Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Polymères riches en soufre pilotés par la lumière et conçus pour une recyclabilité intrinsèque
Des chercheurs ont démontré qu’un apport lumineux contrôlé pouvait servir de levier de synthèse pour des polymères riches en soufre, en exploitant la labilité des liaisons soufre–soufre afin d’assembler des unités monomères par voie radicalaire sous conditions jugées douces et accessibles. Le procédé repose sur l’activation initiale par ultraviolet, puis sur une irradiation par LED modulée en impulsions, conçue pour réguler finement la concentration en radicaux et limiter les phénomènes de dégradation pendant la propagation, ce qui favorise l’obtention de chaînes de masse molaire élevée et de réseaux exploitables en formulation. Cette maîtrise cinétique ouvre un contrôle « marche/arrêt » de la polymérisation, et, à l’inverse des plastiques irréversibles, la même signature chimique rend possible une dépolymérisation déclenchée soit par lumière, soit par chauffage à température élevée, régénérant des briques réutilisables pour refermer le cycle matière. Au-delà de démonstrations déjà associées aux polymères soufrés (captation de métaux, optiques infrarouges, activité antimicrobienne), l’étude met en avant des débouchés directs en adhésifs recyclables, résines photosensibles pour lithographie et revêtements anticorrosion, suggérant une filière de matériaux performants issue de ressources soufrées résiduelles et compatible avec une économie circulaire.
https://phys.org/news/2026-01-sustainable-sulfur-rich-polymers-stay.html
Polyuréthanes sans isocyanates : dicarbamates issus du CO2 pour une synthèse plus sûre et pilotable
Une étude récente met en lumière une voie de synthèse de polyuréthanes dépourvue d’isocyanates, en substituant ces intermédiaires très réactifs par des dicarbamates considérés comme non toxiques et préparés à partir de CO2 et de méthanol via réaction avec des diamines sous haute pression. Le schéma réactionnel conserve l’architecture uréthane attendue : les motifs obtenus sont annoncés comme indiscernables de ceux issus des voies conventionnelles, ce qui permet de transposer les savoir-faire de formulation et de viser des performances mécaniques et viscoélastiques comparables. Sur le plan procédé, un système modulaire est décrit, où le dicarbamate déclenche la polyaddition, des diols polymères règlent l’assouplissement et des allongeurs de chaîne pilotent la réticulation, avec une mise en œuvre par fusion, agitation à température élevée puis refroidissement avant caractérisations (résistance, élasticité, aptitude adhésive). À l’inverse des isocyanates, la moindre réactivité des dicarbamates impose une cinétique plus lente, mais rend le suivi industriel plus maîtrisable, limitant rebuts et dérives de qualité tout en allégeant les contraintes HSE lors de la fabrication. Parallèlement, des voies de recyclage de polyuréthanes en fin de vie sont explorées, afin de réintroduire la matière dans de nouvelles formulations, et des démonstrateurs visent des tubes de cathéter biocompatibles ainsi que des adhésifs d’assemblage, ouvrant une trajectoire crédible vers une production de PUR plus sûre et industrialisable à empreinte carbone réduite.
https://phys.org/news/2026-02-sustainable-polyurethane-production-toxic-isocyanate.html
Photodégradation sélective des polyoléfines en mélange avec du polychlorure de vinyle via des transferts d’hydrogène photo-induits
Une étude récente met en lumière une stratégie de recyclage chimique innovante permettant de traiter des flux de déchets plastiques mixtes, traditionnellement incompatibles, grâce à l’exploitation des interactions photochimiques entre polymères. Des chercheurs ont démontré que la présence de polychlorure de vinyle (PVC) au sein de mélanges de polyoléfines, loin d’être un contaminant délétère, peut agir comme un agent promoteur de dégradation sous l’effet d’un rayonnement ultraviolet. Le mécanisme réactionnel repose sur une déshydrochloration photo-induite du PVC, générant des radicaux chlore et des séquences polyéniques qui facilitent l’abstraction d’hydrogène sur les chaînes de polyéthylène ou de polypropylène. Ce transfert d’atomes d’hydrogène déclenche une scission de chaîne efficace, transformant des macromolécules de masse molaire élevée en oligomères valorisables ou en coupes hydrocarbonées liquides. Parallèlement, cette approche permet de contourner les étapes de tri fastidieuses en utilisant la réactivité intrinsèque des additifs ou des impuretés chlorées pour catalyser la décomposition thermique et photochimique du mélange. Cette synergie réactionnelle entre polymères distincts offre une portée technologique considérable pour le recyclage des plastiques de post-consommation, proposant une voie de valorisation énergétique et chimique là où les procédés mécaniques conventionnels échouent en raison de la séparation de phase et de la dégradation des propriétés mécaniques.
