Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Kirin et Japan Steel Works démontrent la dépolymérisation alcaline du PET sur extrudeuse bivis
Kirin Holdings, par l’intermédiaire de son Packaging Innovation Institute, et The Japan Steel Works ont testé une technologie de dépolymérisation alcaline du poly(éthylène téréphtalate) sur une extrudeuse bivis TEX αIII de dimension industrielle.
Lors de l’essai communiqué par les partenaires, plus de 95 % du PET est dépolymérisé avec un fonctionnement maintenu à un débit d’au moins 250 kg/h.
Les travaux portent sur le passage d’expériences antérieures à une configuration de production continue et sur l’utilisation d’un équipement d’extrusion industriel pour réaliser l’étape de dépolymérisation du PET.
Source : Kirin Holdings — Alkaline depolymerization technology for PET using twin screw extruder
JEPO 2026 – Prolongation des inscriptions jusqu’au 15 septembre
Il reste encore des places disponibles pour participer aux JEPO 2026.
Afin de permettre à davantage de participants de rejoindre l’événement, la date limite de dépôt a été repoussée au 15 septembre 2026.
Les personnes intéressées sont invitées à consulter le site de l’événement pour retrouver toutes les informations pratiques et les modalités de participation.
Date limite : 15 septembre 2026
Site de l’événement :
https://jepo2026.sciencesconf.org/
ACS Spring 2027 – Appel à communications sur les matériaux renouvelables
L’American Chemical Society Spring 2027 se tiendra du 21 au 25 mars 2027 à La Nouvelle-Orléans (Louisiane, États-Unis).
À cette occasion, les divisions Polymer Chemistry (POLY) et Cellulose and Renewable Materials (CELL) de l’ACS organisent conjointement le symposium :
“Advances in Renewable Materials: Functional Macromolecular Architectures from Renewable Feedstocks”
L’appel à communications est actuellement ouvert, avec une date limite de soumission des résumés fixée au 28 septembre 2026. lire plus…
Paris-Saclay et l’IMP Lyon révèlent l’organisation confinée de films minces de poly(liquides ioniques)
Des chercheurs du Laboratoire Léon Brillouin CEA-CNRS, du Laboratoire de Physique des Solides de l’Université Paris-Saclay, de l’Ingénierie des Matériaux Polymères à Lyon et du synchrotron SOLEIL analysent la structuration de films ultraminces de poly(liquides ioniques) à base de poly(1-vinyl-3-alkylimidazolium).
La réflectivité des rayons X et la diffraction en incidence rasante montrent que le confinement modifie l’organisation des chaînes et favorise une structuration lamellaire accompagnée d’une orientation préférentielle des groupes imidazolium. L’épaisseur du film intervient directement sur les distances caractéristiques de cette organisation.
Ces résultats sont particulièrement intéressants pour les électrolytes polymères, les revêtements ioniques et les dispositifs dans lesquels la mobilité des ions et le transport de charge dépendent fortement des interfaces et du confinement nanométrique.
Source : Macromolecules — Confined Interfacial Structure of Poly(ionic liquid) Thin Films
Une nanostructure de PVDF refroidit passivement les surfaces exposées au soleil
Une équipe du CSIC en Espagne a développé une architecture tridimensionnelle de PVDF capable de combiner forte réflexion solaire et émission infrarouge, avec une diminution de température pouvant atteindre 12,9 °C lors d’essais en extérieur.
Le refroidissement radiatif passif vise à évacuer la chaleur d’une surface vers l’espace sans utiliser de compresseur ni d’alimentation électrique. Pour fonctionner en plein jour, le matériau doit simultanément réfléchir une grande partie du rayonnement solaire incident et émettre efficacement son énergie thermique dans la fenêtre de transparence atmosphérique située entre 8 et 13 µm.
Amaia Iglesias-Elcano, Luis Moreno-Sanabria, Marisol Martín-González et Cristina V. Manzano, de l’Institut de micro- et nanotechnologie IMN-CNM du CSIC, ont exploité le fluorure de polyvinylidène comme matériau de base. Le polymère est infiltré dans des matrices tridimensionnelles nanoporeuses d’alumine anodisée, ce qui permet de contrôler sa géométrie à l’échelle nanométrique et de modifier ses propriétés optiques.
Après optimisation du procédé et refroidissement ultra-rapide, la structure autoportante présente une réflectance solaire moyenne de 82,4 % et une émissivité infrarouge de 96,7 % dans la fenêtre atmosphérique 8–13 µm. Les auteurs calculent une puissance théorique de refroidissement diurne de 182,3 W/m² pour une irradiance solaire de 1 000 W/m².
Lors d’essais réalisés en extérieur près de Madrid, avec une irradiance maximale de 962 W/m², le matériau traité par ultraviolet a atteint une température jusqu’à 12,9 °C inférieure à celle d’une boîte de référence vide. Le procédé reste à développer avant une utilisation à grande échelle, mais il ouvre des perspectives pour les toitures et façades, les véhicules, l’électronique ou d’autres applications nécessitant une gestion thermique sans consommation électrique directe.
Publication : Template-Assisted 3D-PVDF Nanonetworks for Passive Daytime Radiative Cooling, Nanophotonics.
Un réseau uréthane combine rigidité élevée et autoréparation à température ambiante
Des chercheurs de l’Université du Sichuan montrent qu’il est possible de concevoir un polymère vitreux très résistant tout en conservant une capacité d’autoréparation, grâce à une organisation coopérative de liaisons hydrogène.
Les matériaux polymères autoréparables reposent souvent sur des interactions dynamiques faibles capables de se rompre puis de se reformer. Cette mobilité facilite la cicatrisation, mais elle se traduit généralement par une diminution de la rigidité ou de la résistance mécanique. Le travail conduit par l’équipe de Jinrong Wu propose une stratégie permettant de contourner ce compromis.
Les chercheurs placent un accepteur faible, ici un groupe thioéther, à proximité de fonctions uréthane flexibles. Cette organisation, décrite comme un effet coopératif d’accepteur proximal, stabilise les liaisons hydrogène entre fonctions uréthane tout en créant simultanément des interactions thioéther–uréthane plus dynamiques.
Le réseau de poly(thioéther-uréthane) obtenu atteint une résistance à la traction de 79,5 MPa et un module de Young de 3,3 GPa. Malgré une température de transition vitreuse de 62,7 °C, le matériau est capable de récupérer complètement sa résistance en 70 minutes à température ambiante lorsque les surfaces endommagées sont remises en contact sous compression.
L’introduction des groupes thioéther apporte également une meilleure résistance à l’humidité : après 120 heures à 80 % d’humidité relative, le matériau conserve plus de 90 % de sa résistance et de son module. Cette architecture moléculaire offre ainsi une nouvelle voie pour développer des matériaux polymères à la fois rigides, résistants et réparables sans chauffage important.
Publication : Weak Acceptors Abnormally Reinforce Urethane Networks while Enabling Glassy-State Healability, Macromolecules.
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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Waters_logo_stacked_K_web-NEW
http://www.waters.com
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
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cnrs
http://www.ispa.asso.fr
lrccp
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arkema
http://www.coatex.com
LPMC
http://www.ispa.asso.fr
hutchinson
http://www.hutchinson.com/fr
ICS
https://www-ics.u-strasbg.fr/
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