Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Nanocomposites polymères à relaxation améliorée par boucles polymériques liées aux nanoparticules
Cette étude propose une approche interfaciale innovante pour dépasser le compromis entre fluidité et résistance dans les nanocomposites polymères. En remplaçant la couche adsorbée rigide formée à la surface des nanoparticules par une couche de grandes boucles polymériques liées, les chercheurs conçoivent un réseau particulaire plus mobile et moins contraint. Ces boucles, issues d’un copolymère statistique P(styrène-ran-4-hydroxystyrene), favorisent la relaxation des chaînes de matrice, maintiennent un comportement rhéologique fluide et empêchent la formation de réseaux permanents limitant la mise en œuvre. Les composites ainsi obtenus présentent une viscosité réduite tout en conservant une forte cohésion interfaciale et une dissipation d’énergie accrue. Les enchevêtrements topologiques entre boucles et chaînes de matrice renforcent la résistance et la ténacité à l’état vitreux. Cette stratégie, fondée sur le contrôle dynamique des interfaces plutôt que sur la modification chimique, ouvre la voie à des nanocomposites à haute charge combinant processabilité et performances mécaniques élevées.
Nature Production autonome de propylène oxyde : un système catalytique sans énergie externe révolutionne la chimie des polymères
Des chercheurs de l’Université nationale des sciences et technologies d’Ulsan (UNIST) ont mis au point un système catalytique autoalimenté capable de produire du propylène oxyde (PO) — un intermédiaire clé pour les polyuréthanes, polyesters et plastiques techniques — sans recourir à l’électricité ni à la lumière solaire. Publiée dans Nature Communications, cette avancée repose sur la génération in situ de peroxyde d’hydrogène (H₂O₂) via une réaction électrochimique spontanée entre l’oxygène et le formaldéhyde, exploitant uniquement la différence de potentiel chimique entre les demi-réactions. Le H₂O₂ ainsi formé oxyde directement le propylène en PO au sein du même dispositif. L’équipe a repensé la structure du catalyseur, surpassant les limites des zéolithes TS-1 traditionnelles dont l’activité chute en milieu alcalin, condition pourtant nécessaire à la formation de H₂O₂. Ce design innovant améliore considérablement le rendement de l’époxydation, atteignant des performances huit fois supérieures aux procédés écologiques précédents. Outre une réduction de 8 % des coûts de production et l’absence d’équipement sous pression ou à haute température, le procédé produit également de l’hydrogène comme co-produit énergétique. Compact, modulable et décentralisable, ce système marque un tournant vers une chimie du propylène plus durable, conciliant efficacité énergétique, économie circulaire et autonomie des sites de production.
https://phys.org/news/2025-11-key-plastic-ingredient-house-generated.html
Analyse dynamique-mécanique des mousses polymères pour la conception de systèmes résistants aux impacts
Cette étude évalue le potentiel de l’analyse mécanique thermique dynamique (DMTA) comme outil complémentaire pour caractériser les mousses polymères destinées aux systèmes de protection contre les chocs. Trois familles de mousses commerciales – polyoléfine, polyuréthane et caoutchouc – ont été examinées selon trois modes expérimentaux : variation d’amplitude, de fréquence et de température. Ces essais permettent de simuler respectivement la déformation sous impact, le comportement à faible ou haute sollicitation et les conditions thermiques d’usage. Les résultats montrent que la tangente de l’angle de perte, rapport des modules de perte et de stockage, corrèle qualitativement avec la résistance à l’impact : les mousses plus visqueuses dissipent mieux l’énergie mais se déforment davantage, tandis que les plus élastiques résistent mieux à la rupture. La DMTA met ainsi en évidence la nécessité d’un équilibre entre contributions élastique (E′) et visqueuse (E″) pour concilier stabilité dimensionnelle et capacité d’amortissement. L’analyse révèle également que la microstructure cellulaire et la température influencent fortement la réponse viscoélastique, orientant le choix des mousses selon l’environnement et la fréquence des sollicitations. Bien que la corrélation quantitative avec les essais d’impact ou de compression reste limitée, cette approche fournit une compréhension mécanistique fine et propose la DMTA comme méthode de présélection efficace pour la conception de matériaux absorbant les chocs dans les équipements de protection, le sport ou la sécurité automobile.
