Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Le recyclage du plastique, une réalité industrielle appuyée par la science
La campagne “Recycling is Real” de la Plastics Industry Association met en lumière les avancées concrètes du recyclage des plastiques à travers les États-Unis, en s’appuyant sur des technologies de pointe comme la thermoformage de plastiques post-consommation. En filmant des sites comme celui de Plastic Ingenuity dans le Wisconsin, qui transforme les déchets plastiques en emballages pour les secteurs alimentaire et médical, l’initiative démontre comment des approches industrielles fondées sur la science des matériaux et l’ingénierie environnementale permettent de réintégrer le plastique dans une boucle circulaire. Cette démonstration pragmatique de recyclage vise aussi à corriger les idées reçues en soulignant que l’innovation technique et la rigueur scientifique sont au cœur des solutions pour réduire l’impact environnemental du plastique.
https://www.plasticstoday.com/sustainability/plastics-showcases-real-recycling-success-stories
Recycler le PVC sans risque, c’est (enfin) possible
Le PVC est un plastique omniprésent… et l’un des plus difficiles à recycler. Trop chloré, il résiste aux procédés classiques et génère des sous-produits toxiques lorsqu’on tente de le brûler ou de le dégrader. Une équipe chinoise a mis au point une solution élégante et propre : un catalyseur sur-mesure (LaFe₀.₃Al₀.₇O₃) qui déclenche une « cascade » de réactions douces dans l’eau, à température ambiante.
Ce procédé active d’abord une forme spéciale d’oxygène singulet pour retirer les atomes de chlore de manière sélective. Ensuite, des radicaux hydroxyles attaquent la chaîne carbonée, menant à une dépolymérisation complète. Résultat : le PVC est transformé en CO₂ et en hydrocarbures liquides réutilisables, sans aucun résidu solide ni composé chloré toxique.
Une analyse du cycle de vie montre que cette approche réduit drastiquement les émissions et les impacts environnementaux par rapport à l’enfouissement ou à l’incinération. C’est un bel exemple de chimie durable, qui transforme un plastique problématique en ressource utile — et ouvre la voie à un recyclage plus propre et plus circulaire.
Nature Nanofiltration membranaire : une percée pour purifier et recycler les plastiques sans les dégrader
Des chercheurs canadiens proposent une approche inédite de recyclage physique des plastiques fondée sur la nanofiltration membranaire. Publiée dans Communications Chemistry, l’étude démontre qu’il est possible d’éliminer efficacement les additifs et les fragments de polymères dégradés en exploitant un simple principe de séparation par taille moléculaire. Les polymères, dont les masses molaires dépassent 100 000 g/mol, sont des macromolécules bien plus volumineuses que les additifs (200–2000 g/mol). En dissolvant le plastique dans un solvant sélectif puis en le soumettant à une membrane céramique à pores nanométriques, les petites molécules migrent vers le perméat tandis que les chaînes polymères restent dans le rétentat. Appliqué au polystyrène contaminé par l’hexabromocyclododécane (HBCD), un retardateur de flamme interdit, le procédé atteint plus de 90 % d’élimination des contaminants tout en supprimant les chaînes courtes oxydées, améliorant ainsi la qualité du polymère recyclé. Ce système, pilotable par simple ajustement du volume de solvant ou de la pression transmembranaire, permet de contrôler précisément la pureté finale du produit. Compatible avec les polyoléfines, PVC, polyuréthanes et polystyrènes — soit près de 70 % du marché mondial des plastiques —, cette technologie comble l’écart entre recyclage mécanique et recyclage chimique. Sa scalabilité industrielle et sa capacité à générer des résines « quasi vierges » ouvrent la voie à un recyclage circulaire haute valeur ajoutée, limitant les pertes de matière et la dépendance aux ressources fossiles.
