Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Une électrode à nanofils d’argent convertit le CO₂ en précurseurs de plastiques avec une forte sélectivité
Des chercheurs ont développé une architecture d’électrode destinée à améliorer la conversion électrochimique du dioxyde de carbone en composés carbonés utilisables comme précurseurs de plastiques, notamment l’éthylène. Le verrou traité est celui de l’inondation des électrodes, phénomène dans lequel l’électrolyte pénètre la structure poreuse et réduit l’accès du CO₂ aux sites catalytiques. La solution proposée repose sur une organisation en trois couches associant un support hydrophobe, une couche catalytique à base de cuivre et un réseau supérieur de nanofils d’argent. Cette architecture ne sert pas seulement à conduire les charges : les nanofils participent aussi à la réaction en générant du monoxyde de carbone, ensuite transféré vers les sites cuivre où se forment des produits multicarbonés. L’électrode fonctionne donc comme un système catalytique tandem, dans lequel conduction, protection contre l’eau et sélectivité réactionnelle sont intégrées dans un même objet. L’intérêt technologique est important pour la chimie du carbone, car cette stratégie rapproche la conversion du CO₂ d’une voie plus stable et plus sélective vers des intermédiaires de l’industrie des polymères. À terme, elle pourrait alimenter des procédés de production d’oléfines, d’alcools ou de carburants à partir de carbone recyclé plutôt que de ressources fossiles.
https://phys.org/news/2026-04-electrode-technology-efficiency-plastic-precursors.html
Durabilité des polymères en environnement marin : l’IFREMER consolide les bases physico-chimiques du vieillissement en mer
Des chercheurs de l’IFREMER Centre de Bretagne proposent une mise au point structurante sur le comportement à long terme des matériaux polymères exposés aux contraintes marines. L’article replace la durabilité non comme une simple résistance globale, mais comme le résultat d’un couplage entre pénétration de l’eau, oxygène dissous, rayonnement ultraviolet, sollicitations mécaniques et évolution progressive de la microstructure. La synthèse insiste sur la manière dont l’absorption d’eau, la plastification, l’oxydation et les endommagements interfaciaux modifient la réponse mécanique, en particulier lorsque les matériaux sont employés dans des structures offshore, des équipements immergés ou des composants soumis à des cycles environnementaux répétés. L’intérêt de ce travail tient à son articulation entre vieillissement chimique, comportement mécanique et conditions d’usage réelles, ce qui permet d’éviter une vision trop simplifiée des essais accélérés. Pour l’industrie maritime, l’enjeu est direct : mieux prévoir les pertes de performance, dimensionner les pièces avec des marges plus rationnelles et orienter le choix des formulations vers des solutions plus robustes ou plus réparables.
Nature Des microgels adhésifs agrègent les microplastiques pour faciliter leur extraction de l’eau
Une nouvelle approche exploite des microgels souples comme agents de capture capables d’adhérer à des microplastiques de nature variée et de favoriser leur rassemblement aux interfaces. Le principe repose sur des interactions multivalentes : au lieu de chercher une reconnaissance chimique unique, les particules de gel offrent une surface déformable capable de multiplier les contacts faibles avec des fragments de plastiques hétérogènes. Cette logique est particulièrement intéressante pour le traitement des eaux, car les microplastiques environnementaux présentent des morphologies, des charges de surface et des états d’oxydation très différents selon leur origine et leur vieillissement. Le système ne se limite donc pas à une famille de polymères idéale, mais vise une robustesse d’interaction dans un milieu complexe. Sur le plan des procédés, l’intérêt réside dans l’agrégation induite, qui transforme des particules dispersées et difficiles à retirer en ensembles plus manipulables par séparation interfaciale ou filtration. Le débouché industriel se situe dans les technologies de dépollution douce, avec un potentiel pour des modules compacts de traitement d’eaux usées ou d’effluents chargés en fragments plastiques.
