Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
PEF biosourcé : un polyester à barrière exceptionnelle pour l’hydrogène sous pression
Une étude computationnelle démontre que le polyéthylène furanoate (PEF), polyester biosourcé doté d’un cycle furane rigide, présente des barrières de diffusion de l’hydrogène bien supérieures à celles du PA6 et du PE, matériaux actuellement utilisés pour les réservoirs de type IV. Les calculs DFT, MD et NEB révèlent que l’α-PEF combine une forte densité cristalline à des pièges quasi-coplanaires formés par des atomes d’oxygène intrachaîne, élevant les barrières de diffusion (0,828 eV, soit ~26× PE). Cette organisation confère une résistance remarquable à la perméation, soutenue par une stabilité mécanique et thermique intrinsèque. Bien que l’étude se concentre sur les domaines cristallins, ces résultats ouvrent la voie à l’intégration de PEF ou de composites dérivés comme matériaux de liners durables pour le stockage et le transport d’hydrogène haute pression.
Électrochimie et revalorisation des oligomères issus du recyclage des composites
Une équipe de l’Université de l’Illinois démontre qu’un traitement électrochimique permet de transformer les oligomères, sous-produits de la déconstruction des composites à fibres de carbone, en matériaux dynamiques à hautes performances. En réalisant une double fonctionnalisation C–H coopérative directement sur l’ossature oligomérique, les chercheurs introduisent des groupements capables de réformer un réseau polymère covalent adaptable (CANs). Ce procédé confère à ces fragments initialement peu valorisables de nouvelles propriétés mécaniques et une recyclabilité accrue, ouvrant la voie à des thermodurcissables circulaires pour l’automobile, l’aéronautique et l’électronique. Outre l’intérêt applicatif, cette première démonstration à grande échelle d’une double fonctionnalisation C–H sur une matrice polymère complexe marque une avancée chimique majeure et illustre le potentiel de l’électrochimie comme levier pour l’upcycling des polymères.
https://phys.org/news/2025-09-electrochemistry-enables-upcycling-polymer-high.html
Sels chaotropes et déstructuration entropique des kératines
Des chercheurs de Harvard (SEAS) ont élucidé le mécanisme par lequel des sels tels que le bromure de lithium dénaturent les protéines fibreuses (kératine de cheveux, laine, plumes). Contrairement au paradigme classique d’une interaction directe sel–protéine, les simulations et expériences révèlent une action indirecte sur le réseau d’eau : la structuration de l’eau par les ions modifie l’environnement thermodynamique, induisant l’ouverture spontanée des chaînes kératiniques. Cette compréhension mécanistique a permis de développer un procédé réversible, doux et réutilisable, pour extraire la kératine et générer des gels solides sans recourir à des agents corrosifs. L’approche ouvre la voie à l’upcycling de gisements massifs de biomasse protéique animale en matériaux fonctionnels durables, offrant des alternatives potentielles aux plastiques d’origine fossile et de nouvelles plateformes biomédicales.
https://www.sciencedaily.com/releases/2025/09/250916221913.htm
Craquage électrifié du py-oil à 100 % dans le RDR de Coolbrook
Coolbrook a validé pour la première fois le craquage direct d’une huile de pyrolyse issue à 100 % de déchets plastiques dans son réacteur électrifié RotoDynamic Reactor™. Sans dilution fossile, le procédé atteint >1000 °C par énergie renouvelable et génère des rendements élevés d’éthylène et de propylène en conditions stables, sans surcokage. Cette avancée illustre le potentiel du RDR pour boucler la circularité carbone et fournir une voie industrielle décarbonée et traçable pour la production d’oléfines.
Les microplastiques, nouveaux acteurs du remodelage osseux pathologique
Une revue de 62 articles scientifiques, publiée dans Osteoporosis International, met en évidence l’impact délétère des microplastiques sur le tissu osseux. Ces particules, désormais détectées jusque dans la moelle osseuse, altèrent la viabilité cellulaire, accélèrent la sénescence et favorisent la différenciation ostéoclastique, intensifiant la résorption osseuse. Des modèles animaux montrent un affaiblissement de la microarchitecture, des dysplasies et un arrêt de croissance squelettique. Ces données suggèrent que l’exposition chronique pourrait contribuer aux maladies ostéométaboliques et à l’augmentation prévue des fractures liées à l’ostéoporose. Identifier les microplastiques comme facteur environnemental contrôlable devient un enjeu majeur pour la prévention des pathologies osseuses.
Plastiques témoignages de l’Anthropocène
Un article publié dans Cambridge Prisms: Plastics propose une approche inédite : considérer les plastiques comme des vestiges archéologiques. Les chercheurs de l’Université de York et de Flinders University avancent que les déchets plastiques constituent un véritable enregistrement des comportements humains, au même titre que les silex ou tessons de poterie pour les civilisations passées. La “Plastic Age”, débutée dans les années 1950 avec l’essor des plastiques à usage unique, se distingue par son caractère universel et immédiat. Objets datés (bouteilles, sacs, emballages) pourraient ainsi devenir des marqueurs stratigraphiques précis pour les archéologues du futur. Mais ce constat s’accompagne d’un dilemme éthique : si ces plastiques sont une archive précieuse de nos modes de vie, ils représentent aussi une menace environnementale majeure. Les auteurs proposent donc de les envisager comme une mémoire matérielle à documenter plutôt qu’à préserver, ouvrant une nouvelle dimension dans l’étude du rapport entre matériaux, comportements humains et santé planétaire.
https://www.plasticstoday.com/materials/plastics-are-an-archaeology-of-us-
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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cnrs
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Waters_logo_stacked_K_web-NEW
http://www.waters.com
LPMC
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hutchinson
http://www.hutchinson.com/fr
lrccp
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arkema
http://www.coatex.com
ICS
https://www-ics.u-strasbg.fr/
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http://www.ispa.asso.fr
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