Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Hommage à Frédéric Thiébaud
Chères et chers collègues,
C’est avec une profonde émotion que nous vous faisons part du décès de notre collègue Frédéric Thiébaud. Sa disparition laisse une grande tristesse au sein de notre communauté et un vide immense sur les plans humain, scientifique et académique. lire plus…
Ateliers Prospective 2026 : ATTENTION NOUVELLE DATE A VENIR
Polymères pour batteries Metal ion
Date : Annulation de la date de 04/02, nouvelle date à venir
La filière européenne des batteries vit une phase stratégique, produire des batteries metal ion hautes performances, compétitives, durables et souveraines.
Les polymères y jouent un rôle déterminant, les binders d’électrodes jusqu’aux séparateurs et électrolytes solides.
Ils conditionnent, en partie, la productivité des lignes, la sécurité, la durabilité des cellules metal-ion. lire plus…
Couplage Vibronique et Amplification de la Chiralité Optique dans les Polymères Conjugués
Des travaux récents mettent en lumière une avancée méthodologique majeure pour surmonter les limitations intrinsèques des matériaux organiques chiraux, dont les facteurs de dissymétrie optique demeurent souvent modestes à l’état solide. En déployant une stratégie d’excitation spectroscopique à double résonance, les chercheurs ont réussi à exalter le couplage vibronique énantio-sélectif au sein de polymères conjugués à architecture hélicoïdale. Ce procédé novateur repose sur le pompage sélectif et simultané de niveaux vibrationnels et électroniques spécifiques, déclenchant une émission par conversion ascendante (upconversion) dont l’intensité dépend intimement du champ électromagnétique incident. Contrairement aux approches classiques d’absorption linéaire, cette technique non linéaire permet de discriminer finement les contributions structurales et électroniques à la chiralité, révélant ainsi une anisotropie optique nettement supérieure aux standards habituels. Par conséquent, la mise en évidence de ce mécanisme de transduction chiroptique offre une compréhension renouvelée des interactions lumière-matière dans les systèmes macromoléculaires complexes. Cette rupture conceptuelle ouvre des perspectives technologiques immédiates pour l’élaboration de dispositifs photoniques avancés, notamment dans les domaines de la détection ultrasensible, de l’affichage 3D et du stockage optique de l’information, où la modulation précise de la polarisation constitue un enjeu industriel critique.
Stéréochimie macromoléculaire programmable : vers des polymères eutactiques sur mesure
Une avancée majeure en chimie des polymères permet désormais un contrôle absolu de l’architecture stéréochimique des macromolécules synthétiques, dépassant les limitations historiques des matériaux atactiques, isotactiques ou syndiotactiques traditionnels. En s’inspirant de la précision biologique de la synthèse de l’ADN, des chercheurs ont développé une méthode itérative automatisée sur support solide, exploitant la chimie des phosphoramidites pour assembler séquentiellement des monomères énantiomériquement purs. Cette stratégie offre une maîtrise totale de l’enchaînement et de l’orientation spatiale de chaque unité constitutive, permettant de générer des chaînes de longueur parfaitement définie et d’une uniformité structurelle sans précédent. Par conséquent, cette innovation ouvre la voie à la conception de polymères « eutactiques » aux propriétés physico-chimiques et optiques finement ajustables, avec des applications potentielles révolutionnaires dans le stockage d’information moléculaire, les matériaux auto-assemblés et les dispositifs optiquement actifs de haute précision.
Monomères Photosensibles : Une nouvelle ère pour la polymérisation contrôlée
Des chercheurs ont introduit une stratégie de rupture dans le domaine de la polymérisation par ouverture de cycle par métathèse (ROMP), délaissant la modulation traditionnelle des catalyseurs au profit d’un contrôle direct de la réactivité des monomères. Cette approche repose sur l’exploitation de couples isomériques, tels que le système quadricyclane-norbornadiène, où la forme bicyclique latente demeure parfaitement inerte en présence d’initiateurs au ruthénium, assurant ainsi une stabilité de stockage remarquable. L’activation, déclenchée à la demande par des stimuli thermiques ou photothermiques via des nanostructures d’or, convertit le précurseur dormant en monomère réactif, initiant instantanément la croissance des chaînes. Ce mécanisme offre une maîtrise spatiotemporelle inédite, permettant non seulement la synthèse « monotope » de copolymères séquencés complexes, mais également un durcissement séquentiel précis. Par conséquent, cette innovation lève des verrous technologiques majeurs pour l’impression 3D haute résolution, les revêtements intelligents et l’ingénierie des matériaux avancés, alliant robustesse industrielle et finesse architecturale.
Nature Microfluidique sur papier : la miniaturisation analytique par l’impression 3D
Une avancée significative dans les technologies analytiques à faible coût permet de transformer du papier filtre standard en plateformes microfluidiques miniaturisées, notamment par l’intégration d’une technique d’impression 3D par projection de lumière numérique (DLP 3D printing) pour la structuration. Cette approche exploite la nature capillaire de la cellulose pour diriger l’écoulement des fluides au travers de canaux délimités par des barrières hydrophobes, offrant une alternative extrêmement économique et simple aux dispositifs microfluidiques conventionnels. Ces plateformes sur papier se distinguent par leur portabilité, leur faible coût de fabrication et leur caractère biodégradable, ce qui les positionne comme des outils essentiels pour les diagnostics rapides au point d’intervention (Point-of-Care), la surveillance environnementale et les analyses de qualité alimentaire dans les régions à ressources limitées.
https://phys.org/news/2025-12-everyday-filter-paper-miniature-microfluidic.html
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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