Le réseau

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L'organisation

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La structure de veille et de réflexion prospective

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Actualités

 

Chiralité supramoléculaire comme levier pour améliorer la conductivité des polymères dopés

Des chercheurs ont montré qu’en modulant la chiralité supramoléculaire de polymères conjugués — autrement dit l’organisation hélicoïdale des chaînes à l’échelle supramoléculaire — on peut augmenter de façon significative l’efficacité du dopage chimique et améliorer la conductivité des films obtenus. Le procédé repose sur un soin apporté à la mise en solution et au dépôt : en modifiant subtilement la nature du solvant, les chaînes polymères, initialement achirales, s’auto-assemblent en phases mésomorphes hélicoïdales dont la « torsion » est conservée lors de la solidification. Après dopage, ces films à forte chiralité présentent une densité de porteurs de charge plus élevée qu’un même polymère non chiralisé, ce qui suggère que l’architecture hélicoïdale favorise l’oxydation et la génération de porteurs. Ce résultat renverse l’hypothèse selon laquelle la chiralité coutumière limite la mobilité de charge, et ouvre une nouvelle dimension dans la conception des semi-conducteurs organiques : l’agencement supramoléculaire devient un paramètre clé pour optimiser le transport électronique, ouvrant des perspectives pour l’électronique organique, les capteurs ou les électrodes flexibles.

https://phys.org/news/2025-11-chirality-polymers-doping.html

U.S. Environmental Protection Agency (EPA) propose d’ajuster les obligations de déclaration concernant les PFAS sous le Toxic Substances Control Act (TSCA) : un assouplissement encadré pour l’industrie chimique

L’EPA a soumis une proposition de modification de sa règle 2023 de déclaration unique des substances PFAS, en visant à alléger les contraintes pour les fabricants et importateurs tout en maintenant l’acquisition d’informations critiques sur l’usage et les risques. Le nouveau projet prévoit une série d’exemptions : PFAS présents en faibles concentrations (≤ 0,1 %) dans des mélanges ou des articles, PFAS importés sous forme d’objets finis, sous-produits ou impuretés, intermédiaires non isolés, et substances à usage exclusif de recherche-développement. Par ailleurs, des corrections techniques et un ajustement du calendrier de soumission — fenêtre réduite de trois mois, déclenchée 60 jours après la finalisation — sont proposés pour rendre l’obligation plus réaliste et moins lourde administrativement. Ces changements visent prioritairement à réduire le fardeau réglementaire pesant sur les petites structures, à éviter des déclarations redondantes, et à recentrer les efforts d’analyse sur les cas présentant les enjeux de santé et d’environnement les plus pertinents.

https://www.specialchem.com/plastics/news/epa-proposes-to-improve-scope-of-pfas-reporting-regulations-under-tsca

ExxonMobil, Milliken et Ravago : des composés PP recyclés prêts pour l’automobile

Des chercheurs et industriels ont récemment démontré qu’il est possible de formuler des composés à base de polypropylène recyclé (rPP) combinés à des modificateurs de performance et des élastomères polyoléfiniques, tout en atteignant des performances comparables à celles des résines vierges pour des applications automobiles exigeantes. Le procédé s’appuie sur l’ajout de plastomères et d’additifs optimisés pour améliorer l’adhésion des chaînes, homogénéiser la matrice, et corriger les défauts structurels typiques des rPP — fragilité, variabilité de composition, et mauvaises propriétés mécaniques. Le matériau résultant possède un bon équilibre entre rigidité, résistance aux chocs, comportement mécanique acceptable à différentes températures, et un débit de fusion compatible avec des cycles de moulage par injection rapides. Ces avancées ouvrent la voie à l’usage de rPP dans des pièces automobiles critiques comme les passages de roue ou les déflecteurs avant : c’est un exemple concret de circularité industrielle, combinant performance, économie de ressources et réduction de dépendance aux polymères vierges.

https://www.plasticstoday.com/automotive-mobility/exxonmobil-collaborates-on-recycled-content-pp-compounds

Renaissance des matériaux bio- et géo-sourcés : mobilisation de la région Hauts-de-France pour textiles, bois, cellulose moulée et plastiques renouvelables

