Le réseau

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L'organisation

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La structure de veille et de réflexion prospective

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Actualités

 

Conversion catalytique innovante du polyéthylène téréphtalate (PET) en composés valorisés

Une innovation récente révèle qu’une équipe a développé un procédé de recyclage chimique efficace du PET, en exploitant un système catalytique à base de chlorure de fer (III) associé à une amine et d’alcools comme agents de transestérification. Le procédé vise à couper sélectivement les liaisons ester caractéristiques du PET (bouteilles, déchets textiles), afin de produire des diesters de téréphtalate tels que le diméthyl téréphtalate, avec des rendements très élevés. Cette architecture catalytique abandonne l’usage d’acides ou de bases fortes, réduit la température d’opération et utilise un métal abondant, ce qui constitue une avancée sur les procédés classiques exigeant conditions sévères et matériaux coûteux. Le mécanisme s’appuie sur l’activation des esters intermédiaires par le fer et l’amine, suivie d’une substitution par l’alcool pour générer le diester, tandis que le matériau polymère initial est converti directement en matière première chimique de haut grade. L’intérêt technologique est double : d’une part, ce recyclage dit « chimique » permet une boucle circulaire des polyesters industriels, et d’autre part, il ouvre la voie à des filières ayant un potentiel industriel élevé en termes de valorisation de déchets plastiques. Cette méthode pourrait à terme réduire la dépendance aux ressources vierges et favoriser le développement de structures polymères régénérables à l’échelle industrielle.

https://phys.org/news/2025-11-pet-recycling-iron-catalyst-alcohols.html

40 ans d’innovation et de passion pour les polymères au LCPO

Depuis sa création en 1985, le LCPO a affirmé son positionnement à l’interface de la chimie macromoléculaire et des matériaux innovants, en mobilisant des architectures polymères conçues pour des applications allant de l’énergie aux matériaux pour le vivant. L’équipe du laboratoire explore des procédés de synthèse sobres et verts — incluant la chimie des polymères organiques, les formulations avancées et les caractérisations fines — pour générer des polymères ou copolymères dotés de propriétés fonctionnelles (conductivité, recyclabilité, biocompatibilité, dynamisme moléculaire). Sur le plan technologique, le LCPO a développé des partenariats industriels (notamment pour l’aéronautique ou les cosmétiques) et déposé plus de soixante brevets ces dernières années, ce qui témoigne de sa double orientation vers l’excellence académique et les usages applicatifs. Les architectures moléculaires conçues y sont souvent modifiées pour introduire des fonctions actives, des motifs réactifs ou des segments biosourcés, offrant ainsi des matériaux polymères « sur-mesure » dont les propriétés — mécanique, thermique, surface, recyclage — sont optimisées. Cette vision conduit à des solutions technologiques capables de répondre aux grands enjeux du XXIᵉ siècle : transition énergétique, économie circulaire, santé et bien-être, voire électronique souple. Ainsi, le LCPO incarne un laboratoire de recherche sur les polymères qui conjugue rigueur scientifique, stratégie d’innovation et mise en œuvre industrielle.
https://www.aquitaine.cnrs.fr/fr/cnrsinfo/40-ans-dinnovation-et-de-passion-pour-les-polymeres-au-lcpo

Libération de micro- et nanoplastiques à partir des matériaux au contact des aliments : état des connaissances

Une revue structurée des publications couvrant la période 2015–2025 a examiné la libération de micro- et nanoplastiques (MNP) à partir des matériaux de contact alimentaire (MCA) et révèle une évidence de libération de microplastiques, mais aussi de grandes incertitudes méthodologiques et analytiques. Il ressort que la majorité des études emploient des milieux simulant l’eau ou des liquides aqueux plutôt que des aliments solides, ce qui limite la pertinence industrielle ; les mécanismes identifiés incluent principalement l’abrasion ou la friction et la présence de structures ouvertes ou fibreuses dans les matériaux ; cependant les quantités réelles de libération sont probablement bien inférieures à celles rapportées dans nombre d’articles en raison de manques en fiabilité de préparation d’échantillons, de conditions de test non représentatives et de défaillances analytiques. À ce jour, il n’existe pas de base suffisante pour quantifier l’exposition aux MNP liée à l’usage des MCA. Enfin, cette revue met en avant des lacunes critiques : les données sur les nanoplastiques sont quasi nulles, les matériaux solides faiblement étudiés, et des recommandations sont formulées pour améliorer la standardisation des méthodes, l’analyse des particules, l’étude de la transformation des MCA en conditions réelles et l’évaluation toxicologique corrélée.

