Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Vers une ère automobile circulaire : les polymères recyclés s’imposent avant la nouvelle législation européenne
À l’approche de la future réglementation européenne sur la fin de vie des véhicules (ELV), les constructeurs accélèrent l’intégration de polymères recyclés dans leurs modèles. Au salon K 2025, Borealis a présenté une série d’applications automobiles illustrant cette mutation vers l’économie circulaire. L’un des exemples phares est un support de pare-chocs Volvo fabriqué à partir d’un polypropylène (PP) renforcé de fibres de verre, composé à 65 % de polymère post-consommation (PCR). Ce même matériau, Borcycle GD3600SY, avait initialement été développé pour la console centrale du Peugeot 3008. Les innovations s’étendent aussi aux polymères post-industriels (PIR) : Volvo utilise un PP minéralisé contenant 78 % de PIR pour un faisceau de câbles, tandis que BMW et Mercedes-Benz adoptent des composites Borcycle riches en PCR (jusqu’à 40 %) pour des éléments visibles comme les panneaux de porte ou les consoles centrales. Ces grades recyclés, souvent renforcés par des fibres de verre ou des charges minérales, offrent une apparence et des performances mécaniques comparables aux matériaux vierges. Borealis démontre également comment ces approches peuvent se combiner à des innovations fonctionnelles, telle qu’un film électrothermique en polyoléfine monomatériau pour le chauffage localisé des intérieurs de véhicules électriques. Cette convergence entre recyclabilité, efficacité énergétique et design marque une étape clé vers une industrie automobile à faible empreinte carbone, capable de concilier performance, esthétique et responsabilité environnementale.
International : Les étoiles montantes de la science des polymères 2025 : une génération entre durabilité, interfaces et matériaux intelligents
Le numéro spécial Rising Stars in Polymer Science 2025 du Polymer Journal met en lumière une nouvelle génération de chercheurs dont les travaux redéfinissent les frontières de la chimie et de la physique des polymères. Ces jeunes scientifiques, issus d’universités de premier plan au Japon, aux États-Unis, en Corée, à Taïwan et en Chine, illustrent la diversité et la vitalité de la recherche actuelle. Leurs approches couvrent un large spectre, de la conception de polymères durables et recyclables à base de biomasse ou de CO₂, à la mise au point de matériaux multifonctionnels pour l’énergie, l’électronique et la santé. Plusieurs lauréats s’attachent à comprendre la dynamique et la rhéologie des systèmes macromoléculaires, en explorant les relations entre structure, interfaces et propriétés mécaniques. D’autres développent des réseaux supramoléculaires réticulables, des gels dynamiques et des polymères reprocessables pour une chimie circulaire. L’essor des matériaux électroactifs et des polymères conducteurs pour batteries, capteurs et dispositifs flexibles traduit également la convergence entre ingénierie, durabilité et intelligence des matériaux. Ensemble, ces travaux annoncent une transition vers une science des polymères plus intégrée, capable de relier conception moléculaire, fonctionnalité et impact environnemental — une vision portée par cette nouvelle génération de chercheurs, à la croisée de la chimie verte, des nanostructures et des technologies adaptatives.
Effet de la convection forcée non uniforme sur les propriétés locales des polymères dans la fabrication additive par extrusion
Cette étude explore l’influence méconnue de la convection forcée générée par le ventilateur de refroidissement dans la fabrication additive par extrusion de fil fondu (FFF). À l’aide d’un réseau de thermocouples intégré sous le plateau chauffant d’une imprimante Prusa MK3S+, les chercheurs ont mesuré en temps réel les gradients thermiques induits par le flux d’air du ventilateur. Les résultats révèlent des écarts de température pouvant atteindre plusieurs dizaines de degrés entre le centre et la périphérie du plateau, accentués à haute température de consigne. Ces variations entraînent une compensation thermique du plateau et amplifient les gradients locaux, altérant la solidification du polymère. Des cubes en acide polylactique (PLA) ont ensuite été imprimés avec différents paramètres d’activation du ventilateur afin d’évaluer les effets sur la rugosité de surface, la fidélité géométrique et le retrait dimensionnel. Les zones non refroidies se sont avérées jusqu’à deux fois plus rugueuses et ont subi des déformations et rétrécissements marqués, tandis que le refroidissement non uniforme a provoqué des écarts importants entre les faces avant et arrière des pièces. Ces observations confirment que la convection forcée agit de manière hétérogène sur le processus de solidification et qu’elle doit être intégrée dans les modèles de transfert thermique du procédé FFF. Cette approche instrumentée, simple et non invasive, ouvre la voie à un contrôle thermique plus précis et à une meilleure prédiction des propriétés locales des polymères imprimés.
