Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Nanocomposites PMMA/PANI dopés au WO₃ : vers des polymères à conductivité ionique et bande interdite modulables
Des chercheurs ont développé un composite polymère innovant combinant PMMA et polyaniline (PANI) dopés par du trioxyde de tungstène (WO₃). Ce système hybride montre une réduction significative de la bande interdite (3,80 → 3,18 eV) et une augmentation de la conductivité ionique de trois ordres de grandeur, tout en améliorant la stabilité thermique et la constante diélectrique. Les interactions polymère–nanoparticule, confirmées par XRD et FTIR, favorisent la mobilité des charges et la polarisation interfaciale. Ces matériaux multifonctionnels ouvrent la voie à des dispositifs optoélectroniques flexibles et des systèmes de stockage d’énergie à haute performance.
Nature Des catalyseurs confinés dans des MOF pour polymériser des cycles peu réactifs
Des chercheurs de Boston College et de l’Iowa State University ont développé une méthode bio-inspirée de polymérisation par métathèse en ouverture de cycle (ROMP) pour les cycloalcènes faiblement contraints comme le cyclooctène. En encapsulant des catalyseurs de type Grubbs dans des cages de réseaux métalliques-organique (MOF), ils ont empêché les réactions secondaires et obtenu des polymères ultra-hauts poids moléculaires à faible dispersité, présentant des propriétés mécaniques et adhésives renforcées ainsi qu’une dégradabilité contrôlée.
Nature Membranes polyamides ultrarapides pour solvants polaires et apolaires
Des chercheurs ont mis au point une stratégie simple pour fabriquer des membranes de nanofiltration organique (OSN) capables de séparer efficacement solvants polaires et non polaires. En utilisant un monomère diamine non planaire à motif diphényléther et en réalisant la polymérisation interfaciale à l’interface solvant eutectique profond/alcane, ils obtiennent une couche polyamide ultrafine (~12 nm) dotée d’une microporosité élevée, de nanopores uniformes et d’une microstructure de type Janus. Ces membranes affichent une perméabilité exceptionnelle (36,6 L m⁻² h⁻¹ bar⁻¹ pour le méthanol, 56,6 L m⁻² h⁻¹ bar⁻¹ pour l’hexane), une sélectivité moléculaire précise et une excellente stabilité structurale. Ce travail propose une approche de conception moléculaire et de contrôle de procédé qui établit une nouvelle référence pour les membranes OSN haute performance.
Nature Un hydrogel intelligent pour soulager durablement l’arthrose
Des chercheurs de l’Université de Cambridge ont mis au point un hydrogel capable de détecter les variations locales de pH associées aux poussées inflammatoires de l’arthrite et de libérer, en réponse, des anti-inflammatoires directement dans l’articulation. Ce matériau polymère, dont les liaisons réversibles confèrent des propriétés mécaniques proches de celles du cartilage, devient plus souple en milieu acide et déclenche alors la libération du principe actif encapsulé. En mimant le rôle mécanique du cartilage tout en assurant une délivrance ciblée et autonome des médicaments, ce système pourrait réduire les effets secondaires, améliorer l’efficacité thérapeutique et offrir un traitement continu aux patients souffrant d’arthrose. Publiés dans le Journal of the American Chemical Society, ces travaux ouvrent la voie à une nouvelle génération de biomatériaux réactifs pour le traitement des maladies chroniques, avec des perspectives allant au-delà de l’arthrite, notamment en cancérologie.
Les TPUs redéfinissent les matériaux pour dispositifs médicaux
Les polyuréthanes thermoplastiques (TPU) médicaux s’imposent comme des matériaux de choix pour concilier flexibilité, résistance mécanique et biocompatibilité dans des applications allant des cathéters aux dispositifs portables. Leur succès tient à l’équilibre entre souplesse et rigidité, à leur résistance aux agents chimiques et aux procédés de stérilisation, ainsi qu’à leur biostabilité face aux contraintes physiologiques. La sélection des formulations doit intégrer non seulement des critères mécaniques (dureté, allongement, fatigue) mais aussi la compatibilité avec les fluides corporels et la sécurité à long terme, conformément aux normes ISO 10993, USP Class VI et FDA. Des grades spécialisés apportent de nouvelles fonctionnalités comme la radiopacité, l’antimicrobien ou la réduction du coefficient de friction. Parallèlement, les acteurs du secteur – Lubrizol, Covestro, Avient, BASF – développent des TPUs biosourcés ou à empreinte carbone réduite, intégrant des approches IA pour optimiser extrusion et injection. Ces innovations ouvrent la voie à des dispositifs médicaux plus sûrs, plus durables et adaptés aux tendances émergentes telles que les capteurs portables, la médecine à domicile et les technologies mini-invasives.
https://www.plasticstoday.com/medical/tpus-revolutionize-medical-device-manufacturing
Des chimistes IA conçoivent des caoutchoucs plus résistants
Une équipe internationale a utilisé l’intelligence artificielle pour concevoir de nouveaux matériaux élastomères capables de mieux résister aux conditions extrêmes. L’IA a permis de prédire et d’optimiser les architectures moléculaires de polymères à base de caoutchouc, ouvrant la voie à des matériaux combinant flexibilité, résistance mécanique et durabilité. Ces caoutchoucs de nouvelle génération pourraient trouver des applications dans l’aéronautique, l’automobile et les dispositifs médicaux. L’approche démontre l’efficacité de l’IA dans l’ingénierie des polymères complexes, accélérant la mise au point de formulations performantes et durables.
https://phys.org/news/2025-09-ai-chemists-rubber-materials.html
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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LPMC
http://www.ispa.asso.fr
cnrs
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
arkema
http://www.coatex.com
hutchinson
http://www.hutchinson.com/fr
lrccp
http://www.ispa.asso.fr
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
ICS
https://www-ics.u-strasbg.fr/
Logo-ChemSuD
http://www.ispa.asso.fr
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