https://advanced.onlinelibrary.wiley.com/doi/abs/10.1002/advs.75293
Des méthodes d’évaluation pour sécuriser les plastiques recyclés destinés aux emballages alimentaires
Une publication sectorielle récente met en avant un enjeu devenu central pour l’intégration de matières recyclées dans les emballages alimentaires : la capacité à démontrer, par des méthodes d’évaluation robustes, que les plastiques recyclés peuvent être employés sans compromettre la sécurité sanitaire. Le verrou ne réside pas seulement dans la qualité mécanique ou optique de la matière régénérée, mais dans la maîtrise des contaminants potentiels, de leur migration et de leur variabilité selon l’origine des déchets. Pour les polymères destinés au contact alimentaire, cette exigence impose une approche beaucoup plus fine que le simple contrôle de formulation : il faut qualifier le gisement, documenter les procédés de décontamination, vérifier l’aptitude au contact et établir des critères reproductibles de conformité. Ce type de démarche est particulièrement important pour le PET, mais il concerne plus largement toutes les filières qui ambitionnent d’introduire davantage de contenu recyclé dans des usages sensibles. Sur le plan industriel, la portée est majeure : sans outils d’évaluation crédibles, le recyclage alimentaire reste limité par la défiance réglementaire et la difficulté de preuve ; avec des méthodes stabilisées, il peut devenir une voie plus sûre pour concilier circularité, exigences sanitaires et montée en taux de matière recyclée.
L’Usine Nouvelle Journées scientifiques 2026 du GDR MultiPODE
GDR MultiPODE « Multifunctional nanostructured POlymer systems by DEsign » :
L’événement est gratuit (inscription obligatoire) et se tiendra les 15 et 16 juin 2026 à Paris, sur le campus des grands moulins, Université Paris Cité.
L’appel à communications est lancé. Date limite de soumission des résumés fixée au 30 avril.
Site web : https://multipode2026.sciencesconf.org/ lire plus…
Des chaînes dégradables conçues par métathèse alternée à partir de briques biosourcées
Une nouvelle approche permet de produire des matériaux dégradables à partir de monomères issus de la biomasse en mobilisant une copolymérisation alternée par ouverture de cycle de type métathèse entre des oxa-norbornènes biosourcés et le dihydrofurane. Le point fort du travail tient au fait que la déconstructibilité n’est pas ajoutée après coup sur une chaîne récalcitrante, mais inscrite dans l’ossature même du matériau par l’introduction maîtrisée de motifs énol-éther sensibles à l’acide. Cette stratégie de séquence alternée répond à une difficulté classique de la chimie des matériaux biosourcés : obtenir des chaînes à la fois solubles, bien définies et capables de se dégrader proprement en fragments dérivés des unités de départ. L’étude montre également que la régiosélectivité n’est pas laissée au hasard de la polymérisation, mais résulte d’un contrôle cinétique éclairé par le calcul, ce qui renforce la valeur prédictive de la méthode. En outre, la possibilité de régler les propriétés thermiques et mécaniques par le choix du substituant porté par l’oxa-norbornène élargit nettement le champ des applications. Cette contribution dessine ainsi une voie crédible vers des matériaux de spécialité où origine renouvelable, précision de structure et fin de vie chimique sont conçues comme un ensemble cohérent.
Nature Lorem ipsum dolor sit amet, consectetur adipiscing elit. Sed posuere tincidunt quam sit amet viverra. Nam in consequat nulla. Nunc rhoncus orci vitae arcu sagittis, in auctor nibh posuere. Donec ut nulla id enim tempor feugiat.
Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.
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Les partenaires
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LPMC
http://www.ispa.asso.fr
lrccp
http://www.ispa.asso.fr
ICS
https://www-ics.u-strasbg.fr/
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
Logo-ChemSuD
http://www.ispa.asso.fr
hutchinson
http://www.hutchinson.com/fr
arkema
http://www.coatex.com
cnrs
http://www.ispa.asso.fr
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