Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Voie radicalaire dynamique pour plastiques haute performance et recyclables
Des chercheurs ont mis au point une nouvelle stratégie de conception de vitrimeres fondée sur une chimie radicalaire activable thermiquement, permettant d’obtenir des matériaux à la fois performants et reconfigurables. L’approche repose sur l’introduction de motifs disulfures capables de générer des radicaux de manière réversible sous l’effet de la chaleur ; ces radicaux déclenchent des échanges de liaisons au sein du réseau sans déstabiliser l’architecture tridimensionnelle, ce qui confère au matériau une mobilité contrôlée tout en préservant rigidité, stabilité thermique et résistance chimique. Ce mécanisme dynamique, intégré directement dans le maillage du polymère, offre la possibilité de remodeler, réparer ou recycler le matériau sans dégradation notable des performances, surmontant ainsi les limites classiques des thermodurcissables irréversibles. Cette avancée ouvre une voie nouvelle pour des plastiques hautes performances compatibles avec des cycles multiples de transformation, et constitue une étape importante vers des matériaux durables destinés à des secteurs exigeants tels que l’aéronautique, l’automobile ou l’électronique.
Renforcement des propriétés physiques d’un film PVA/PVP dopé au chlorure de fer : vers des composites opto-électroniques et antimicrobiens
Des chercheurs ont élaboré des films composites à base de polyvinyl alcohol (PVA) et de polyvinylpyrrolidone (PVP), dans lesquels ils ont incorporé du ferrous chloride (FeCl₂) en différentes proportions afin d’évaluer l’impact sur la structure, les propriétés physiques et les performances antimicrobiennes. L’ajout de FeCl₂ modifie significativement la morphologie : l’analyse structural par diffraction et spectroscopie révèle une augmentation de la fraction amorphe et des interactions fortes entre le polymère et le filler, ce qui tend à perturber l’ordre cristallin initial du mélange. Du point de vue thermique, le composite gagne en stabilité, tandis que sur le plan optique l’écart de bande diminue — une réduction suffisamment marquée pour envisager des applications opto-électroniques plutôt qu’isolantes. Par ailleurs, les propriétés électriques sont fortement améliorées : la constante diélectrique augmente, la conductivité alternative (AC) s’accroît, et le comportement diélectrique montre des relaxations non-Debye, ce qui suggère des mécanismes de conduction par saut et une complexité dans la polarisation locale. Enfin, les films présentent une activité antibactérienne notable contre des bactéries Gram-positives et Gram-négatives. Ce travail illustre comment une modification simple par sel inorganique peut conduire à des composites polymères multifonctionnels — alliant comportement opto-électronique, conduction, et action antimicrobienne — et ouvre des perspectives pour des matériaux flexibles, bon marché et polyvalents.
Nature Étiquette polymère biodégradable et thermo-réactive : une approche pour l’électronique jetable durable
Des chercheurs ont développé une étiquette entièrement biodégradable, sans puce, capable d’indiquer de manière irréversible un dépassement de température grâce à l’intégration contrôlée de polymères biodérivés, de métaux imprimables et de matériaux à changement de phase. Le dispositif repose sur un substrat composite associant un biopolymère aliphatique et des fibres cellulosiques, offrant une stabilité mécanique et thermique suffisante pour l’impression de motifs conducteurs tout en conservant une bonne compostabilité. Des traces métalliques déposées en couches minces constituent un circuit résonant dont la fréquence dépend de l’environnement diélectrique local. L’introduction de micro-réservoirs contenant des huiles végétales solidifiées crée un mécanisme déclencheur : lorsque la température dépasse le seuil de fusion choisi, la phase liquide envahit la zone active, modifie la permittivité locale et entraîne un décalage permanent de la résonance. Cette configuration combine architecture multicouche, micro-encapsulation et électronique imprimée pour produire un système fonctionnel sans silicium, à très faible coût, adapté aux contraintes de la chaîne du froid ou de la logistique intelligente. En intégrant uniquement des matériaux compostables, l’étude illustre une approche de conception circulaire visant à créer des dispositifs polymères écoresponsables, activables par des stimuli environnementaux et alignés sur les besoins croissants en électronique jetable durable.