Nature Polymérisation induite par vinyl-aza-[3]cumulène : une voie stéréocontrôlée vers des poly(sulfonylamidines) intelligents pour la délivrance de médicaments
Une équipe chinoise a mis au point une nouvelle réaction multicomposante cuivre-catalysée permettant d’accéder à des polymères inédits à base de poly(diényle-N-sulfonylamidines), via des intermédiaires réactifs jusque-là inconnus : les vinyl-aza-[3]cumulènes. Ces espèces hautement électrophiles, formées in situ à partir d’esters, d’amines et d’azotures, induisent une polymérisation régiosélective et stéréocontrôlée donnant exclusivement des motifs diéniques de configuration E. L’approche permet la synthèse de polymères bien définis, thermiquement stables et hydrolysables, dont la dégradation en milieu basique libère des diénamides structurés. Grâce à leur squelette conjugué et à la présence de groupes sulfonylamidine zwitterioniques, ces macromolécules s’auto-assemblent spontanément en nanoparticules chargées négativement en milieu aqueux, capables d’encapsuler la doxorubicine par interactions électrostatiques et hydrophobes. Ces nanoparticules présentent un comportement de libération contrôlé par le pH, libérant plus de 80 % du médicament à pH acide (5–6), ce qui les rend adaptées à la délivrance ciblée en environnement tumoral. L’étude démontre ainsi que la conception rationnelle d’intermédiaires cumulènes azotés ouvre un accès inédit à des polymères fonctionnels stéréodéfinis et stimuli-réactifs, combinant stabilité, dégradabilité et auto-organisation. Cette avancée relie chimie des cumulènes, polymérisation multicomposante et nanomédecine, élargissant le champ des matériaux polymères intelligents pour la vectorisation thérapeutique.
![Vinyl-aza-[3]cumulene intermediates induced polymerization for accessing E-dienyl poly(sulfonylamidines) towards pH-responsive drug delivery - Nature Communications](https://media.springernature.com/m685/springer-static/image/art%3A10.1038%2Fs41467-025-65320-y/MediaObjects/41467_2025_65320_Fig1_HTML.png)
Nature Des polyesters fluorés recyclables pour des plastiques plus performants
Des chercheurs de l’Université de Bayreuth ont mis au point une nouvelle classe de polyesters dégradables enrichis en fluor, capables d’allier performances mécaniques accrues et recyclabilité chimique. Grâce à l’intégration sélective d’atomes de fluor, ces plastiques présentent une polymérisation plus rapide, des chaînes plus longues et une meilleure robustesse. Mieux encore, le fluor incorporé peut être récupéré lors du recyclage, offrant un modèle circulaire innovant. Cette approche moléculaire fine, illustrant la puissance de la chimie de précision, permet d’adapter les propriétés des matériaux aux besoins industriels tout en répondant aux enjeux environnementaux.
https://phys.org/news/2025-10-recyclable-fluorine-properties-degradable-polyester.html
Percée pour des polymères auto-réparants ultrarésistants à la fatigue
Des chercheurs chinois ont mis au point un composite auto-réparant associant des feuillets bidimensionnels de MXène à une matrice de polyuréthane supramoléculaire, capable de concilier rigidité, résistance à la fatigue et réparabilité rapide — un triptyque rarement atteint dans les matériaux polymères. En reproduisant la structuration multi-échelle des tissus biologiques, le matériau intègre une phase dure continue nanométrique et un réseau tridimensionnel de MXène interconnecté obtenu par auto-assemblage via des liaisons hydrogène médiées par l’acide phytique. Cette organisation hiérarchique dissipe les contraintes sur plusieurs niveaux, limitant la propagation des fissures de fatigue tout en conférant un module d’Young élevé et une stabilité thermomécanique jusqu’à 70 °C. Les simulations de dynamique moléculaire montrent que la densité d’énergie cohésive élevée et la robustesse des liaisons supramoléculaires préservent l’intégrité du réseau sous sollicitations cycliques. Grâce aux propriétés photothermiques du MXène, la réparation des dommages peut être activée par irradiation infrarouge proche, rétablissant en une minute les performances mécaniques initiales. Cette conception multi-échelle dépasse les limites classiques du compromis entre élasticité et endurance, offrant un modèle général pour des polymères bio-inspirés à comportement adaptatif. Ces matériaux ouvrent des perspectives concrètes dans les domaines de la robotique souple, des prothèses biomécaniques et des structures composites intelligentes, où résistance mécanique, durabilité et réparabilité doivent désormais coexister.
Nature Lorem ipsum dolor sit amet, consectetur adipiscing elit. Sed posuere tincidunt quam sit amet viverra. Nam in consequat nulla. Nunc rhoncus orci vitae arcu sagittis, in auctor nibh posuere. Donec ut nulla id enim tempor feugiat.
Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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Logo-ChemSuD
http://www.ispa.asso.fr
lrccp
http://www.ispa.asso.fr
hutchinson
http://www.hutchinson.com/fr
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
LPMC
http://www.ispa.asso.fr
cnrs
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
ICS
https://www-ics.u-strasbg.fr/
arkema
http://www.coatex.com
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