Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Un bioplastique de bambou aussi résistant que le plastique pétrosourcé, mais biodégradable en 50 jours
Une équipe chinoise dirigée par Haipeng Yu et Dawei Zhao a mis au point un bioplastique issu du bambou combinant haute performance mécanique et biodégradabilité rapide, selon une étude publiée dans Nature Communications. Contrairement aux composites habituels à base de fibres de bambou dispersées dans une matrice polymère non dégradable, cette approche dissout la cellulose du bambou à l’échelle moléculaire grâce à un solvant alcoolique non toxique, puis la restructure en un réseau polymérique dense et orienté. Cette organisation confère au matériau une résistance à la traction de 110 MPa et une énergie de rupture de 80 kJ·m⁻³, supérieures à celles du polystyrène ou de l’acide polylactique, tout en conservant une bonne stabilité thermique et une grande aptitude au moulage. Surtout, le matériau se dégrade totalement dans le sol en moins de deux mois, ou peut être recyclé en boucle fermée sans perte notable de propriétés (90 % de la résistance initiale conservée). Ce procédé de « façonnage moléculaire » ouvre la voie à une nouvelle génération de bioplastiques biosourcés, durables et performants, susceptibles de remplacer les polymères pétrosourcés dans des applications structurelles ou techniques, marquant une avancée majeure vers une économie plastique réellement circulaire et biodégradable.
https://phys.org/news/2025-10-bamboo-based-plastic-biodegrade-quickly.html
Architectures polymères « slippery » imprimées en 3D pour manipulations liquides multifonctions
Les auteurs présentent une plateforme de fabrication numérique qui intègre, en une chaîne photo-induite, la création de matériaux multiphasiques et le greffage de brosses PDMS pour produire des interfaces solides–liquides stables au sein de micro- et macro-architectures polymères. Deux familles complémentaires sont combinées : (i) des réseaux acrylates nanoporeux issus de séparations de phase sous photopolymérisation, ensuite imprégnés d’un lubrifiant silicone et fonctionnalisés, qui offrent une faible fraction solide en contact et une bonne définition de motifs ; (ii) des organogels PDMS transparents et flexibles, obtenus par photo-réticulation de formulations contenant le lubrifiant, assurant une rétention durable et une compatibilité avec l’impression DLP. Cette approche unifiée permet la texturation numérique de la mouillabilité (motifs et gradients anisotropes), l’empreinte UV-NIL de microcavités pilotant l’évaporation et l’agrégation particulaire, et l’impression 3D monolithique de « SlipChips » où des canaux asymétriques guident des gouttes sans apport énergétique externe. Les surfaces obtenues conjuguent anti-adhérence (liquides, glace), anti-salissure, transparence et confinement capillaire localisé, tout en restant compatibles avec des procédés à grande échelle (roll-to-plate, DLP). Au-delà de l’état de l’art centré sur des géométries planes, cette synthèse matière-procédé élargit le champ des interfaces infusées—du codage de textures mouillantes aux microdispositifs biomédicaux—tout en pointant des axes d’optimisation (résolution verticale et intégrité mécanique des résines photocurables) pour la montée en complexité des architectures.
Nature Un adhésif polymère « stick-peel-reuse » inspiré de la chimie clé-serrure
Des chercheurs de l’Université d’Osaka ont conçu un adhésif polymère réversible capable de coller, se décoller et se recoller à volonté, ouvrant la voie à une adhésion réutilisable et démontable pour l’industrie. Publiée dans Advanced Materials, leur étude repose sur la chimie des complexes hôte–invité, où une molécule « hôte » dotée d’une cavité accueille une molécule « invitée » complémentaire, à la manière d’une clé entrant dans une serrure. Les chercheurs ont synthétisé deux polymères capables de former ces liaisons supramoléculaires à leur interface, tout en ajustant leur température de transition vitreuse (Tg) pour favoriser la mobilité des chaînes et permettre la formation efficace des complexes. Grâce à des analyses par diffusion de neutrons, l’équipe a observé en temps réel la formation et la rupture de ces liaisons : le contrôle de la température ou l’ajout/retrait de réactifs permet d’activer ou de désactiver l’adhésion à la demande. Ce nouveau matériau combine force d’adhérence, recyclabilité et modularité, offrant des perspectives prometteuses pour l’assemblage de dispositifs électroniques, la fabrication de précision ou encore la réduction des déchets industriels. En réinventant la colle comme un système dynamique et intelligent, cette innovation marque une avancée majeure vers des adhésifs polymères durables et reconfigurables.
