Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Du rebut aux reflets cristallins : une technique innovante pour un plastique recyclé limpide
Des chercheurs de l’Université du Wisconsin-Madison ont mis au point une méthode basée sur des solvants pour éliminer les pigments récalcitrants des emballages plastiques multicouches recyclés, améliorant ainsi considérablement la qualité visuelle et commerciale du plastique recyclé. Le procédé, qui s’appuie sur la technique STRAP (solvent-targeted recovery and precipitation), permet de dissoudre sélectivement chaque couche de plastique et de récupérer les monomères, tout en identifiant que le pigment responsable du teint jaunâtre est le Yellow 12. En sélectionnant un solvant présentant une faible solubilité pour Yellow 12 et en y ajoutant du charbon actif pour piéger davantage ce pigment, les chercheurs parviennent à éliminer complètement la coloration indésirable lors de l’évaporation finale du solvant, aboutissant à un plastique clair, sans teinte perceptible à l’œil nu. Cette avancée est cruciale, car un plastique recyclé transparent peut avoir une valeur de marché jusqu’à dix fois supérieure à celle des plastiques colorés, favorisant ainsi une économie circulaire plus efficace.
Décomposition quasi-totale du PMMA par photodépolymérisation
Des chercheurs de l’ETH Zurich, dirigés par Athina Anastasaki, ont mis au point une méthode surprenante permettant de décomposer presque entièrement le PMMA (verre acrylique) en ses monomères de départ. En dissolvant le PMMA dans un solvant chloré et en appliquant de la lumière UV ou visible, la réaction génère des radicaux chlorés qui provoquent la rupture ciblée des chaînes polymériques, même en présence d’additifs. Ce procédé simple et efficace atteint des rendements compris entre 94 % et 98 %, offrant ainsi une alternative bien plus sélective et énergétiquement avantageuse par rapport à la pyrolyse traditionnelle, qui requiert des températures élevées et produit un mélange complexe de produits de dégradation. Bien que prometteuse, la technique nécessite encore des ajustements pour éliminer l’utilisation de solvants chlorés, afin de réduire son impact environnemental. Ces résultats ouvrent la voie à des stratégies de recyclage chimique ciblées pour des plastiques jusqu’alors difficiles à décomposer, avec de fortes implications pour l’économie circulaire des matériaux plastiques.
Plastics Europe appelle à une solution diplomatique pour atténuer les effets des tarifs réciproques
Face aux tarifs rétaliques par l’UE en réponse aux 25 % de droits sur l’acier et l’aluminium appliqués par l’administration Trump, Plastics Europe souligne l’importance de préserver les principes du libre-échange. L’association met en garde contre les perturbations des chaînes d’approvisionnement et l’augmentation des coûts pour les entreprises et les consommateurs de part et d’autre de l’Atlantique. Le nouvel ajustement tarifaire de l’UE, qui prévoit une réimposition des taxes d’avril prochain et l’application de nouveaux droits en mi-avril sur 18 milliards d’euros d’exportations américaines, pourrait compromettre la compétitivité du secteur plastique, qui réalise 11,7 % des exportations de l’UE. Dans un contexte où la coopération économique reste cruciale, Plastics Europe appelle à des négociations diplomatiques pour résoudre ce différend de manière équilibrée et protéger les intérêts des industries, des emplois et des consommateurs des deux côtés de l’Atlantique.
Synthèse précise de polymères 2D conjugés sp²-carbonés
Des chercheurs chinois, dirigés par le Professeur Zhang Tao de l’Institut de Technologie des Matériaux de Ningbo (NIMTE) en collaboration avec le Professeur Feng Xinliang du Max Planck Institute of Microstructure Physics, ont développé une stratégie innovante de polycondensation interfaciale aldolique assistée par pyridinium amphiphile pour fabriquer des films polymériques 2D conjugés sp². En favorisant l’auto-assemblage des monomères en monocouches ordonnées à l’interface eau, leur procédé irréversible sous conditions douces permet d’obtenir des films présentant une organisation moléculaire de longue portée, un cadre chargé robuste et une épaisseur modulable de la monocouche au multicouche. Ces caractéristiques confèrent aux polymères une stabilité chimique exceptionnelle et une conductivité améliorée, ouvrant ainsi de nouvelles perspectives pour des applications avancées en membranes, électronique organique et conversion d’énergie par gradients salins, comme démontré par leurs performances remarquables dans des générateurs osmotiques sous conditions acides.
https://phys.org/news/2025-03-scientists-precise-synthesis-crystalline-sp.html
Moteurs moléculaires en action : observation du mouvement des α-cyclodextrines
Des chercheurs du Japan Advanced Institute of Science and Technology ont réussi à visualiser en temps réel le déplacement des anneaux d’α-cyclodextrine le long d’une chaîne de polyéthylène glycol dans des structures de polypseudorotaxane. Grâce à une technique de cryo-microscopie à balayage rapide (FS-AFM), ils ont pu observer comment ces anneaux, qui s’auto-assemblent sur la chaîne, induisent des mouvements de contraction et d’extension, révélant ainsi des changements structuraux locaux essentiels à la compréhension des mécanismes de mouvement dans les systèmes supramoléculaires. Ces observations, corroborées par des simulations de dynamique moléculaire, offrent une nouvelle perspective sur la conception de moteurs moléculaires efficaces, exploitant l’énergie thermique ambiante pour des applications potentielles en nanotechnologie et en dispositifs biomédicaux.
https://phys.org/news/2025-03-molecular-motors-action-visualizing-cyclodextrin.html
Stabilité thermique et dégradation d’un adhésif photo-croisé à faible indice de réfraction
Cette étude examine la dégradation de l’adhésif PC373HA, utilisé dans les assemblages laser, via une analyse thermogravimétrique. Les chercheurs ont modélisé son vieillissement par des approches basées sur la loi d’Arrhenius, notamment les modèles Ozawa-Flynn-Wall et Kissinger-Akahira-Sunose. Ils identifient 150 °C comme seuil critique pour une opération de 15 h, tandis qu’à 220 °C la dégradation s’accélère (≈10 minutes) et à 180 °C (≈100 minutes). Ces résultats fournissent des repères essentiels pour anticiper le remplacement de l’adhésif en cas d’incidents thermiques, garantissant ainsi la fiabilité des systèmes laser.
https://www.sciencedirect.com/science/article/abs/pii/S0143749625000235?via%3Dihub
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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LPMC
http://www.ispa.asso.fr
cnrs
http://www.ispa.asso.fr
arkema
http://www.coatex.com
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
Logo-ChemSuD
http://www.ispa.asso.fr
lrccp
http://www.ispa.asso.fr
ICS
https://www-ics.u-strasbg.fr/
hutchinson
http://www.hutchinson.com/fr
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