Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Un catalyseur au bore détruit les PFAS en quelques secondes à température ambiante
Des chimistes de l’Université Goethe de Francfort ont mis au point un catalyseur boré capable de briser les très stables liaisons C–F des PFAS, molécules réputées « éternelles » pour leur résistance thermique et chimique. Le catalyseur, composé de deux atomes de bore insérés dans un squelette carboné, transfère efficacement des électrons—provenant pour l’instant du lithium—vers les liaisons C–F. Cette rupture se fait en quelques secondes, à température ambiante. Des travaux sont en cours pour remplacer le lithium par un courant électrique, simplifiant ainsi le procédé. Outre la dégradation des PFAS, cette stratégie ouvre la voie à un contrôle précis de la fluorination dans les molécules pharmaceutiques.
https://scitechdaily.com/new-catalyst-destroys-forever-chemicals-in-seconds/
Un catalyseur au cobalt surclasse le platine pour produire du propylène
Des chercheurs chinois ont développé un catalyseur zéolitique à base de cobalt (CoS-1) surpassant les performances du classique PtSn/Al₂O₃ pour la déshydrogénation du propane en propylène. Synthétisé par voie hydrothermale puis purifié pour ne conserver que des sites cobalt tétraédriques stables, CoS-1 atteint une productivité de 9,7 kgC₃/kg/h. Les simulations DFT révèlent que le cadre flexible de la zéolithe abaisse la barrière énergétique par effets entropiques, expliquant sa haute activité. Sa stabilité remarquable s’explique par une désorption rapide du propylène, limitant la formation de coke.
https://scitechdaily.com/the-new-king-of-propylene-cobalt-catalyst-outperforms-precious-metals/
Composites polymères pour des nanogénérateurs triboélectriques durables et imprimables
Des chercheurs de l’université de Boise State ont conçu un nanogénérateur triboélectrique (TENG) imprimé, souple et respectueux de l’environnement, en combinant un copolymère PVBVA avec des nanosheets de MXene (Ti₃C₂Tx). Ce composite, déposé par impression à partir d’encres éthanoliques, permet de convertir l’énergie mécanique issue du mouvement humain ou de l’environnement (pluie) en électricité, tout en assurant une fonction de capteur de mouvement en temps réel.
Avec une tension à vide de 252 V et une densité de puissance maximale atteignant 760 mW/m², cette architecture repose sur une forte polarisation interfaciale entre les charges de surface du MXene et la matrice polymère. Ce couplage assure une stabilité mécanique après plus de 10 000 cycles de flexion. L’intégration de l’électrode argentée et l’usage d’un procédé d’impression additive rendent le dispositif à la fois scalable et compatible avec des applications portables, sans solvants fluorés nocifs.
L’étude ouvre de nouvelles perspectives dans la conception de capteurs souples autonomes pour l’électronique portable, les interfaces homme-machine et la récupération d’énergie à faible impact environnemental.
Peaux polymères inspirées des céphalopodes pour l’affichage souple et les capteurs autonomes
Des chercheurs de l’Université du Nebraska ont développé des peaux synthétiques biomimétiques imitant les chromatophores des céphalopodes, ces organes pigmentaires musculaires responsables de leur capacité à changer de couleur. Composées de microgels élastomères assemblés en réseaux extensibles, ces structures polymères sont capables de changer de teinte et de motif de manière dynamique sous stimuli mécaniques ou environnementaux, sans apport énergétique externe.
Ces chromatophores synthétiques forment une classe émergente de matériaux dits « autonomes », capables de percevoir et de réagir à leur environnement, ouvrant la voie à des technologies souples pour la robotique douce, les capteurs portables et les interfaces homme-machine. Par programmation chimique, ils peuvent répondre à des paramètres comme la température, l’humidité ou le pH, tout en restant conformables, extensibles et fonctionnels en milieux aqueux. Cette avancée s’inscrit dans la perspective d’un affichage passif sans écran rigide, adaptable et multifonctionnel pour des applications biomédicales, environnementales ou embarquées.
https://phys.org/news/2025-06-cephalopod-synthetic-skins-enable-soft.html
Un plastique supramoléculaire soluble dans l’eau salée pour lutter contre les microplastiques
Des chercheurs du RIKEN au Japon ont mis au point un polymère supramoléculaire inédit capable de se dissoudre rapidement dans l’eau salée. Combinant du sodium hexamétaphosphate et des monomères à base de guanidinium, leur matériau forme des « ponts salins » assurant à la fois solidité mécanique et dégradabilité ciblée. Ces liaisons réversibles confèrent au polymère une grande résistance à sec, mais se rompent sous l’effet des électrolytes de l’eau de mer, permettant sa désintégration complète en moins de 9 heures. Ce plastique se distingue par sa transparence, sa stabilité thermique, sa non-inflammabilité et son aptitude à la recyclabilité moléculaire. En fin de vie, il libère des composés azotés et phosphorés non toxiques, valorisables biologiquement mais devant être maîtrisés pour éviter l’eutrophisation. Cette approche innovante marque une avancée majeure vers des plastiques marins biodégradables à haute performance, avec un potentiel de circularité par dépolymérisation contrôlée.
https://omnexus.specialchem.com/news/industry-news/new-plastic-that-dissolves-in-saltwater-000237407
Des pontons rotomoulés en PE recyclables pour une modularité sans limites
Rotax Marine innove dans les solutions flottantes en proposant une gamme de pontons et plateformes pour jetski rotomoulés en polyéthylène, résistants au milieu salin, fabriqués dans l’Ain. Grâce à une conception monobloc sans collage et à des connecteurs en TPV issus de l’automobile, ces structures offrent robustesse et adaptabilité. Assemblables sur mesure, transportables et garantes d’une durabilité de 8 ans, elles ciblent loisirs, ports, travaux maritimes ou collectivités.
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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hutchinson
http://www.hutchinson.com/fr
arkema
http://www.coatex.com
Logo-ChemSuD
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ICS
https://www-ics.u-strasbg.fr/
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lrccp
http://www.ispa.asso.fr
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LPMC
http://www.ispa.asso.fr
cnrs
http://www.ispa.asso.fr
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