https://www.specialchem.com/plastics/news/literature-review-on-micro-and-nanoplastics-release-during-food-contact-material-use

Valorisation de déchets plastiques en catalyseur multifonction pour l’épuration de l’eau

Une équipe de recherche a démontré une voie innovante pour transformer des déchets de plastique en un matériau catalytique polyvalent dédié à l’épuration de l’eau. Les scientifiques ont mis au point un procédé de synthèse mécanochemique, utilisant un broyeur planétaire, combinant du dioxyde de molybdène (MoO₃) à du polypropylène usagé, afin de générer un composite constitué de bronze hydrogéné de molybdène (HₓMoO₃₋ᵧ), de MoO₂ et de carbone activé. Ce matériau déclenche à la fois des effets plasmoniques et photothermiques, assurant une absorption large du spectre solaire (UV-visible-infrarouge) et induisant un échauffement rapide, ce qui permet à la fois la photodégradation de polluants organiques, l’évaporation photothermique et l’adsorption d’ions métalliques lourds même en l’absence de lumière. Cette architecture moléculaire et composite marie des fonctions catalytiques acido-Brønsted, photothermiques et adsorbantes, offrant une solution technologique à faible coût et à grande scalabilité pour le traitement de l’eau. L’approche ouvre une nouvelle perspective industrielle : la conversion de plastiques jetés en matériaux actives pour la désalinisation, la purification de l’eau et plus largement pour des applications environnementales durables.

https://scitechdaily.com/from-plastic-to-pure-water-scientists-turn-trash-into-a-super-catalyst/

Une nouvelle étude met en évidence une atteinte artérielle spécifique chez les mâles exposés aux micro-plastiques

Une équipe de chercheurs de l’University of California, Riverside a démontré que l’exposition quotidienne à des fragments de polymères de taille microscopique, issus d’emballages, de textiles ou d’autres produits plastiques, peut accélérer la formation de plaques d’athérosclérose chez des souris mâles, tandis que les femelles ne présentaient pas d’aggravation équivalente. L’étude a utilisé un modèle murin prédisposé à l’athérosclérose, soumis à une dose environnementale de micro-plastiques pendant plusieurs semaines, et a montré que la charge lipidique sanguine et le poids corporel restaient inchangés, ce qui suggère que le mécanisme d’action ne passe pas par les voies métaboliques classiques. Des analyses de séquençage unicellulaire ont révélé que les cellules endothéliales, qui tapissent les vaisseaux, étaient particulièrement perturbées : les micro-plastiques se sont infiltrés jusqu’à la couche endothéliale, ont modifié l’expression de gènes pro-athérogènes et altéré la proportion de certains sous-types cellulaires impliqués dans l’inflammation vasculaire. Cette avancée souligne la dimension potentiellement directe des polymères de dispersion environnementale sur la santé cardiovasculaire et suggère un nouveau levier technologique et réglementaire : mieux intégrer l’impact des micro-plastiques à la conception, à la recyclabilité et à la gestion des matériaux polymères dans le but de limiter l’exposition humaine et ses effets à long terme.

https://www.eurekalert.org/news-releases/1106506

Nouvelle membrane hydrogel conducteur compatible avec les tissus mous

Une équipe de chercheurs de l’University of Groningen a mis au point un hydrogel polymère à la fois souple et hautement conducteur, visant à rapprocher les matériaux électroniques de la mécanique des tissus biologiques. Le procédé repose sur un substrat hydrogel poreux recouvert d’une fine couche de Polypyrrole appliquée par dépôt chimique en phase vapeur oxydative, ce qui permet de préserver l’élasticité et l’amplitude de déformation du gel tout en assurant une conductivité comparable à celle des métaux. Les architectures moléculaires du polypyrrole se structurent autour des pores du gel sans compromettre sa flexibilité, et les tests de compatibilité ont montré qu’il est favorable à la viabilité des cellules neuronales. Cette innovation ouvre des perspectives significatives pour des applications en bioélectronique souple — par exemple des capteurs implantables capables de détecter pression, activité musculaire ou cycle de cicatrisation — et elle contribue à franchir une étape technologique importante dans la conception d’interfaces homme-machine plus naturelles et durables.

https://www.eurekalert.org/news-releases/1106857

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Adhérez au GFP

Devenez un membre et découvrez les avantages d’un abonnement GFP.

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Sections locales GFP

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