Nature Déchiffrer le code des films multicouches pour promouvoir la circularité des emballages plastiques à usage unique
Une étude récente met en lumière la nécessité impérative de repenser l’architecture macromoléculaire des films multicouches (MLF) pour pallier leur incompatibilité structurelle avec les filières de recyclage actuelles. Ces matériaux, essentiels à la conservation alimentaire, tirent leur performance d’une stratification complexe de polymères tels que le PE, le PET et le PA, dont les propriétés barrières sont souvent assurées par des couches de PVDC ou d’EVOH. Or, la nature hétérogène de ces assemblages provoque une séparation de phase lors de la réticulation thermique en recyclage mécanique, entraînant une fragilité interfaciale et une dégradation des propriétés mécaniques. Parallèlement, le traitement par pyrolyse ou dissolution sélective (STRAP) se heurte à des contraintes énergétiques élevées ou à la génération de sous-produits halogénés toxiques. Pour surmonter ces verrous, les chercheurs exploitent désormais l’apprentissage automatique, notamment via l’outil PolyID, afin de prédire des structures polyesters alternatives présentant une densité et une cristallinité optimisées sans compromettre l’étanchéité à l’oxygène ou à l’humidité. Cette approche « recyclable dès la conception » favorise l’émergence de solutions mono-matériaux ou biosourcées. Une telle transition technologique s’avère cruciale pour transformer ces déchets persistants en ressources circulaires, garantissant ainsi la viabilité économique et environnementale des futurs systèmes d’emballage industriels.
EUPOC 2026 – Designing New Polymers by Combining High-Throughput and Artificial Intelligence Tools
Dear Colleagues,
This is to gently remind you about the forthcoming:
EUPOC 2026 – Designing New Polymers by Combining High-Throughput and Artificial Intelligence Tools
Bertinoro (FC), Italy
17-21 May, 2026
https://www.aim.it/eupoc2026
Submission of abstracts is open until next March 15, 2026.
Template of the abstract is available at the link https://www.aim.it/eupoc2026/abstract
If you wish to register to the conference and contribute with a paper, please follow the instructions on the webpage https://www.aim.it/eupoc2026/registration
Acceptance of abstracts will be announced on April 1st, 2026.
Exaltation des propriétés de détection par nanoconfinement macromoléculaire
Une étude récente met en lumière une stratégie d’ingénierie des matériaux visant à surmonter les limitations de sensibilité des capteurs organiques traditionnels en exploitant les phénomènes de confinement spatial. En utilisant des membranes d’oxyde d’aluminium anodique comme matrices templataires rigides, les chercheurs sont parvenus à synthétiser des nanotubes de polymères conducteurs aux dimensions parfaitement contrôlées. Ce procédé d’infiltration force les chaînes macromoléculaires à s’aligner et à cristalliser selon une orientation préférentielle le long de l’axe des nanopores, induisant une anisotropie structurelle qui exalte spectaculairement la mobilité des porteurs de charge et la conductivité électrique par rapport au matériau massif. Cette architecture tubulaire nanométrique ne se contente pas d’optimiser le transport électronique ; elle offre également une surface spécifique accrue pour l’interaction avec les analytes ou les particules incidentes. Cette rupture technologique ouvre des perspectives prometteuses pour la conception de détecteurs de particules de haute performance et de dispositifs de surveillance environnementale ultra-sensibles, capables d’opérer avec une précision et une réactivité inédites dans des dispositifs compacts et flexibles.
CNRS Le journal Lorem ipsum dolor sit amet, consectetur adipiscing elit. Sed posuere tincidunt quam sit amet viverra. Nam in consequat nulla. Nunc rhoncus orci vitae arcu sagittis, in auctor nibh posuere. Donec ut nulla id enim tempor feugiat.
Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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Waters_logo_stacked_K_web-NEW
http://www.waters.com
LPMC
http://www.ispa.asso.fr
lrccp
http://www.ispa.asso.fr
cnrs
http://www.ispa.asso.fr
ICS
https://www-ics.u-strasbg.fr/
hutchinson
http://www.hutchinson.com/fr
arkema
http://www.coatex.com
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
Logo-ChemSuD
http://www.ispa.asso.fr
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