Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
L’entropie topologique appliquée aux polymères : une approche mathématique prédictive
Des chercheurs ont exploité la théorie des graphes pour quantifier la complexité structurale de polymères comme les polyesters et polycarbonates. En calculant divers indices topologiques (Zagreb, géométrico-arithmétique, connectivité atome-liaison) et leurs entropies de Shannon associées, ils ont établi un modèle de régression logarithmique reliant ces descripteurs à la désorganisation moléculaire. Cette approche mathématique permet de relier la structure chimique à des propriétés physicochimiques clés, ouvrant la voie à une prédiction fine des performances des matériaux polymères à partir de leur topologie moléculaire.
La cryo-tomographie révèle la dynamique des polymères photo-résistants pour une lithographie sans défauts
Des chercheurs chinois ont utilisé la cryo-tomographie électronique pour reconstruire en 3D le comportement des polymères photo-résistants dans un film liquide, étape clé du développement des circuits intégrés. Cette méthode révèle pour la première fois l’organisation et les enchevêtrements moléculaires au niveau de l’interface air-liquide, responsables de nombreux défauts de motifs. En optimisant ces interactions, les auteurs ont supprimé plus de 99 % des contaminations sur des plaquettes de 12 pouces, ouvrant la voie à une lithographie industrielle plus précise et compatible avec les procédés de fabrication avancés.
Nature Renforcer les bioplastiques de soja grâce à une ingénierie bio-inspirée
Des chercheurs de l’Université Washington à St. Louis ont mis au point une méthode innovante pour améliorer considérablement les performances mécaniques des bioplastiques à base de protéines de soja et de cellulose. Ces polymères naturels, proposés comme alternatives aux plastiques pétrosourcés, souffrent souvent de fragilité et de faible résistance. L’équipe de Marcus Foston a montré que le revêtement des nanocristaux de cellulose par une fine couche de polydopamine — molécule inspirée des adhésifs marins des moules — modifie l’interface entre phases et accroît la cohésion du matériau. Cette modification de surface optimise les interactions entre la matrice protéique et le renfort cellulosique, multipliant par plus de 300 % la résistance à la traction et la flexibilité du composite. Cette approche, décrite dans Polymer Composites, démontre que les biopolymères issus de ressources végétales peuvent être structurellement optimisés pour rivaliser avec les polymères fossiles, ouvrant la voie à une nouvelle génération de matériaux biosourcés performants et durables.
Une catalyse enzymatique accélère la production de plastiques biosourcés fonctionnels
Des chercheurs de l’Université de Hokkaido ont mis au point un procédé biocatalytique inédit permettant de produire rapidement des polyesters biosourcés aux propriétés fonctionnelles avancées. Publiés dans ACS Sustainable Chemistry & Engineering, leurs travaux décrivent l’utilisation d’une enzyme modifiée, la cutinase issue de levures, pour polymériser efficacement des monomères dérivés de ressources renouvelables comme les acides gras et les diols végétaux. Ce procédé, mené en conditions douces, permet d’obtenir des polymères présentant des groupements fonctionnels réactifs tout en réduisant le recours aux solvants et catalyseurs métalliques. Les plastiques ainsi formés présentent des propriétés mécaniques modulables et une dégradabilité accrue, tout en étant produits à une vitesse plus de dix fois supérieure aux approches enzymatiques classiques. Cette avancée démontre le potentiel de la catalyse biotechnologique pour accélérer la fabrication de polymères durables et multifonctionnels, tout en rapprochant la chimie verte des exigences industrielles de performance et de rendement.
https://phys.org/news/2025-10-faster-bio-based-functional-plastic.html
Hydrogels fongiques : la nature inspire une nouvelle génération de biomatériaux
Des chercheurs de l’Université de l’Utah ont découvert qu’un champignon du sol, Marquandomyces marquandii, forme spontanément des hydrogels multicouches capables d’absorber jusqu’à 83 % d’eau tout en conservant leur élasticité. Ces structures, constituées de chitine — biopolymère également présent dans les coquilles et exosquelettes — présentent des porosités différenciées et une remarquable résistance mécanique. Leur composition et leur comportement de déformation suggèrent un potentiel majeur pour des applications biomédicales, notamment en régénération tissulaire, en matrices cellulaires ou en dispositifs souples implantables. Cette approche bio-inspirée illustre comment les architectures mycéliennes naturelles peuvent servir de gabarits à des hydrogels fonctionnellement gradués, alliant durabilité, biocompatibilité et performance mécanique.
https://phys.org/news/2025-10-soil-fungus-durable-hydrogels-potential.html
Recyclage du plastique : quand la solution devient parfois contre-productive
Selon une analyse publiée par le CNRS, le recyclage des plastiques ne constitue pas systématiquement une option vertueuse pour l’environnement. Les chercheurs rappellent que si le recyclage mécanique permet de prolonger la durée de vie des polymères, il ne supprime ni la dépendance au carbone fossile ni la dégradation progressive des propriétés du matériau. Pire, les procédés eux-mêmes — broyage, lavage, extrusion — consomment énergie et eau tout en générant des microplastiques. L’étude souligne également que la réintégration de plastiques recyclés dans des produits à faible durée de vie ne réduit pas significativement la production de matière vierge. Les scientifiques plaident pour un changement de paradigme : plutôt que de miser uniquement sur le recyclage, il faut concevoir des matériaux réellement circulaires, via la chimie de dépollution, le recyclage chimique sélectif, l’écoconception et la réduction à la source. Le recyclage n’est donc pas une fin en soi, mais un maillon parmi d’autres d’une transition plus systémique vers la sobriété matérielle.
CNRS Le journal Lorem ipsum dolor sit amet, consectetur adipiscing elit. Sed posuere tincidunt quam sit amet viverra. Nam in consequat nulla. Nunc rhoncus orci vitae arcu sagittis, in auctor nibh posuere. Donec ut nulla id enim tempor feugiat.
Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.
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hutchinson
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cnrs
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LPMC
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arkema
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