Nature Polymère composite conducteur activé par ondes électromagnétiques : une stratégie innovante pour réseaux résistifs souples
Des chercheurs ont mis en lumière une méthode originale d’assemblage interne dans les composites polymères : l’exposition à de faibles ondes électromagnétiques (EMWs) suffit à « cohérer » les microparticules conductrices dispersées dans la matrice polymère, sans recours à un ajout massif de charges conductrices. Dans cette étude, des microfibres métalliques intégrées dans un élastomère souple forment, après traitement EMW, un réseau conducteur optimisé : la brève sollicitation électromagnétique entraîne la rupture des couches d’oxyde superficiel des microfibres et favorise des contacts métalliques consolidés par chauffage local (effet Joule), réorganisant la topologie interne du composite. Ce mécanisme repose exclusivement sur des effets physiques — induction de tension, effondrement d’oxyde, chauffage local — sans modification chimique des constituants. L’activation ainsi obtenue provoque une transition spectaculaire du matériau, passant d’un état isolant à un état hautement conducteur, tout en conservant la flexibilité du polymère. Cette approche universelle fonctionne avec différents types de fillers (métalliques ou carbonés) et de matrices polymères, ce qui souligne sa robustesse et sa versatilité. Sur le plan technologique, ce concept ouvre de nouvelles perspectives pour la fabrication de matériaux souples et conducteurs à faible coût, et pourrait être exploité dans le domaine de l’électronique flexible, des dispositifs mémoire résistifs, de l’emballage électronique ou des systèmes auto-configurables — contribuant potentiellement à transformer la conception de composites conducteurs dans des applications industrielles.
Nature Solvant eutectique non toxique pour le recyclage sélectif des textiles coton-polyester
Des chercheurs ont mis au point un solvant eutectique non toxique capable de dissoudre sélectivement la fraction polyester dans les textiles mélangés tout en préservant l’intégrité des fibres de coton, ouvrant ainsi une voie efficace pour recycler des tissus considérés jusqu’ici comme difficilement valorisables. Le procédé repose sur une interaction chimique ciblée entre le solvant et les liaisons ester du polyester, permettant une dépolymérisation ou une solubilisation contrôlée du composant synthétique sans altérer les structures cellulosiques naturelles. Cette approche permet de séparer proprement les deux constituants : le coton demeure récupérable sous forme de fibres intactes et le polyester dissous peut être converti ou réutilisé. L’innovation illustre comment un ajustement fin des forces d’interaction au niveau moléculaire peut transformer un gisement textile problématique en ressource circulaire. Sur le plan technologique, cette méthode offre un levier pour industrialiser le recyclage des textiles mixtes, améliorer la pureté des flux de matières et réduire la dépendance aux fibres vierges, tout en limitant l’usage de solvants dangereux et en améliorant la durabilité du secteur textile.
https://phys.org/news/2025-11-toxic-solvent-enables-recycling-fiber.html
Revêtements polymères-zinc intelligents pour la protection anticorrosion en milieu marin
Des chercheurs ont récemment synthétisé des composites associant zinc et matrices polymères pour développer des revêtements protecteurs destinés à la corrosion des structures métalliques en milieu marin, combinant protection anodique et propriétés de barrière avec des fonctionnalités de type « auto-guérison ». Leur approche repose sur la dispersion de particules ou alliages à base de zinc — agents sacrifiables — dans des matrices polymères, éventuellement enrichies en nanomatériaux (porous frameworks, matériaux bidimensionnels, nanoparticules conductrices ou inhibiteurs encapsulés), de façon à conjuguer l’action cathodique/anodique du zinc, une barrière physique contre l’eau et les ions chlorure, et des mécanismes de libération contrôlée d’inhibiteurs ou de réparation à la demande. En cas de dégradation locale du revêtement, des nanoconteneurs réactifs (par exemple des frameworks métalliques organiques) peuvent libérer des molécules inhibitrices, ou le polymère peut reformer des liaisons (via des réseaux dynamiques, interactions supramoléculaires ou microcapsules), assurant une régénération partielle ou totale de la protection. Ce concept hybride — mélange de protection active, barrière passive et auto-réparation — représente une avancée significative par rapport aux méthodes traditionnelles (galvanisation, revêtements époxy classiques), en offrant potentiellement une durée de vie prolongée des infrastructures marines, une réduction des coûts de maintenance, et un moindre impact environnemental grâce à l’efficacité consolidée des systèmes composites. Ces développements ouvrent la voie à des matériaux de protection anticorrosion plus durables, adaptatifs et intelligents, particulièrement adaptés aux environnements agressifs comme ceux des installations offshore et des infrastructures côtières.
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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ICS
https://www-ics.u-strasbg.fr/
cnrs
http://www.ispa.asso.fr
arkema
http://www.coatex.com
Waters_logo_stacked_K_web-NEW
http://www.waters.com
Logo-ChemSuD
http://www.ispa.asso.fr
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
LPMC
http://www.ispa.asso.fr
hutchinson
http://www.hutchinson.com/fr
lrccp
http://www.ispa.asso.fr
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