Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
L’eau transformée en réticulateur cinétique pour des polymères se rigidifiant sous impact
Habituellement considérée comme un plastifiant indésirable, l’eau résiduelle devient ici un composant actif du réseau polymère. Confinées dans une matrice riche en protons, les molécules d’eau forment un réseau dynamique de liaisons hydrogène dont la dissociation dépend de la vitesse de sollicitation. Sous impact, le matériau passe rapidement d’un état souple à un état rigide, tout en conservant des capacités d’auto-réparation, d’adhésion et de dissipation d’énergie. Le principe, démontré avec le poly(acide thioctique), peut être étendu à d’autres polymères hydrophiles riches en fonctions acides.
La répartition des additifs gouverne la dégradation des plastiques exposés à l’environnement
Une collaboration associant notamment Géosciences Rennes, l’Institut de physique de Rennes, l’Institut des sciences chimiques de Rennes, le Synchrotron SOLEIL, ISTerre et INRAE montre que la dégradation de fragments de polyéthylène dépend fortement de l’organisation spatiale initiale de leurs additifs. La microfluorescence X synchrotron et la spectroscopie infrarouge photothermique révèlent trois comportements distincts : rupture préférentielle des domaines riches en additifs, redistribution des éléments le long des fissures oxydées et altération plus homogène des formulations faiblement structurées. La proximité du titane et du chrome avec les fronts d’oxydation souligne que la topologie des additifs constitue un paramètre déterminant, indépendamment de leur concentration globale.
Pyrolyse à basse température de polyuréthanes sans isocyanate
L’article analyse la transformation thermique de polyuréthanes sans isocyanate au moyen de techniques thermo-analytiques couplées et d’une étude cinétique détaillée. Les profils de décomposition permettent d’identifier les différentes étapes de rupture de la structure macromoléculaire et de relier leur progression à la température et à la composition du matériau. Ce travail fournit une base expérimentale pour concevoir des procédés de pyrolyse à basse température adaptés au recyclage chimique de cette famille de polyuréthanes.
https://www.sciencedirect.com/science/article/pii/S004060312600184X
Beyond Waste 2027
Chers et chères collègues,
Avant d’entrer au cœur de l’été, nous tenions à vous rappeler que l’appel à communication pour Beyond Waste 2027 est ouvert jusqu’au 10 septembre 2026.
Beyond Waste est le colloque international sur le recyclage et la circularité des matières, organisé par le PEPR « Recyclage, Recyclabilité et Ré-utilisation des matières », Il se tiendra à Lille Grand Palais du 16 au 18 mars 2027 et réunira des experts et expertes du monde entier pour se rencontrer et discuter autour de thématiques de recherche liées au recyclage, à l’écoconception et à la circularité des matières. lire plus…
Visage du GFP : Rencontre avec Delphine Chan-Seng
🏆 Rencontre avec Delphine Chan-Seng
Lors du dernier colloque national du GFP – Groupe Français d’Études et d’Applications des Polymères en novembre 2025, Delphine Chan-Seng était conférencière invitée.
A cette occasion et dans cette interview exclusive, elle nous parle de sa passion pour les polymères et leurs applications au domaine de la santé mais aussi de ses liens très forts avec notre communauté notamment en tant qu’ancienne secrétaire générale du GFP. 🔬✨
LinkedIn Stéréochimie du cyclohexanediméthanol et photostabilité des copolyesters PETG
Une série de copolyesters PETG contenant entre 67 et 99 % de la configuration trans du 1,4-cyclohexanediméthanol a été préparée par polycondensation en masse. L’étude relie directement la stéréochimie du comonomère à la température de transition vitreuse, à la stabilité thermique et au comportement sous irradiation ultraviolette. L’exposition aux UV provoque une isomérisation progressive des unités trans vers la configuration cis, accompagnée d’une évolution des propriétés mécaniques et de la viscosité intrinsèque. Le contrôle du taux d’isomère trans constitue ainsi un paramètre de formulation permettant d’accroître la résistance au vieillissement lumineux des copolyesters PETG.
Nature Lorem ipsum dolor sit amet, consectetur adipiscing elit. Sed posuere tincidunt quam sit amet viverra. Nam in consequat nulla. Nunc rhoncus orci vitae arcu sagittis, in auctor nibh posuere. Donec ut nulla id enim tempor feugiat.
Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.
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