Des acteurs de la région Hauts-de-France ont lancé une initiative régionale visant à accompagner les transformateurs dans le développement de matériaux bio-, géo- ou recyclo-sourcés — incluant textiles durables, fibres bois-cellulose, polymères issus de ressources renouvelables ou matériaux composites bois-plastique. L’objectif est de structurer une filière locale capable de substituer progressivement les matériaux fossiles traditionnels par des solutions plus écologiques, tout en maintenant des performances adaptées aux exigences industrielles. Au cœur de cette démarche, on promeut des processus de transformation compatibles avec les ressources régionales — valorisation de la biomasse locale, utilisation de cellulose moulée ou de bois de première ou seconde transformation, et développement de plastiques à base de ressources végétales. Le dispositif prévoit un soutien technique et industriel aux transformateurs : développement de prototypes, mise en place de filières de production, accompagnement au passage à l’échelle, et partage de bonnes pratiques. Cette stratégie fédère des acteurs variés — industrie, recherche, collectivités — et vise à créer une offre compétitive et durable de matériaux de nouvelle génération, favorisant l’économie circulaire, la réduction de l’empreinte carbone et la souveraineté locale en matière de ressources. L’initiative illustre une ambition de transition systémique vers des matériaux plus durables, adaptatifs aux contraintes industrielles actuelles, tout en stimulant l’innovation régionale.

Matériau polymère auto-réparable et électroluminescent : vers des élastomères souples multifonctionnels

Des chercheurs ont mis au point un copolymère à base d’isoprène et de 1-vinylnaphtalène combinant souplesse, auto-guérison à température ambiante et émission lumineuse élevée, ouvrant la voie à des élastomères opto-électroniques innovants. En dispersant des micro-domaines naphtalène au sein d’une matrice cis-1,4-polyisoprène flexible, l’architecture crée une microséparation à l’échelle nanométrique qui contraint les groupements aromatiques, favorisant la formation d’« excimers » stables sous excitation UV. Ce concept de « polymère-constrained excimer » confère au matériau une photoluminescence efficace et intense à l’état solide, tout en maintenant une bonne élasticité et une capacité de réparation intrinsèque sans sollicitation externe. Par ailleurs, ces nanodomaines aromatiques assurent un comportement d’électret — c’est-à-dire la capacité à piéger des charges électriques après sollicitation mécanique — prolongeant la fonctionnalité du matériau bien au-delà de la simple émission lumineuse. L’ensemble de ces propriétés — flexibilité, auto-réparation, luminescence et rétention de charge — suggère des applications prometteuses dans l’électronique souple, les capteurs tactiles ou les interfaces robotiques, et témoigne de l’intérêt d’ingénieries macromoléculaires fines pour concevoir des polymères multifonctionnels adaptés aux technologies portables et adaptatives.

Conformational pre-organisation des groupes voisins : vers des plastiques programmables capables de s’auto-désintégrer

Des chercheurs ont démontré qu’il est possible de concevoir des polymères synthétiques dont la déconstruction — la rupture des liaisons dans le polymère — peut être programmée et régulée par la seule architecture conformationnelle de la chaîne, sans modifier la nature chimique des liaisons fragiles. L’idée clé repose sur un « pré-arrangement conformationnel » des groupes nucléophiles voisins d’une liaison susceptible de se rompre : en ajustant spatialement ces groupes, le polymère adopte préférentiellement des géométries réactives, ce qui accélère la scission de la liaison lorsque les conditions le permettent. Cette stratégie s’applique aussi bien à des polymères linéaires qu’à des réseaux thermodurcissables en masse, ouvrant la possibilité de matériaux recyclables ou biodégradables qui conservent leurs propriétés mécaniques tant qu’ils restent intacts. Par ailleurs, les auteurs montrent qu’à l’aide de repliements induits par des ions métalliques — modifiant la conformation globale — la déconstruction peut être activée ou inhibée de manière réversible, offrant un contrôle dynamique de la durée de vie du matériau. Ce mécanisme, inspiré des comportements de dégradation des macromolécules naturelles, esquisse un paradigme nouveau : concevoir des plastiques dont la robustesse et la durée de vie sont planifiables, tout en assurant, à terme, une rupture maîtrisée. Au-delà de l’innovation conceptuelle, cette approche pourrait bouleverser la conception de polymères durables, recyclables ou biodégradables, et orienter la fabrication vers des matériaux « vivants » dont la fin de vie serait intégrée dès la phase de conception.

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Adhérez au GFP

Devenez un membre et découvrez les avantages d’un abonnement GFP.

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Sections locales GFP

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