Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
IA et surfaces de membranes poreuses pour une filtration par affinité chimique
Une équipe a développé un matériau de membrane ultrafiltrante novateur capable de trier des molécules de taille identique mais de nature chimique différente grâce à une architecture de pores fonctionnalisés. Le procédé repose sur l’auto-assemblage de micelles de copolymères à blocs chimiquement distincts, mélangés puis transformés en films poreux dont la surface interne présente des motifs chimiques variés selon les micelles utilisées. L’identification et l’optimisation de cette organisation complexe ont été rendues possibles par l’usage de techniques d’imagerie par microscopie électronique couplées à un algorithme d’apprentissage automatique, tandis que des simulations moléculaires ont permis d’éclairer les règles gouvernant l’auto-assemblage ; cette approche révèle comment la chimie des pores — et non seulement leur taille — peut être programmée. Du point de vue moléculaire, l’architecture repose sur la juxtaposition sélective de domaines fonctionnels dans les parois de pores, ce qui modifie l’affinité des molécules entrantes et permet de discriminer celles qui présentent des groupements de surface différents. Cette avancée ouvre des perspectives technologiques importantes : produire par des procédés industriels existants des membranes ultrafiltrantes capables de séparer selon l’affinité chimique, ce qui pourrait révolutionner des secteurs tels que la bio-pharmacie, le traitement de l’eau, voire les capteurs et revêtements intelligents.
https://phys.org/news/2025-11-machine-membranes-chemical-affinity.html
Conversion catalytique innovante du polyéthylène téréphtalate (PET) en composés valorisés
Une innovation récente révèle qu’une équipe a développé un procédé de recyclage chimique efficace du PET, en exploitant un système catalytique à base de chlorure de fer (III) associé à une amine et d’alcools comme agents de transestérification. Le procédé vise à couper sélectivement les liaisons ester caractéristiques du PET (bouteilles, déchets textiles), afin de produire des diesters de téréphtalate tels que le diméthyl téréphtalate, avec des rendements très élevés. Cette architecture catalytique abandonne l’usage d’acides ou de bases fortes, réduit la température d’opération et utilise un métal abondant, ce qui constitue une avancée sur les procédés classiques exigeant conditions sévères et matériaux coûteux. Le mécanisme s’appuie sur l’activation des esters intermédiaires par le fer et l’amine, suivie d’une substitution par l’alcool pour générer le diester, tandis que le matériau polymère initial est converti directement en matière première chimique de haut grade. L’intérêt technologique est double : d’une part, ce recyclage dit « chimique » permet une boucle circulaire des polyesters industriels, et d’autre part, il ouvre la voie à des filières ayant un potentiel industriel élevé en termes de valorisation de déchets plastiques. Cette méthode pourrait à terme réduire la dépendance aux ressources vierges et favoriser le développement de structures polymères régénérables à l’échelle industrielle.
https://phys.org/news/2025-11-pet-recycling-iron-catalyst-alcohols.html
40 ans d’innovation et de passion pour les polymères au LCPO
Depuis sa création en 1985, le LCPO a affirmé son positionnement à l’interface de la chimie macromoléculaire et des matériaux innovants, en mobilisant des architectures polymères conçues pour des applications allant de l’énergie aux matériaux pour le vivant. L’équipe du laboratoire explore des procédés de synthèse sobres et verts — incluant la chimie des polymères organiques, les formulations avancées et les caractérisations fines — pour générer des polymères ou copolymères dotés de propriétés fonctionnelles (conductivité, recyclabilité, biocompatibilité, dynamisme moléculaire). Sur le plan technologique, le LCPO a développé des partenariats industriels (notamment pour l’aéronautique ou les cosmétiques) et déposé plus de soixante brevets ces dernières années, ce qui témoigne de sa double orientation vers l’excellence académique et les usages applicatifs. Les architectures moléculaires conçues y sont souvent modifiées pour introduire des fonctions actives, des motifs réactifs ou des segments biosourcés, offrant ainsi des matériaux polymères « sur-mesure » dont les propriétés — mécanique, thermique, surface, recyclage — sont optimisées. Cette vision conduit à des solutions technologiques capables de répondre aux grands enjeux du XXIᵉ siècle : transition énergétique, économie circulaire, santé et bien-être, voire électronique souple. Ainsi, le LCPO incarne un laboratoire de recherche sur les polymères qui conjugue rigueur scientifique, stratégie d’innovation et mise en œuvre industrielle.
