Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
De la bière sumérienne au milkshake moderne : la saga polymère de la paille
Née il y a des millénaires, la paille connaît son essor au XIXe siècle avec l’invention du modèle en papier par Marvin Stone. Mais c’est dans les années 1930 que la flexibilité s’invite, grâce au génie de Joseph Friedman et à l’ingénierie du papier strié. Cette avancée sera d’abord adoptée dans les hôpitaux avant de conquérir les fast-foods. Dans les années 1960, le plastique supplantera rapidement le papier : le polypropylène et le polystyrène permettent alors des pailles bon marché, rigides ou flexibles, incassables, moulées en masse avec précision. Cette migration vers les polymères thermoplastiques incarne la transition vers une culture jetable mais accessible, où l’extrusion et le moulage par injection façonnent des milliards de pailles chaque jour. À l’heure des remises en question environnementales, la paille plastique devient aussi symbole du défi de la circularité des polymères.
https://www.plasticstoday.com/extrusion-pipe-profile/a-brief-history-of-the-drinking-straw
Le téléphone Bakélite : premier chef-d’œuvre plastique et tournant industriel
Dans les années 1930, le téléphone en bakélite marque un jalon dans l’histoire des polymères. Ce plastique thermodurcissable, entièrement synthétique et mis au point en 1907, permet enfin une fabrication rapide, reproductible et sûre de pièces complexes. Résistant à la chaleur et isolant, il remplace avantageusement le métal dans les boîtiers de téléphones, abaissant le temps de production de plusieurs jours à quelques minutes. Sa mise en forme par moulage ouvre la voie au design moderne et à la production de masse, inaugurant l’ère des plastiques utilitaires et esthétiques.
Recyclage chimique de pneus usagés en cycloalcènes pour caoutchouc et nylon
Des chercheurs de KAIST ont mis au point une méthode catalytique double permettant de recycler les pneus usagés en cycloalcènes à haute pureté, comme le cyclopentène et le cyclohexène, à des rendements et sélectivités élevés. Cette approche surmonte les difficultés liées à la vulcanisation des caoutchoucs en déstructurant les réticulations par catalyse douce, contrairement à la pyrolyse classique. Les produits obtenus sont des précurseurs industriels pour les fibres de nylon et les élastomères, ouvrant la voie à un recyclage chimique efficace et circulaire des polymères complexes.
Transformer le CO₂ en plastique grâce à l’électricité verte
Des chercheurs du Caltech ont mis au point un procédé en deux étapes capable de convertir du dioxyde de carbone, de l’eau et de l’électricité en polymères industriels. La première étape électrochimique transforme le CO₂ en monomères comme l’éthylène et le CO, puis une catalyse homogène les copolymérise. L’innovation réside dans l’intégration des deux boucles réactionnelles, malgré la présence d’impuretés issues de la réduction du CO₂, et ouvre la voie à des polymères durables produits sans hydrocarbures.
https://phys.org/news/2025-06-plastic-carbon-dioxide-electricity.html
Vers un recyclage enzymatique industriel du PET à coût compétitif
Une nouvelle étude multidisciplinaire montre que le recyclage enzymatique du PET pourrait devenir économiquement viable à l’échelle industrielle. En optimisant la déconstruction enzymatique et la récupération des monomères, les chercheurs réduisent de 74 % les coûts de fonctionnement annuels et de 65 % la consommation énergétique. Le PET recyclé enzymatiquement est désormais moins cher que le PET vierge aux États-Unis, ouvrant une voie réaliste pour valoriser les plastiques post-consommation difficiles à traiter.
https://phys.org/news/2025-06-enzyme-based-plastics-recycling-industrial.html
La structure du MAO enfin élucidée après 40 ans de mystère en catalyse des polyoléfines
Une équipe franco-américaine révèle la structure fine du méthylaluminoxane (MAO), co-catalyseur central dans la polymérisation des polyoléfines. Grâce à la RMN 27Al à très haut champ (1,2 GHz) couplée à la modélisation DFT, cinq types de centres d’aluminium ont été identifiés dans le MAO solide, dont deux très réactifs, impliqués dans l’activation des catalyseurs à base de zirconium. L’étude met en évidence la formation de cations [AlMe₂]+ et des échanges de groupes méthyle, validant des hypothèses longtemps spéculées. Cette percée ouvre la voie à la conception de co-catalyseurs optimisés pour une production de polyéthylène et polypropylène plus économe en énergie.
https://www.inc.cnrs.fr/fr/cnrsinfo/un-ingredient-cle-de-la-chimie-industrielle-des-polyolefines-enfin-compris
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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