/fr
ICS
https://www-ics.u-strasbg.fr/
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
LPMC
http://www.ispa.asso.fr
lrccp
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
cnrs
http://www.ispa.asso.fr
Logo-ChemSuD
http://www.ispa.asso.fr
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