https://phys.org/news/2025-10-reuse-adhesive-based-key-chemistry.html
Durabilité chimique des composites bio-polyamide renforcés en fibres de cellulose régénérée face aux milieux acides et basiques
Cette étude analyse la stabilité chimique du polyamide biosourcé PA5.10 et de ses composites renforcés par des fibres de cellulose régénérée (RCF), dans le but d’évaluer leur aptitude à remplacer les polyamides pétrosourcés dans des applications techniques exigeantes. Les échantillons, élaborés par extrusion bi-vis et moulage par injection, ont été exposés à divers environnements aqueux, acides, alcalins et organiques afin d’identifier les mécanismes de dégradation et les effets sur les propriétés mécaniques et structurales. Les résultats montrent que la dégradation hydrolytique constitue le principal facteur d’altération du polymère, se traduisant par des phénomènes de coupure de chaînes, de gonflement des fibres et de désadhésion à l’interface matrice-fibre. Les milieux acides et basiques accélèrent la scission des liaisons amide dans la matrice et la rupture des liaisons glycosidiques de la cellulose, provoquant un affaiblissement progressif du renfort et une perte de cohésion du composite. Les analyses FTIR et microscopiques confirment ces processus, tandis que les essais mécaniques mettent en évidence une baisse de résistance en traction corrélée à l’absorption d’humidité et à la dégradation chimique. Malgré cette sensibilité, les composites PA5.10/RCF présentent un comportement ductile et une densité réduite, constituant une alternative plus légère et à plus faible empreinte carbone que les composites à fibres de verre. Les auteurs soulignent toutefois la nécessité d’optimiser la formulation par l’ajout de stabilisants hydrolytiques ou de traitements de surface des fibres afin d’améliorer la durabilité de ces matériaux biosourcés dans des environnements chimiques sévères.
Nature Réseau PVA–SPPESK à volume libre optimisé et photothermie sélective pour des revêtements anti-buée durables et transparents
Les auteurs proposent une architecture polymère qui combine une matrice hydrophile à liaisons hydrogène (polyvinylalcool) et des segments sulfonés à géométrie torsadée non coplanaire (SPPESK) afin d’augmenter le volume libre interne sans épaissir le film, stabiliser l’adhésion interfaciale et maintenir la transparence; cette conformation favorise un maillage dense de liaisons H et engendre une distribution bimodale de cavités, couplant des pores « piégeurs » nanométriques (rétention d’eau non givrante) et des canaux de diffusion (apport rapide), ce qui supprime la nucléation de microgouttes au profit d’un film continu même sous cycles humidité/séchage; l’intégration de nanocristaux de bronze tungstate césium (CTB) ajoute une photothermie sélective UV/NIR tout en préservant la transmission visible, convertissant une part significative du spectre solaire en élévation locale de température pour prévenir ou résorber la buée sans alimentation électrique; la formulation, mise en œuvre par trempage, essorage ou racle, montre une forte robustesse mécanique (adhésion, anti-abrasion, anti-encrassement) et une compatibilité substrats rigides/flexibles, avec des essais en conditions réelles (verres correcteurs, pare-brise, serres) confirmant la constance d’optique et l’anti-buée prolongée; en reliant conception moléculaire (torsion, sulfonation) et ingénierie d’interface (brosses H, volume libre hiérarchisé, photothermie transparente), cette stratégie dépasse les limites des hydrophiles gonflants et des hydrophobes cassie-baxteriens, ouvrant la voie à des revêtements anti-buée pérennes, recyclables en service par la lumière ambiante et industrialisables à grande échelle.
Nature Syensqo met au point une technologie de recyclage chimique pour des polymères sulfonés circulaires
Le groupe Syensqo annonce une avancée majeure dans le domaine des polymères techniques avec le développement d’une technologie exclusive de recyclage chimique capable de dépolymériser efficacement les polymères sulfonés (PAES) afin d’en extraire des monomères purifiés réutilisables à l’infini. Cette innovation, issue de la gamme durable ECHO™, permet de transformer aussi bien les rebuts de production que les produits en fin de vie en matières premières de haute pureté, sans dégradation des performances. Les monomères régénérés peuvent être réincorporés dans les grades emblématiques de Syensqo — Udel® PSU, Radel® PPSU et Veradel® PESU — ou dans d’autres polymères thermoplastiques et formulations d’époxy, garantissant une véritable circularité moléculaire. En ciblant les marchés exigeants tels que la filtration, la santé ou l’aéronautique, l’entreprise renforce son leadership en matière de polymères durables à haute performance. Selon Floryan De Campo, vice-président Life Solutions, cette technologie marque une étape décisive vers la décarbonation et l’intégration accrue de matières recyclées dans les chaînes de valeur. En s’appuyant sur la coopération entre acteurs du tri, de la collecte et de la transformation, Syensqo trace la voie d’un modèle circulaire pour les polymères sulfonés, conciliant innovation industrielle et responsabilité environnementale.
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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LPMC
http://www.ispa.asso.fr
logo-ispa_coul_fond-fonce
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lrccp
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ICS
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http://www.waters.com
arkema
http://www.coatex.com
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hutchinson
http://www.hutchinson.com/fr
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