Nature Sculpter la matière de l’intérieur : une méthode transforme les plastiques ordinaires en matériaux poreux avancés
Des chimistes de l’Université de Floride ont mis au point une approche inédite pour créer des matériaux hautement poreux à partir des blocs de construction des plastiques courants, tels que le plexiglas et le polystyrène. Publiée dans ACS Central Science, cette méthode dite d’« addition par soustraction » exploite la différence de température de dégradation entre deux polymères incompatibles pour façonner la matière de l’intérieur. En chauffant le mélange à une température où les segments de type plexiglas s’évaporent tandis que la matrice de polystyrène demeure stable, les chercheurs obtiennent un réseau dense de nanopores dont la taille est inférieure à celle d’un virus. Un seul gramme de ce matériau présente une surface interne équivalente à celle d’un court de tennis, conférant des propriétés exceptionnelles pour la filtration, les séparations chimiques et la fabrication de membranes pour batteries. Cette porosité contrôlée, obtenue sans solvants ni agents gonflants, pourrait également être ajustée pour les applications électroniques et de stockage magnétique à haute densité. Inspirée des travaux du groupe Sumerlin sur la dépolymérisation et le recyclage des plastiques, cette technique illustre comment une compréhension fine des cinétiques thermiques de dégradation peut conduire à la création de matériaux fonctionnels, durables et issus de polymères existants — une approche qui relie ingénieusement chimie des plastiques et ingénierie des matériaux de nouvelle génération.
https://phys.org/news/2025-11-sculpting-technique-advanced-materials-basic.html
SynPet Technologies mise 300 millions d’euros sur le recyclage chimique des plastiques à Anvers-Bruges
Alors que plusieurs projets européens de recyclage avancé ont récemment été suspendus, l’entreprise belgo-turque SynPet Technologies relance la dynamique avec un investissement de 300 millions d’euros dans une unité de recyclage chimique sur le port d’Anvers-Bruges, l’un des pôles industriels majeurs de la pétrochimie européenne. Prévue pour entrer en service au second semestre 2028, l’usine exploitera le Thermal Conversion Process (TCP), une technologie propriétaire capable de convertir des déchets plastiques mixtes en matières premières circulaires utilisables par l’industrie chimique. Ce procédé thermique, sans incinération, vise à produire des hydrocarbures légers et des gaz de synthèse tout en limitant les émissions résiduelles, se distinguant des approches classiques de pyrolyse. Par cette implantation stratégique au cœur d’un hub logistique et énergétique, SynPet entend créer un écosystème industriel fermé, reliant collecte, valorisation et production de polymères circulaires. Le projet s’inscrit dans le mouvement de relocalisation des capacités européennes de recyclage avancé, à un moment où la réglementation européenne sur les plastiques impose une part croissante de contenu recyclé. En misant sur la stabilité technologique et la proximité des infrastructures chimiques, SynPet ambitionne de démontrer la viabilité industrielle du recyclage chimique à grande échelle, ouvrant une nouvelle voie vers la neutralité carbone du secteur des plastiques.
L’Usine Nouvelle Composite polymère biodégradable PLA/Henné pour l’optimisation des fluides de forage : amélioration de la rhéologie et de la filtration
Cette étude présente un additif polymérique innovant associant l’acide polylactique (PLA) et la poudre de henné pour améliorer les propriétés des fluides de forage à base d’eau. Le composite, obtenu par extrusion et caractérisé par SEM, EDS et FTIR, montre une dispersion homogène des particules de henné dans la matrice de PLA et une compatibilité interfaciale élevée, favorisant la formation de réseaux structuraux dans le fluide. Les essais rhéologiques confirment un comportement pseudoplastique typique des fluides à seuil, bien décrit par le modèle de Bingham, avec une augmentation notable de la viscosité plastique et du point de rendement jusqu’à 2 % massique de composite, seuil optimal avant saturation des effets. Cette concentration renforce la stabilité en suspension et la portance des déblais tout en limitant la sédimentation. Les tests de filtration à basse et haute pression-température révèlent une diminution significative du volume filtré et de la perte initiale, attribuée à la formation d’un gâteau filtrant fin et dense, où les groupements hydroxyles du henné interagissent par liaisons hydrogène avec les phases aqueuses et polymériques. L’association PLA/Henna agit ainsi comme agent de pontage et de colmatage des pores, améliorant la compacité et la cohésion du dépôt. Biodégradable, stable et compatible avec les formulations existantes, ce composite constitue une alternative durable aux additifs synthétiques, conciliant performance rhéologique, contrôle de la filtration et réduction de l’empreinte environnementale dans les opérations de forage pétrolier et gazier.
Nature Lorem ipsum dolor sit amet, consectetur adipiscing elit. Sed posuere tincidunt quam sit amet viverra. Nam in consequat nulla. Nunc rhoncus orci vitae arcu sagittis, in auctor nibh posuere. Donec ut nulla id enim tempor feugiat.
Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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Waters_logo_stacked_K_web-NEW
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ICS
https://www-ics.u-strasbg.fr/
arkema
http://www.coatex.com
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lrccp
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http://www.hutchinson.com/fr
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http://www.ispa.asso.fr
cnrs
http://www.ispa.asso.fr
LPMC
http://www.ispa.asso.fr
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