https://www.aquitaine.cnrs.fr/fr/cnrsinfo/40-ans-dinnovation-et-de-passion-pour-les-polymeres-au-lcpo
Libération de micro- et nanoplastiques à partir des matériaux au contact des aliments : état des connaissances
Une revue structurée des publications couvrant la période 2015–2025 a examiné la libération de micro- et nanoplastiques (MNP) à partir des matériaux de contact alimentaire (MCA) et révèle une évidence de libération de microplastiques, mais aussi de grandes incertitudes méthodologiques et analytiques. Il ressort que la majorité des études emploient des milieux simulant l’eau ou des liquides aqueux plutôt que des aliments solides, ce qui limite la pertinence industrielle ; les mécanismes identifiés incluent principalement l’abrasion ou la friction et la présence de structures ouvertes ou fibreuses dans les matériaux ; cependant les quantités réelles de libération sont probablement bien inférieures à celles rapportées dans nombre d’articles en raison de manques en fiabilité de préparation d’échantillons, de conditions de test non représentatives et de défaillances analytiques. À ce jour, il n’existe pas de base suffisante pour quantifier l’exposition aux MNP liée à l’usage des MCA. Enfin, cette revue met en avant des lacunes critiques : les données sur les nanoplastiques sont quasi nulles, les matériaux solides faiblement étudiés, et des recommandations sont formulées pour améliorer la standardisation des méthodes, l’analyse des particules, l’étude de la transformation des MCA en conditions réelles et l’évaluation toxicologique corrélée.
Valorisation de déchets plastiques en catalyseur multifonction pour l’épuration de l’eau
Une équipe de recherche a démontré une voie innovante pour transformer des déchets de plastique en un matériau catalytique polyvalent dédié à l’épuration de l’eau. Les scientifiques ont mis au point un procédé de synthèse mécanochemique, utilisant un broyeur planétaire, combinant du dioxyde de molybdène (MoO₃) à du polypropylène usagé, afin de générer un composite constitué de bronze hydrogéné de molybdène (HₓMoO₃₋ᵧ), de MoO₂ et de carbone activé. Ce matériau déclenche à la fois des effets plasmoniques et photothermiques, assurant une absorption large du spectre solaire (UV-visible-infrarouge) et induisant un échauffement rapide, ce qui permet à la fois la photodégradation de polluants organiques, l’évaporation photothermique et l’adsorption d’ions métalliques lourds même en l’absence de lumière. Cette architecture moléculaire et composite marie des fonctions catalytiques acido-Brønsted, photothermiques et adsorbantes, offrant une solution technologique à faible coût et à grande scalabilité pour le traitement de l’eau. L’approche ouvre une nouvelle perspective industrielle : la conversion de plastiques jetés en matériaux actives pour la désalinisation, la purification de l’eau et plus largement pour des applications environnementales durables.
https://scitechdaily.com/from-plastic-to-pure-water-scientists-turn-trash-into-a-super-catalyst/
Protocole standardisé pour l’extraction et la caractérisation des micro- et nanoplastiques dans les matrices environnementales
Des chercheurs ont mis au point un protocole systématique couvrant la prétraitement des échantillons, l’extraction en quatre étapes et la caractérisation qualitative et quantitative des micro- et nanoplastiques à partir de matrices environnementales variées. Le dispositif combine digestion chimique, séparation par densité, et techniques spectroscopiques avancées (ATR-FTIR, LDIR, O-PTIR), permettant une récupération et une pureté maximisées tout en minimisant les transformations artefactuelles. Ce cadre méthodologique cible les plastiques courants comme PE, PET, PP, PS et PMMA dans des tailles allant de la nano- à la microscale. En fournissant également des recommandations pour l’adaptation du protocole selon la complexité de l’échantillon et des conseils pour la validation via AFM ou cytométrie en flux, cette procédure favorise une comparaison inter-études plus rigoureuse. Fournir un tel standard répond à un besoin croissant de reproductibilité dans l’évaluation de la pollution plastique.
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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ICS
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cnrs
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lrccp
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LPMC
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arkema
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http://www.waters.com
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http://www.ispa.asso.fr
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