Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Une turbulence cachée révélée dans les fluides polymères
Des chercheurs de l’Okinawa Institute of Science and Technology ont montré que deux formes de turbulence coexistent dans les fluides polymères utilisés au quotidien, comme les shampooings ou le ketchup. Jusqu’ici, l’inertielle (due aux forces de mouvement) et l’élastique (due à l’élongation des chaînes polymères) étaient considérées comme distinctes, apparaissant dans des conditions opposées. Grâce à des simulations numériques à très haute résolution, l’équipe a découvert que, dans un même écoulement, les grandes échelles suivent la turbulence inertielle tandis que les petites échelles révèlent une turbulence élastique. Cette avancée unifie deux branches de la mécanique des fluides complexes et ouvre des perspectives pour la maîtrise des écoulements polymères dans le transport, le mélange chimique et les applications biomédicales.
[GDR MultiPODE] CALL FOR COMMUNICATIONS : September 30 & October 1, 2025, Bordeaux – Two scientific days dedicated to bio-based materials & eco-design, organized by the GPR PPM and GDR MultiPODE
Le Grand Programme de Recherche bordelais « Matériaux post-pétrole » (GPR PPM) et le GDR Multipode « Multifunctional nanostructured POlymer systems by DEsign » s’associent pour proposer deux journées thématiques dédiées aux matériaux bio-sourcés & à l’éco-conception le mardi 30 septembre et le mercredi 1 octobre à Talence. lire plus…
Construire et déconstruire les plastiques avec la lumière
Des chercheurs de l’Université de technologie d’Eindhoven viennent de démontrer qu’il est possible de créer et de recycler un polymère uniquement avec de la lumière LED. Cette nouvelle génération de matériaux repose sur une conception « design for recycling » où les liaisons chimiques sont pensées pour être réversibles. Alors que le recyclage classique par fusion dégrade progressivement les chaînes macromoléculaires, la voie photchimique permet de les scinder sélectivement en leurs briques constitutives, puis de reformer le polymère avec une qualité identique. Le groupe de recherche mené par Fabian Eisenreich a ainsi obtenu en laboratoire les premiers polymères capables d’entrer dans une boucle fermée de recyclage chimique, déclenchée par irradiation lumineuse. Au-delà d’un simple prototype, cette approche ouvre des perspectives pour des applications spécialisées comme des adhésifs recyclables ou la fabrication additive par photopolymérisation. L’ambition est d’élargir ces procédés à des polymères plus conventionnels, jusqu’à imaginer un jour un recyclage activé directement par la lumière solaire.
https://phys.org/news/2025-08-plastics-chemists-rethink-plastic-recycling.html
L’imagerie moléculaire révèle des défauts cachés dans les polymères électroniques
Des chercheurs ont utilisé la microscopie à effet tunnel (STM) couplée à l’électrospray deposition (ESD) pour observer au niveau moléculaire des polymères conducteurs issus de la condensation aldolique, une méthode de synthèse réputée verte et sans métaux. Cette analyse a mis en évidence deux types de défauts : des défauts de couplage, liés à des liaisons mal orientées créant des “coudes” dans la chaîne, et des défauts de séquence, perturbant l’ordre des motifs répétés. Ces irrégularités freinent le transport des électrons et peuvent limiter les performances en électronique flexible ou en dispositifs thermoélectriques. En optimisant la purification des monomères ou en combinant la condensation aldolique avec d’autres voies de polymérisation, l’équipe a démontré qu’il était possible de réduire fortement ces défauts et d’obtenir des polymères aux propriétés électroniques plus fiables, ouvrant la voie à des plastiques conducteurs à la fois performants et durables.
https://phys.org/news/2025-08-molecular-imaging-uncovers-hidden-flaws.html
Quand l’IA découvre des molécules qui rendent les plastiques plus résistants
Des chercheurs du MIT et de l’université Duke ont utilisé l’intelligence artificielle pour accélérer la recherche de nouvelles molécules capables de renforcer les polymères. Ils se sont intéressés aux ferrocenes, des composés organométalliques où un atome de fer est pris en sandwich entre deux cycles carbonés. Intégrés comme mécanophores — ces maillons moléculaires qui réagissent à une contrainte mécanique — certains ferrocenes agissent comme des points de rupture contrôlés. Au lieu de propager une fissure dans tout le matériau, ces liaisons plus faibles obligent la fracture à contourner les zones solides, ce qui augmente la résistance globale. Grâce à un réseau de neurones entraîné sur plus de 5 000 ferrocenes issus de bases de données, l’équipe a identifié une centaine de candidats prometteurs. Testé dans une matrice de polyacrylate, l’un d’eux, le m-TMS-Fc, a permis d’obtenir un plastique quatre fois plus résistant à la déchirure qu’un polymère classique. Cette stratégie ouvre la voie à des plastiques durables, dont la longévité accrue pourrait réduire la production et donc les déchets, tout en élargissant le champ des mécanophores utilisables, y compris pour des applications comme les capteurs de contrainte ou les catalyseurs activables mécaniquement.
https://phys.org/news/2025-08-ai-uncovers-molecules-stronger-longer.html
Un plastique intelligent auto-cicatrisant plus résistant que l’acier
Des chercheurs de Texas A&M University ont révélé les propriétés exceptionnelles d’un copolyester thermodurcissable aromatique (ATSP) renforcé de fibres de carbone. Ce vitrimer associe la stabilité des thermodurcissables et la flexibilité des thermoplastiques, donnant naissance à un matériau plus léger que l’aluminium et plusieurs fois plus résistant que l’acier. Sa particularité réside dans sa capacité à se réparer et à retrouver sa forme après un dommage, grâce à des échanges de liaisons activés par la chaleur. Lors de tests de fatigue cyclique, le matériau endommagé a retrouvé presque toute sa résistance après deux cycles de chauffage à 280 °C. ATSP est également recyclable : il peut être broyé, remodelé et réutilisé sans perte significative de performances, ce qui en fait un candidat prometteur pour l’aéronautique, la défense et l’automobile. Cette avancée ouvre la voie à une nouvelle génération de composites polymères adaptatifs, capables d’évoluer et de durer dans des environnements extrêmes.
https://www.specialchem.com/plastics/news/new-self-healing-smart-plastic-that-is-stronger-than-steel
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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http://www.ispa.asso.fr
Logo-ChemSuD
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lrccp
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LPMC
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arkema
http://www.coatex.com
ICS
https://www-ics.u-strasbg.fr/
cnrs
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http://www.waters.com
hutchinson
http://www.hutchinson.com/fr
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