Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Polymérisation photo-induite pour l’impression directe d’électrodes flexibles
Une étude récente dévoile une méthode de synthèse révolutionnaire permettant de générer des électrodes conductrices flexibles à même la peau ou les textiles via un processus de polymérisation activé par la lumière visible. S’affranchissant des contraintes habituelles liées aux solvants toxiques et aux conditions réactionnelles sévères, cette approche repose sur l’utilisation de précurseurs monomères hydrosolubles et biocompatibles, capables de se structurer en réseaux de polymères conjugués sous une simple irradiation lumineuse. Ce procédé de photo-structuration douce assure la formation de jonctions électroniques intimes avec des substrats biologiques ou fibreux irréguliers, garantissant une impédance de contact réduite et une fidélité de signal accrue pour le monitoring physiologique. La capacité de ce système à produire des circuits fonctionnels sans recourir à des équipements de lithographie onéreux ni à des traitements thermiques destructeurs témoigne d’une avancée significative en électronique organique. Par conséquent, cette technologie de fabrication simplifiée pave la voie à une nouvelle génération de dispositifs biomédicaux portables et d’interfaces homme-machine, alliant haute performance électrique, confort d’usage et innocuité totale pour les tissus vivants.
https://phys.org/news/2025-12-driven-flexible-electrodes-skin-textiles.html
Transformation des déchets plastiques en précurseurs pharmaceutiques anticancéreux
Une étude récente met en lumière une avancée majeure dans la valorisation chimique des déchets ménagers en polyéthylène téréphtalate. En soumettant ces polymères post-consommation à un procédé de semi-hydrogénation catalysé par le ruthénium, les chercheurs ont réussi à dépolymériser sélectivement la matrice pour générer de l’éthyl-4-hydroxyméthyl benzoate, un intermédiaire chimique à haute valeur ajoutée. Contrairement aux méthodes de recyclage traditionnelles qui dégradent souvent la qualité du matériau, cette approche de surcyclage permet d’obtenir des briques moléculaires précurseurs indispensables à la synthèse de médicaments vitaux, notamment des traitements anticancéreux, des agents anti-inflammatoires et des agrochimiques. Le mécanisme réactionnel, validé par une analyse de cycle de vie, démontre une empreinte environnementale significativement réduite par rapport aux voies de production pétrochimiques conventionnelles, tout en offrant une alternative viable pour la synthèse d’ingrédients pharmaceutiques actifs. Dès lors, cette découverte redéfinit le statut du déchet plastique, le transformant en ressource stratégique pour l’industrie de la santé et accélérant la transition vers une économie circulaire sophistiquée.
https://phys.org/news/2025-12-discovery-household-plastic-recycling-anti.html
Synergie entre modèles de langage et calcul quantique pour la conception générative de matériaux
Une initiative scientifique récente orchestre la convergence stratégique entre l’intelligence artificielle générative et la chimie théorique pour surmonter les barrières temporelles inhérentes à la découverte de nouveaux matériaux. En hybridant les architectures neuronales avancées, spécifiquement les grands modèles de langage, avec la rigueur prédictive des simulations quantiques basées sur la fonctionnelle de la densité, le projet AIM-GPT déploie une plateforme de conception in silico autonome. Ce système ne se contente pas d’explorer de vastes espaces chimiques pour générer des structures moléculaires et cristallines inédites ; il opère simultanément un criblage virtuel rigoureux en évaluant les propriétés intrinsèques des candidats avant toute tentative de synthèse. Cette méthodologie permet ainsi de cibler avec une précision accrue des solutions robustes pour des applications critiques telles que le stockage électrochimique ou la catalyse hétérogène. Dès lors, cette alliance entre calcul haute performance et science des matériaux promet de réduire drastiquement les cycles de développement, offrant des outils ouverts indispensables pour accélérer l’innovation face aux impératifs de la transition énergétique.
