Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
JEPO 2026 – Prolongation des inscriptions jusqu’au 15 septembre
Il reste encore des places disponibles pour participer aux JEPO 2026.
Afin de permettre à davantage de participants de rejoindre l’événement, la date limite de dépôt a été repoussée au 15 septembre 2026.
Les personnes intéressées sont invitées à consulter le site de l’événement pour retrouver toutes les informations pratiques et les modalités de participation.
Date limite : 15 septembre 2026
Site de l’événement :
https://jepo2026.sciencesconf.org/
ACS Spring 2027 – Appel à communications sur les matériaux renouvelables
L’American Chemical Society Spring 2027 se tiendra du 21 au 25 mars 2027 à La Nouvelle-Orléans (Louisiane, États-Unis).
À cette occasion, les divisions Polymer Chemistry (POLY) et Cellulose and Renewable Materials (CELL) de l’ACS organisent conjointement le symposium :
“Advances in Renewable Materials: Functional Macromolecular Architectures from Renewable Feedstocks”
L’appel à communications est actuellement ouvert, avec une date limite de soumission des résumés fixée au 28 septembre 2026. lire plus…
Une nanostructure de PVDF refroidit passivement les surfaces exposées au soleil
Une équipe du CSIC en Espagne a développé une architecture tridimensionnelle de PVDF capable de combiner forte réflexion solaire et émission infrarouge, avec une diminution de température pouvant atteindre 12,9 °C lors d’essais en extérieur.
Le refroidissement radiatif passif vise à évacuer la chaleur d’une surface vers l’espace sans utiliser de compresseur ni d’alimentation électrique. Pour fonctionner en plein jour, le matériau doit simultanément réfléchir une grande partie du rayonnement solaire incident et émettre efficacement son énergie thermique dans la fenêtre de transparence atmosphérique située entre 8 et 13 µm.
Amaia Iglesias-Elcano, Luis Moreno-Sanabria, Marisol Martín-González et Cristina V. Manzano, de l’Institut de micro- et nanotechnologie IMN-CNM du CSIC, ont exploité le fluorure de polyvinylidène comme matériau de base. Le polymère est infiltré dans des matrices tridimensionnelles nanoporeuses d’alumine anodisée, ce qui permet de contrôler sa géométrie à l’échelle nanométrique et de modifier ses propriétés optiques.
Après optimisation du procédé et refroidissement ultra-rapide, la structure autoportante présente une réflectance solaire moyenne de 82,4 % et une émissivité infrarouge de 96,7 % dans la fenêtre atmosphérique 8–13 µm. Les auteurs calculent une puissance théorique de refroidissement diurne de 182,3 W/m² pour une irradiance solaire de 1 000 W/m².
Lors d’essais réalisés en extérieur près de Madrid, avec une irradiance maximale de 962 W/m², le matériau traité par ultraviolet a atteint une température jusqu’à 12,9 °C inférieure à celle d’une boîte de référence vide. Le procédé reste à développer avant une utilisation à grande échelle, mais il ouvre des perspectives pour les toitures et façades, les véhicules, l’électronique ou d’autres applications nécessitant une gestion thermique sans consommation électrique directe.
Publication : Template-Assisted 3D-PVDF Nanonetworks for Passive Daytime Radiative Cooling, Nanophotonics.
Un réseau uréthane combine rigidité élevée et autoréparation à température ambiante
Des chercheurs de l’Université du Sichuan montrent qu’il est possible de concevoir un polymère vitreux très résistant tout en conservant une capacité d’autoréparation, grâce à une organisation coopérative de liaisons hydrogène.
Les matériaux polymères autoréparables reposent souvent sur des interactions dynamiques faibles capables de se rompre puis de se reformer. Cette mobilité facilite la cicatrisation, mais elle se traduit généralement par une diminution de la rigidité ou de la résistance mécanique. Le travail conduit par l’équipe de Jinrong Wu propose une stratégie permettant de contourner ce compromis.
Les chercheurs placent un accepteur faible, ici un groupe thioéther, à proximité de fonctions uréthane flexibles. Cette organisation, décrite comme un effet coopératif d’accepteur proximal, stabilise les liaisons hydrogène entre fonctions uréthane tout en créant simultanément des interactions thioéther–uréthane plus dynamiques.
Le réseau de poly(thioéther-uréthane) obtenu atteint une résistance à la traction de 79,5 MPa et un module de Young de 3,3 GPa. Malgré une température de transition vitreuse de 62,7 °C, le matériau est capable de récupérer complètement sa résistance en 70 minutes à température ambiante lorsque les surfaces endommagées sont remises en contact sous compression.