Nature Capteurs mécanoluminescents à polymère conjugué : vers des dispositifs haptiques écologiques et sans alimentation
Une équipe de l’Université Hanyang, en collaboration avec des chercheurs britanniques, a mis au point une nouvelle génération de capteurs mécanoluminescents (ML) capables d’émettre une lumière à haute résolution sans source d’énergie externe. Publiés dans Advanced Materials, leurs travaux exploitent une stratégie de filtration chromatique fondée sur l’enrobage de particules de ZnS:Cu par un polymère conjugué, le poly(9,9-dioctylfluorène-alt-benzothiadiazole) (F8BT). Cette couche polymérique agit simultanément comme filtre spectral et amplificateur de luminescence, réduisant l’élargissement du spectre d’émission (de 94 à 55 nm) tout en compensant la perte d’intensité lumineuse habituelle. Le résultat est une émission plus pure et moins bruitée dans le bleu, améliorant la précision des signaux dans les applications haptiques. Les chercheurs ont démontré un prototype de système de suivi chromatique sensible à la pression, capable de distinguer des émissions bleu et vert en temps réel. Cette approche ouvre la voie à des dispositifs sans batterie, adaptés à la robotique d’assistance, au suivi de mouvement, ou à des interfaces gestuelles novatrices comme les contrôleurs buccaux destinés aux fauteuils roulants. À plus long terme, ces capteurs pourraient équiper textiles intelligents, équipements de sécurité ou dispositifs de secours autonomes, transformant la lumière issue de la contrainte mécanique en signal fonctionnel, et dessinant un futur énergétiquement sobre et technologiquement sensible au toucher.
https://phys.org/news/2025-11-mechanoluminescent-sensors-dual-function-polymer.html
Nanocomposites polymères à relaxation améliorée par boucles polymériques liées aux nanoparticules
Cette étude propose une approche interfaciale innovante pour dépasser le compromis entre fluidité et résistance dans les nanocomposites polymères. En remplaçant la couche adsorbée rigide formée à la surface des nanoparticules par une couche de grandes boucles polymériques liées, les chercheurs conçoivent un réseau particulaire plus mobile et moins contraint. Ces boucles, issues d’un copolymère statistique P(styrène-ran-4-hydroxystyrene), favorisent la relaxation des chaînes de matrice, maintiennent un comportement rhéologique fluide et empêchent la formation de réseaux permanents limitant la mise en œuvre. Les composites ainsi obtenus présentent une viscosité réduite tout en conservant une forte cohésion interfaciale et une dissipation d’énergie accrue. Les enchevêtrements topologiques entre boucles et chaînes de matrice renforcent la résistance et la ténacité à l’état vitreux. Cette stratégie, fondée sur le contrôle dynamique des interfaces plutôt que sur la modification chimique, ouvre la voie à des nanocomposites à haute charge combinant processabilité et performances mécaniques élevées.
Nature Production autonome de propylène oxyde : un système catalytique sans énergie externe révolutionne la chimie des polymères
Des chercheurs de l’Université nationale des sciences et technologies d’Ulsan (UNIST) ont mis au point un système catalytique autoalimenté capable de produire du propylène oxyde (PO) — un intermédiaire clé pour les polyuréthanes, polyesters et plastiques techniques — sans recourir à l’électricité ni à la lumière solaire. Publiée dans Nature Communications, cette avancée repose sur la génération in situ de peroxyde d’hydrogène (H₂O₂) via une réaction électrochimique spontanée entre l’oxygène et le formaldéhyde, exploitant uniquement la différence de potentiel chimique entre les demi-réactions. Le H₂O₂ ainsi formé oxyde directement le propylène en PO au sein du même dispositif. L’équipe a repensé la structure du catalyseur, surpassant les limites des zéolithes TS-1 traditionnelles dont l’activité chute en milieu alcalin, condition pourtant nécessaire à la formation de H₂O₂. Ce design innovant améliore considérablement le rendement de l’époxydation, atteignant des performances huit fois supérieures aux procédés écologiques précédents. Outre une réduction de 8 % des coûts de production et l’absence d’équipement sous pression ou à haute température, le procédé produit également de l’hydrogène comme co-produit énergétique. Compact, modulable et décentralisable, ce système marque un tournant vers une chimie du propylène plus durable, conciliant efficacité énergétique, économie circulaire et autonomie des sites de production.
https://phys.org/news/2025-11-key-plastic-ingredient-house-generated.html
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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cnrs
http://www.ispa.asso.fr
hutchinson
http://www.hutchinson.com/fr
arkema
http://www.coatex.com
LPMC
http://www.ispa.asso.fr
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
ICS
https://www-ics.u-strasbg.fr/
lrccp
http://www.ispa.asso.fr
Logo-ChemSuD
http://www.ispa.asso.fr
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