Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Interactions coopératives intermoléculaires : régulation de l’assemblage des polymères supramoléculaires
Des chercheurs de l’Université de Chiba, dirigés par le Dr Hiroki Hanayama et le professeur Shiki Yagai, ont mis en évidence un mécanisme de « coopérativité d’ordre supérieur » régissant l’auto-assemblage de polymères supramoléculaires courbés. Leurs travaux, publiés dans le Journal of the American Chemical Society, démontrent comment la croissance hélicoïdale de ces structures induit des interactions intermoléculaires spécifiques qui stabilisent l’assemblage et guident sa formation. Contrairement aux modèles classiques de polymérisation, ce processus est piloté par une transition structurelle sensible à la température, où la formation initiale d’un motif en hélice facilite l’ajout ultérieur de monomères, garantissant ainsi une organisation précise à l’échelle nanométrique. Cette découverte offre de nouvelles clés pour contrôler la synthèse de matériaux supramoléculaires complexes, ouvrant la voie à des applications potentielles dans le développement de nanomatériaux fonctionnels adaptatifs et de systèmes moléculaires avancés.
https://phys.org/news/2025-12-cooperative-intermolecular-interactions-supramolecular-polymer.html
Adhésifs intelligents photo-commutables : une alternative biosourcée à haute performance
Des chercheurs de l’Université nationale de Jeonbuk ont mis au point un adhésif intelligent photo-commutable et respectueux de l’environnement, synthétisé majoritairement à partir de dérivés de biomasse naturelle tels que l’huile de rose. Cette innovation repose sur la copolymérisation de méthacrylates de tétrahydrogéraniol avec des motifs azobenzènes fonctionnels, créant une architecture macromoléculaire capable de transitions de phase réversibles sous stimulation lumineuse. Le mécanisme clé réside dans la liquéfaction du matériau sous rayonnement ultraviolet, entraînant une perte d’adhésion significative, suivie d’une resolidification sous lumière visible qui restaure les propriétés adhésives initiales sans dégradation. Outre cette photo-sensibilité, le polymère démontre une robustesse mécanique élevée sur une vaste gamme de substrats (métaux, plastiques, verre) tout en étant sensible à la chaleur et aux traitements chimiques, offrant ainsi une polyvalence de désassemblage inédite. Par conséquent, cette technologie de rupture, qui s’affranchit des ressources pétrochimiques conventionnelles, ouvre des perspectives industrielles prometteuses pour le recyclage simplifié, l’assemblage temporaire de dispositifs électroniques et la conception de capteurs optiques avancés.
https://phys.org/news/2025-12-eco-friendly-photo-switchable-smart.html
Deux percées en recyclage chimique : la valorisation douce du polystyrène et du polyéthylène
Des recherches fondamentales ont abouti à deux méthodes novatrices pour transformer chimiquement le polystyrène (PS) et le polyéthylène (PE), deux des plastiques les plus abondants et les plus résistants à la dégradation, marquant un changement de paradigme vers une circularité plus efficace. D’une part, des scientifiques ont réussi à dépolymériser enzymatiquement le polystyrène en le formulant sous forme de nanoparticules stables dans l’eau, rendant la chaîne polymère accessible à des enzymes fongiques, qui la fragmentent ensuite en molécules à haute valeur ajoutée telles que l’acide benzoïque ou le benzaldéhyde. D’autre part, une équipe distincte a développé un procédé doux, sans catalyseur métallique et activé par la lumière visible ou la chaleur (compatible avec l’extrusion industrielle), pour fonctionnaliser le polyéthylène en le greffant de groupes chimiques (oximes ou cétones) à l’aide d’un simple oxydant, le nitrite de tertio-butyle. Cette modification crée des « points d’entrée » sur la chaîne du PE, permettant de moduler ses propriétés ou de le rendre plus facilement transformable et recyclable. Ces deux approches illustrent le potentiel du recyclage chimique pour transformer les déchets plastiques en produits économiques et écologiques .
