Le réseau

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L'organisation

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La structure de veille et de réflexion prospective

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Actualités

 

Protocole standardisé pour l’extraction et la caractérisation des micro- et nanoplastiques dans les matrices environnementales

Des chercheurs ont mis au point un protocole systématique couvrant la prétraitement des échantillons, l’extraction en quatre étapes et la caractérisation qualitative et quantitative des micro- et nanoplastiques à partir de matrices environnementales variées. Le dispositif combine digestion chimique, séparation par densité, et techniques spectroscopiques avancées (ATR-FTIR, LDIR, O-PTIR), permettant une récupération et une pureté maximisées tout en minimisant les transformations artefactuelles. Ce cadre méthodologique cible les plastiques courants comme PE, PET, PP, PS et PMMA dans des tailles allant de la nano- à la microscale. En fournissant également des recommandations pour l’adaptation du protocole selon la complexité de l’échantillon et des conseils pour la validation via AFM ou cytométrie en flux, cette procédure favorise une comparaison inter-études plus rigoureuse. Fournir un tel standard répond à un besoin croissant de reproductibilité dans l’évaluation de la pollution plastique.

Biocomposites renouvelables à base de polysaccharides et caoutchouc naturel pour applications durables

Des chercheurs ont proposé une nouvelle voie vers des composites issus de ressources renouvelables en combinant des biopolymères naturels — notamment des dérivés de cellulose — avec du latex de caoutchouc naturel, de manière à obtenir des matériaux biodégradables tout en conservant des performances mécaniques compétitives. L’approche repose sur un renforcement interfacial actif : les nanocristaux de cellulose bien dispersés favorisent l’activation des sites de réticulation dans la matrice caoutchouc, améliorant l’organisation structurale à l’échelle nanométrique et réduisant la mobilité des chaînes polymères. Le matériau obtenu témoigne d’un compromis probant entre durabilité environnementale et solidité industrielle, ouvrant concrètement la voie à des alternatives biosourcées pour des pièces ou composants dans le domaine des polymères techniques.

Assemblages de micelles de copolymères en films de surface pour structurer des matériaux fonctionnels

Des chercheurs ont montré qu’en combinant des micelles de copolymères bloqués chimiquement distincts et en contrôlant leur auto-assemblage non-équilibré à la surface de films, on peut obtenir des architectures multi-composantes avec des motifs poreux et des distributions de chimie de surface réglables. Leurs analyses intègrent une segmentation par apprentissage automatique des images de microscopie électronique, ainsi que des simulations de dynamique brownienne et de Monte-Carlo et des analyses de type Voronoï, ce qui permet de relier directement les paramètres colloïdaux (taille, polydispersité, interactions micelle–micelle) à la morphologie finale du film. Cette approche ouvre la voie à la fabrication de films polymères multicouches aux propriétés de surface et de transport ciblées — notamment dans des domaines comme les membranes, les revêtements fonctionnels ou les interfaces capteurs — en faisant évoluer les principes familiers de l’alliage métallique vers la nanostructuration organique.

Photopolymérisation « tout-en-un » initiée par des points quantiques via transfert d’énergie triplet

Des chercheurs ont mis au point un procédé de photopolymérisation utilisant exclusivement des points quantiques colloïdaux (QDs) comme initiateurs, sans recourir à aucun co-additif ou donneur sacrificiel. Le processus repose sur un transfert d’énergie triplet (TET) des excitons photo-excités des QDs vers les états triplets des monomères acrylates, lesquels sont ensuite convertis en radicaux libres par interaction avec les liaisons pendantes des surfaces des QDs, déclenchant ainsi la propagation de chaînes. Ce mécanisme permet d’obtenir une polymérisation contrôlée, avec faible dispersion de masse moléculaire et capacité de synthèse de copolymères, tout en préservant l’émission des QDs et en améliorant leur stabilité dans les nanocomposites. En combinant la fonction d’initiation et l’intégrité optique des QDs, cette approche ouvre de nouvelles voies pour concevoir des systèmes polymères fonctionnels intégrant directement composants optiques ou photoniques, avec des applications potentielles dans l’affichage, le guidage d’ondes et l’impression 3D avancée.

Polyamide cristallin à haute température pour stockage capacitif et mécanique renforcée

Des chercheurs ont mis au point un film de polyamide cristallin entièrement organique conçu pour lever le compromis habituel entre robustesse mécanique et capacité de stockage d’énergie à haute température. En remplaçant les unités traditionnelles par des liaisons amide capables de former de nombreux liaisons hydrogène inter-chaînes, et en introduisant un diamine fluoré de structure torsadée pour augmenter la bande interdite, ils ont obtenu un matériau à haute cristallinité, orienté et compact. Par ailleurs, l’utilisation d’un procédé de complexation/décomplexation à base d’acide de Lewis a permis d’assurer un empilement optimal des chaînes pendant le traitements thermique. Le film abouti présente à la fois une résistance mécanique renforcée et un comportement diélectrique performant à haute température, ouvrant des perspectives nouvelles pour les films polymères utilisés en tant que diélectriques dans les systèmes de stockage d’énergie, les installations d’électronique de puissance ou les véhicules électriques.

Renforcement in situ à l’échelle nanométrique pour gels polymères ultra-performants

Des chercheurs ont montré qu’un ajustement fin de la cinétique de réticulation photo-induite entre deux phases polymères aux rigidités contrastées permet de générer des radicaux nitroxydes persistants qui consolident l’interface inter-phase et favorisent une transmission efficace des contraintes. Cette stratégie conduit à des hydrogels nettement plus résistants et plus tenaces, grâce à l’apparition d’une structuration nanométrique contrôlée au sein du réseau. En agissant directement sur la dynamique des réactions photochimiques, les auteurs parviennent à créer un maillage inter-phase actif capable de surmonter les limites mécaniques habituelles des gels monoréseaux. Les performances obtenues ouvrent la voie à des matériaux mous mieux adaptés aux exigences de l’ingénierie des tissus, de l’électronique souple ou d’autres dispositifs où robustesse et déformabilité doivent coexister dans des architectures polymères de nouvelle génération.

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Adhérez au GFP

Devenez un membre et découvrez les avantages d’un abonnement GFP.

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Sections locales GFP

Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.

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