Synergie catalytique pour la synthèse d’élastomères thermoplastiques hybrides
Des chercheurs ont réussi une prouesse synthétique en unissant deux modes de polymérisation historiquement jugés incompatibles — la voie anionique et la catalyse de coordination — pour concevoir une nouvelle famille d’élastomères thermoplastiques de haute performance. Au sein du laboratoire commun ChemistLab, l’équipe a élaboré des copolymères triblocs inédits (polystyrène-b-poly(éthylène-co-butadiène)-b-polyéthylène) en utilisant des chaînes de polystyrène vivant comme agents de transfert macromoléculaire vers un catalyseur de coordination. Cette architecture macromoléculaire sophistiquée génère, lors du refroidissement, un réseau physique doublement réticulé par des nanodomaines vitreux et cristallins, conférant au matériau une élasticité et une recouvrance exceptionnelles. Parallèlement, la miscibilité des blocs polyoléfiniques à l’état fondu assure une viscosité réduite, facilitant considérablement la mise en forme par rapport aux standards actuels. En surmontant les limites de processabilité des caoutchoucs réticulés irréversibles, cette innovation ouvre la voie à des matériaux durables et recyclables, capables de répondre aux exigences sévères de l’industrie pneumatique tout en s’inscrivant dans une économie circulaire.
Bilan 2025 : innovations de rupture et circularité dans les matériaux d’emballage
Une rétrospective des avancées technologiques de l’année 2025 met en lumière une mutation profonde de l’ingénierie des matériaux d’emballage, désormais pilotée par la convergence entre écoconception rigoureuse et intelligence numérique. Face à l’obsolescence des structures multicouches traditionnelles, l’industrie a massivement basculé vers des architectures mono-matériaux avancées, optimisant ainsi la compatibilité avec les filières de recyclage mécanique sans sacrifier les propriétés barrières. Parallèlement, les polymères biosourcés de nouvelle génération, notamment les polyhydroxyalcanoates et les composites à base de mycélium, ont franchi un seuil de maturité critique, offrant des alternatives compostables robustes pour des applications à haute exigence technique. Cette transition matérielle s’accompagne d’une révolution fonctionnelle où l’intégration de marqueurs cryptographiques et de capteurs biochimiques au sein même de la matrice transforme le contenant en une interface active, capable de garantir la traçabilité et de monitorer l’intégrité du produit en temps réel. En consolidant le déploiement de technologies de recyclage chimique pour les flux complexes, cette dynamique d’innovation redéfinit les standards de durabilité, ancrant le secteur dans une économie circulaire opérationnelle capable de répondre aux pressions réglementaires croissantes.
https://www.plasticstoday.com/packaging/year-in-review-packaging-wrapped-in-innovation
Influence de la substitution halogénée sur la perméabilité des poly(diphénylacétylène)s
Des chercheurs ont synthétisé une nouvelle série de dérivés de poly(diphénylacétylène)s visant à élucider l’impact critique de la nature et de la position des substituants halogénés sur les propriétés de transport gazeux. En incorporant stratégiquement des atomes de fluor ou de chlore conjointement avec des groupements méthyle et triméthylsilyle sur le squelette aromatique, l’étude révèle une dichotomie remarquable dans les performances membranaires. Tandis que la substitution en position para par le fluor engendre une perméabilité à l’oxygène exceptionnellement élevée, surpassant largement les standards habituels, l’introduction analogue de chlore conduit, contre toute attente, à des flux gazeux nettement inférieurs. Cette différence de comportement survient paradoxalement alors que les analyses de diffraction des rayons X indiquent un espacement inter-chaîne plus important pour les analogues chlorés. Ce constat suggère que la nature chimique du substituant, au-delà du simple encombrement stérique, orchestre l’architecture du volume libre fractionnaire et la connectivité des micro-cavités de manière subtile. Ces travaux offrent ainsi des directives précieuses pour le design moléculaire de membranes polymères de nouvelle génération, optimisées pour les procédés industriels de séparation et d’enrichissement des gaz.
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.
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Les partenaires
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LPMC
http://www.ispa.asso.fr
arkema
http://www.coatex.com
hutchinson
http://www.hutchinson.com/fr
cnrs
http://www.ispa.asso.fr
ICS
https://www-ics.u-strasbg.fr/
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
Logo-ChemSuD
http://www.ispa.asso.fr
lrccp
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
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