Validation d’un procédé de recyclage innovant pour le PEHD de grade alimentaire
Une initiative industrielle majeure a été lancée pour évaluer un procédé breveté à base de solvants, conçu pour produire du polyéthylène haute densité recyclé (rPEHD) compatible avec le contact alimentaire. Contrairement au recyclage mécanique conventionnel, cette technologie de purification avancée vise à éliminer efficacement les contaminants et les odeurs persistantes qui limitent actuellement l’utilisation du rPEHD dans les emballages alimentaires sensibles. Le projet pilote, mené en collaboration avec un institut technologique indépendant, se concentre sur la validation des étapes de nettoyage et de traitement pour garantir que le matériau final respecte les normes strictes de sécurité sanitaire, dans l’optique d’obtenir l’approbation des autorités de sécurité alimentaire européennes. Si elle est validée à l’échelle industrielle, cette innovation pourrait combler une lacune critique sur le marché en permettant la production massive d’emballages alimentaires en rPEHD, soutenant ainsi la conformité aux futures réglementations sur le contenu recyclé et favorisant une économie circulaire pour les polyoléfines.
USA : Signes de reprise dans l’industrie manufacturière des plastiques
Une analyse récente des indicateurs macroéconomiques met en lumière un début de résilience au sein du secteur manufacturier des plastiques nord-américain, marquant un tournant après une contraction liée aux taux d’intérêt élevés. Cette reprise naissante est soutenue par un ajustement favorable de la politique monétaire fédérale, qui réduit le coût du capital et favorise un rebond des indices de production ainsi qu’une meilleure utilisation des capacités industrielles. Sur le plan commercial, une dichotomie structurelle persiste : si les matériaux de base comme le polyéthylène génèrent un excédent substantiel, les segments des produits finis et des biens d’équipement enregistrent un déficit chronique, influencé par une forte pénétration des importations asiatiques. Parallèlement, la modération des coûts énergétiques et des matières premières a permis de contenir l’inflation des prix à la production, offrant un répit aux marges des transformateurs malgré les frictions tarifaires sur certains intrants. En conséquence, la convergence d’une demande soutenue et d’un environnement fiscal et monétaire plus accommodant dessine une trajectoire potentiellement expansionniste pour la filière, bien que la vigilance reste de mise face aux aléas exogènes pouvant affecter les chaînes d’approvisionnement mondiales.
Polyuréthanes fluorés supramoléculaires : vers une électronique flexible pour environnements polaires
Une nouvelle approche permet de concevoir des capteurs ioniques résilients capables de surmonter les défaillances classiques en milieux extrêmes grâce à l’ingénierie moléculaire de polyuréthanes supramoléculaires fluorés. En intégrant des segments riches en fluor et des liquides ioniques au sein d’une matrice polymère structurée par des liaisons hydrogène multiples, cette étude établit un réseau dynamique synergique où les interactions électrostatiques dipôle-fluor confinent sélectivement les cations tout en libérant les anions pour former des « autoroutes » conductrices. Cette architecture unique confère au matériau une robustesse exceptionnelle, combinant une conductivité ionique maintenue même sous des conditions thermiques cryogéniques, une capacité d’autoréparation rapide et une mémoire de forme thermique programmable. Parallèlement, le polymère présente des propriétés d’amortissement remarquables et une réponse électrique ultrasensible aux variations de température et de déformation mécanique, garantissant une fidélité de signal de grade médical pour la surveillance physiologique complexe comme l’électrocardiogramme. En conséquence, cette innovation ouvre des perspectives prometteuses pour le développement de dispositifs portables « polaires » et d’interfaces homme-machine avancées, capables de fonctionner durablement dans des environnements hostiles sans compromis entre élasticité, conductivité et stabilité structurelle.
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.
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Les partenaires
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Waters_logo_stacked_K_web-NEW
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ICS
https://www-ics.u-strasbg.fr/
cnrs
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arkema
http://www.coatex.com
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http://www.hutchinson.com/fr
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