Le réseau

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L'organisation

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La structure de veille et de réflexion prospective

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Actualités

 

Chiralité supramoléculaire : un levier majeur pour doper les polymères conjugués

Des chercheurs montrent dans Nature Communications (25 sept. 2025) que la chiralité supramoléculaire acquise lors de l’assemblage en solution–film module fortement l’efficacité du dopage chimique des polymères conjugués. En pilotant finement les voies d’assemblage (phases nématiques twist-bend continues ou striées) par un simple choix de solvants, ils obtiennent des films allant d’achiraux à fortement chiraux ; après dopage séquentiel, les films les plus chiraux présentent la plus forte concentration de porteurs et la meilleure conductivité, effet reproductible sur plusieurs familles (PE2-biOE2OE3, DPP2T-TT, TPT). Les auteurs attribuent ce gain à une cristallinité accrue favorisant la délocalisation des charges et, potentiellement, à un effet CISS (chiral-induced spin selectivity) qui accélère les réactions redox d’oxydation. Ce travail relie pour la première fois la chiralité d’assemblage, la microstructure multi-échelle et l’efficacité de dopage, offrant une nouvelle poignée de conception pour l’électronique organique haute conductivité.

Nanocomposites CNT ultra-étirables pour l’impression 3D de capteurs flexibles

Une équipe coréenne a mis au point des nanocomposites polymère-nanotubes de carbone (CNT) capables de s’étirer jusqu’à 223 % tout en conservant une conductivité électrique de 1,6 × 10⁻³ S/m, performance inédite pour des matériaux optimisés spécifiquement pour la photopolymérisation en cuve (VPP). Dispersés dans une résine uréthane diacrylate, les CNT (0,9 % en masse) permettent une résolution d’impression de 0,6 mm et ouvrent la voie à la fabrication de structures complexes. Des capteurs piézorésistifs basés sur des surfaces minimales périodiques ont ainsi été intégrés dans une semelle connectée, capable de mesurer en temps réel la répartition des pressions plantaires. Ce développement marque un progrès décisif dans la compatibilité entre grande déformabilité mécanique et conduction électrique, conditions essentielles pour les dispositifs portables, l’électronique flexible et les textiles intelligents. Des travaux complémentaires en Europe confirment également l’intérêt de nanofillers comme le graphène oxyde pour surmonter les limites d’absorption UV en impression DLP, ouvrant de nouvelles perspectives pour l’intégration de matériaux conducteurs à haute résolution.

https://www.plasticstoday.com/medical/seoul-researchers-develop-highly-stretchable-cnt-nanocomposites-for-vpp-3d-printing

Un catalyseur MXene au ruthénium pour l’upcycling rapide des plastiques

Une équipe de l’Université du Delaware a mis au point un catalyseur innovant basé sur des MXenes mésoporeux supportant du ruthénium, capable d’accélérer l’hydrogénolyse des plastiques comme le polyéthylène basse densité. Les « piliers » de silice insérés entre les feuillets de MXene ouvrent des canaux facilitant l’accès du polymère fondu aux sites actifs. Résultat : une conversion deux fois plus rapide, sélective vers des carburants liquides, avec peu de méthane formé. Cette avancée démontre le potentiel des catalyseurs nanostructurés pour transformer les déchets plastiques en ressources énergétiques valorisables.
https://phys.org/news/2025-09-mxene-ruthenium-catalyst-upcycling-plastics.html

Polyuréthane éco-conçu à base de vanilline et auto-cicatrisant

Des chercheurs ont mis au point un nouveau polyuréthane en dispersion aqueuse intégrant un diol dérivé de la vanilline, porteur de liaisons imines dynamiques. Ce matériau bio-sourcé affiche une résistance mécanique triplée par rapport aux formulations standards (12,8 MPa contre 4,3 MPa), une auto-réparation complète des rayures en 30 minutes à 80 °C, une meilleure stabilité thermique et une absorption d’eau réduite. Ces films, qui adhèrent fortement aux substrats métalliques, ouvrent la voie à des revêtements protecteurs, adhésifs et élastomères plus durables et recyclables.

DIM MaTerRE : accélérer l’innovation en matériaux avancés durables

Lancé en 2022 par la Région Île-de-France, le programme DIM MaTerRE fédère près de 500 chercheurs et plus de 60 institutions autour d’un objectif : concevoir une nouvelle génération de matériaux avancés écoresponsables pour répondre aux urgences climatique et énergétique. Coordonné par l’ESPCI Paris-PSL sous la direction scientifique de Christian Serre, MaTerRE mise sur la découverte accélérée de matériaux modulables, multifonctionnels et performants, tout en intégrant des procédés respectueux de l’environnement. Quatre axes structurent les recherches : gestion des gaz stratégiques (H₂, CO₂), recyclage et éco-conception, matériaux pour les transports, l’énergie et le bâti, ainsi que procédés durables incluant modélisation, IA et haut débit. Le dispositif finance thèses, prématurations, équipements et missions internationales, avec un appel « Allocations 2026 » ouvert jusqu’à janvier prochain. Au-delà de la recherche fondamentale, MaTerRE vise une articulation forte avec l’innovation industrielle et la compétitivité francilienne, en conciliant performance, durabilité et acceptabilité socio-économique.

Réemploi collaboratif dans les salades prêtes à consommer

Dans le cadre du projet R3Pack, Florette, Les Crudettes et Sodebo se sont associées à Knauf Industries pour développer une barquette standardisée en polypropylène réemployable. Testée dans une vingtaine de magasins Carrefour et Coopérative U, cette barquette thermoformée de 1260 ml, conçue pour faciliter le lavage et limiter les coûts, repose sur le matériau Kaplight, noir sans noir de carbone, offrant résistance thermique et recyclabilité. Chaque marque conserve son identité via l’opercule et des étiquettes adhésives compatibles avec le lavage. Si le succès du modèle dépendra des taux de retour et du nombre de cycles (au moins 6 à 8 pour viabilité économique), l’initiative illustre l’importance de la mutualisation dans le réemploi et montre que des concurrents peuvent unir leurs forces pour accélérer la transition vers l’économie circulaire dans le secteur des salades traiteur.

https://www.usinenouvelle.com/article/reemploi-trois-marques-mais-une-seule-barquette-de-salade.N2238270

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Adhérez au GFP

Devenez un membre et découvrez les avantages d’un abonnement GFP.

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Sections locales GFP

Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.

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