L’introduction des groupes thioéther apporte également une meilleure résistance à l’humidité : après 120 heures à 80 % d’humidité relative, le matériau conserve plus de 90 % de sa résistance et de son module. Cette architecture moléculaire offre ainsi une nouvelle voie pour développer des matériaux polymères à la fois rigides, résistants et réparables sans chauffage important.
Publication : Weak Acceptors Abnormally Reinforce Urethane Networks while Enabling Glassy-State Healability, Macromolecules.
Un carbone biosourcé permet le recyclage photothermique de nombreuses familles de plastiques
Une équipe de Princeton propose une stratégie de recyclage photothermique utilisant un carbone poreux dérivé de protéines pour convertir sélectivement une grande diversité de polymères, y compris des plastiques post-consommation.
La plupart des procédés de recyclage chimique sont conçus pour une famille de polymères particulière. À l’inverse, les procédés thermiques plus généraux peuvent provoquer des réactions secondaires et générer des mélanges complexes de produits. Des chercheurs de l’Université de Princeton ont développé une approche intermédiaire reposant sur un agent photothermique capable de concentrer localement l’énergie lumineuse et de favoriser la dépolymérisation.
Le matériau utilisé est un carbone poreux à grande surface spécifique obtenu à partir de protéines. Sa structure lui permet de convertir efficacement la lumière en chaleur sans devoir être directement incorporé dans le polymère à traiter. De faibles quantités suffisent pour initier la déconstruction de résines de natures très différentes.
La méthode a été démontrée sur le polystyrène, le PMMA, le poly(acétate de vinyle), le poly(alcool vinylique), le polyisoprène trans, le polycarbonate de propylène, le PLLA, le PET et un polycarbonate à base de bisphénol A. Le carbone poreux peut en outre être récupéré et réutilisé plusieurs fois.
Un résultat particulièrement intéressant concerne les plastiques post-consommation, qui peuvent être traités sans prétraitement important. L’approche combine ainsi une large compatibilité avec les polymères, la réutilisation de l’agent photothermique et la possibilité d’une montée en échelle. Elle constitue une piste originale pour développer des procédés de recyclage chimique plus polyvalents face à la diversité croissante des flux de déchets plastiques.
Publication : A universal photothermal recycling strategy for post-consumer plastics using bio-derived porous carbon, Nature Communications.
Des polymères métastables ouvrent la voie à une impression 3D véritablement circulaire
Des chercheurs de l’Université de Heidelberg ont développé des polymères imprimables en 3D capables de se désassembler rapidement en leurs briques moléculaires, qui peuvent ensuite être récupérées et réutilisées pour produire un nouveau matériau.
La photopolymérisation utilisée en impression 3D permet de fabriquer des structures complexes avec une excellente résolution, mais elle conduit généralement à des réseaux très stables et difficiles à recycler. L’équipe d’Eva Blasco à l’Université de Heidelberg propose de renverser cette logique en utilisant des polymères métastables, suffisamment robustes pendant leur utilisation mais programmés pour se déconstruire lorsqu’un stimulus spécifique est appliqué.
Le concept repose sur des polymères auto-immolatifs contenant une unité moléculaire labile qui joue le rôle de point de déclenchement. Lorsqu’un signal chimique approprié active cette unité, une réaction en cascade se propage le long de la macromolécule et provoque sa dépolymérisation, à la manière d’une série de dominos.
Johannes Markhart, Philipp Mainik et Eva Blasco ont formulé ces polymères pour l’impression 3D par traitement numérique de la lumière. Les matériaux permettent de produire des objets complexes présentant des détails à l’échelle micrométrique et une bonne robustesse mécanique. Lorsqu’ils sont exposés au déclencheur prévu, les réseaux imprimés se désassemblent en quelques secondes dans des conditions ambiantes.
Les briques moléculaires sont récupérées avec un rendement proche du quantitatif puis utilisées pour reformer le polymère. Les analyses spectroscopiques montrent que le matériau recyclé possède la même composition chimique que le polymère initial et retrouve ses propriétés d’impression. Cette stratégie apporte ainsi une démonstration particulièrement convaincante d’une circularité chimique appliquée à la fabrication additive.
Publication : Johannes Markhart, Philipp Mainik et Eva Blasco, Metastable Polymers for Circular 3D Printing, Advanced Materials.
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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Waters_logo_stacked_K_web-NEW
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ICS
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cnrs
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arkema
http://www.coatex.com
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lrccp
http://www.ispa.asso.fr
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