Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Valorisation mécanochimique du PVC comme agent de chloration solide
Une étude récente réinvente le paradigme de fin de vie du poly(chlorure de vinyle) (PVC) en exploitant sa charge halogénée via une voie mécanochimique sans solvant pour la fonctionnalisation d’alcools. Au lieu de subir une dégradation thermique énergivore souvent émettrice de composés volatils toxiques, la matrice polymère est ici activée par un broyage à billes à haute énergie, induisant une activation tribochimique des liaisons carbone-chlore sous contrainte de cisaillement intense. Ce procédé permet au PVC usagé d’agir comme un donneur de chlore stœchiométrique, convertissant efficacement une large gamme d’alcools primaires et secondaires en leurs chlorures d’alkyle correspondants par substitution nucléophile, tandis que le squelette macromoléculaire résiduel évolue vers une structure polyénique conjuguée stable et inerte. En s’affranchissant des agents de chloration traditionnels corrosifs et dangereux, cette stratégie d’économie circulaire transforme un déchet plastique problématique en un réactif de synthèse précieux, offrant ainsi une voie durable pour la production de briques élémentaires destinées à la chimie fine et pharmaceutique.
Synthèse de polymères à empreinte moléculaire magnétique pour la dépollution
Des chercheurs ont élaboré une architecture composite hybride destinée à l’extraction sélective de contaminants pharmaceutiques, ciblant spécifiquement le dexaméthasone persistant dans les écosystèmes fluviaux. Cette approche novatrice repose sur la synthèse de polymères à empreinte moléculaire (MIP) greffés à la surface de nanoparticules magnétiques, créant ainsi une structure cœur-coquille fonctionnelle. Le procédé de fabrication implique la polymérisation d’un réseau tridimensionnel autour de la molécule cible agissant comme gabarit ; une fois ce gabarit extrait, le matériau conserve des cavités stériques et chimiques agissant comme des sites de reconnaissance hautement spécifiques, analogues au mécanisme clé-serrure des enzymes. Contrairement aux adsorbants classiques non sélectifs, ce matériau démontre une affinité supérieure pour le corticoïde visé, même en présence d’interférents structurellement proches, tout en permettant une récupération aisée et rapide de la phase solide via un champ magnétique externe. Cette combinaison de sélectivité chimique et de maniabilité physique ouvre des perspectives prometteuses pour le traitement tertiaire des eaux et la remédiation environnementale des micropolluants émergents.
Nature Cadre réglementaire européen et réorientation des architectures macromoléculaires vers la circularité
Une série de mesures stratégiques récemment dévoilées par la Commission européenne redéfinit les paradigmes de conception des matériaux polymères en imposant une approche systémique de la circularité dès la phase de formulation. L’initiative législative, centrée sur le règlement relatif à l’écoconception, contraint les ingénieurs matériaux à revoir l’architecture macromoléculaire des thermoplastiques pour garantir une recyclabilité intrinsèque, privilégiant l’homogénéité chimique et la minimisation des additifs susceptibles de perturber la rhéologie des flux recyclés. Parallèlement, une clarification rigoureuse est apportée concernant les matrices biosourcées et biodégradables : l’usage de ces polymères n’est plus validé par leur seule origine renouvelable, mais doit répondre à des critères physico-chimiques stricts de minéralisation totale dans des environnements définis, réservant leur application aux cas où la séparation des contaminants organiques est techniquement complexe. L’introduction concomitante d’un passeport numérique des produits impose une traçabilité compositionnelle inédite, liant les propriétés mécaniques finales à l’historique de synthèse et de transformation. En structurant ainsi la chaîne de valeur, ce cadre normatif vise à substituer massivement les résines vierges fossiles par des matières premières secondaires de haute pureté, catalysant une transition industrielle majeure vers des filières de valorisation matière pérennes et économiquement viables.
Ingénierie de la sous-surface pour des catalyseurs métalliques haute performance
Une nouvelle approche permet de surmonter le compromis habituel entre activité et stabilité dans les matériaux catalytiques en ciblant l’architecture atomique située juste sous la couche externe. Alors que les stratégies conventionnelles modifient directement la surface réactionnelle, ce qui tend souvent à fragiliser l’édifice cristallin, cette méthode innovante utilise la diffusion contrôlée d’atomes pour réorganiser la structure interne du matériau sans altérer sa topologie de surface. Ce remaniement en profondeur induit une modification favorable de l’environnement électronique des sites actifs exposés, optimisant ainsi leur capacité à interagir avec les molécules cibles tout en bénéficiant de la robustesse mécanique du réseau sous-jacent. En découplant les propriétés de surface de celles du cœur du matériau, les auteurs démontrent qu’il est possible de maintenir une réactivité chimique intense sans provoquer la dégradation prématurée du catalyseur. Cette avancée conceptuelle offre une feuille de route prometteuse pour le développement d’électrocatalyseurs durables, essentiels à la viabilité économique des futures technologies de conversion d’énergie propre.
Matériaux adaptatifs à transition viscoélastique réversible pour la protection biomécanique
Des chercheurs ont élaboré une nouvelle classe d’élastomères intelligents capables de moduler instantanément leur rigidité en réponse à une contrainte mécanique, tout en préservant une interaction physiologique optimale avec les tissus humains. L’architecture macromoléculaire repose sur l’intégration de réseaux supramoléculaires dynamiques au sein d’une matrice polymère souple ; ces liaisons physiques labiles autorisent une grande mobilité des chaînes à l’état de repos, conférant au matériau une compliance élevée et un toucher soyeux. Toutefois, lors d’un impact cinétique soudain, le système subit une transition de phase ultra-rapide caractérisée par le verrouillage transitoire des nœuds de réticulation et une augmentation exponentielle du module de stockage, permettant une dissipation efficace de l’énergie de choc par hystérésis visqueuse. Contrairement aux fluides épaississants traditionnels souvent difficiles à encapsuler, cette formulation solide mais flexible intègre des motifs hydrophiles garantissant la perméabilité à la vapeur d’eau et l’absence de cytotoxicité cutanée. Cette synergie entre protection balistique réactive et ergonomie biomimétique offre des débouchés majeurs pour la conception d’équipements de protection individuelle (EPI) invisibles, de textiles sportifs de haute performance et de dispositifs orthopédiques actifs prévenant les traumatismes articulaires sans entraver la liberté de mouvement.
https://phys.org/news/2026-01-smart-polymers-harden-demand-gentle.html
Le concours CNRS est ouvert
Le concours CNRS est ouvert : 🙂
https://carrieres.cnrs.fr/concours-externes-des-chercheurs-h-f/
L’inscription aux concours externes des chercheurs (H/F) ouvre le 12 décembre 2025.
Date limite de candidature : 12/01/2026 à 13:00 – heure de Paris
Faites circuler l’information dans vos réseaux.
Et faites aussi la promotion du nouveau site web de la section 13 (merci Emilie Secret et Isabelle Borsenberger!) : 😉
https://section13conrs.wixsite.com/section13conrs
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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LPMC
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
Logo-ChemSuD
http://www.ispa.asso.fr
lrccp
http://www.ispa.asso.fr
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
arkema
http://www.coatex.com
hutchinson
http://www.hutchinson.com/fr
cnrs
http://www.ispa.asso.fr
ICS
https://www-ics.u-strasbg.fr/
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