Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
L’IPREM développe des latex aqueux biosourcés à partir d’un acrylate terpénique et d’une huile naturelle
Une collaboration impliquant Laurent Billon, professeur à l’Université de Pau et des Pays de l’Adour et chercheur à l’IPREM, UMR CNRS 5254, propose une voie de polymérisation aqueuse combinant un monomère acrylique d’origine terpénique et un tensioactif naturel extrait de graines d’Opuntia ficus-indica. Les procédés d’émulsion permettent de préparer des latex de polystyrène, de poly(acrylate de menthyle) et de leurs copolymères sous forme de particules sphériques de l’ordre de 70 à 200 nm. Les formulations optimisées atteignent des conversions allant jusqu’à 79 % sans coagulation et présentent une stabilité colloïdale prolongée. Ces travaux mettent en avant les compétences françaises de l’IPREM en polymérisation en milieu dispersé, colloïdes et matériaux macromoléculaires issus de ressources renouvelables.
Microsphères creuses en polyacrylate pour le refroidissement radiatif
Des microsphères creuses dotées d’une coque en poly(triméthylolpropane triacrylate) sont préparées avec un cœur volatil éliminé après polymérisation. Leur diamètre moyen est proche de 2 µm pour une paroi d’environ 50 nm. Incorporées dans un revêtement textile, elles combinent une réflectance solaire supérieure à 80 % et une émissivité infrarouge dépassant 90 %. Les essais en extérieur montrent un écart maximal de température de surface de 6,9 °C et une diminution de plusieurs degrés de la température au contact de la peau.
SpringerLink Ponts soufrés pour améliorer le transport de charges dans des polymères conjugués
Deux polymères conjugués comportant des motifs pontés par le soufre sont étudiés sous forme de films déposés sur des électrodes d’oxyde d’indium-étain. La microscopie à force atomique, la photoluminescence, la spectroscopie d’impédance et les mesures courant-tension mettent en évidence des différences d’organisation et de transport électronique. Le polymère présentant la conjugaison la plus étendue possède une bande interdite optique de 2,37 eV et une conduction améliorée. Les résultats relient directement la structure du squelette, l’empilement moléculaire et les propriétés électriques.
SpringerLink Polyuréthanes actionnables par la chaleur, la lumière et l’humidité
Des polyuréthanes contenant des segments polyéther ou polyester cristallisables et des unités azobenzène sont orientés par étirage à froid. Leur organisation interne commande ensuite les déformations produites par chauffage ou irradiation lumineuse. Les formulations contenant des segments de polyéthylène oxyde répondent également à l’humidité, avec une direction de courbure dépendant de l’état d’orientation du matériau. L’effet photothermique apparaît comme le principal moteur de l’actionnement sous lumière.
SpringerLink Déchets de coquillages utilisés comme renfort tribologique de résines époxy
Des poudres de coquillages riches en carbonate de calcium sont incorporées à une matrice époxy afin d’améliorer son comportement au frottement et à l’usure. Les essais montrent une augmentation de la résistance à l’usure et une diminution du coefficient de frottement jusqu’à une concentration optimale en charge. Au-delà de cette teneur, la dispersion et la cohésion du composite se dégradent. Le travail illustre la possibilité de transformer un déchet marin minéral en charge fonctionnelle pour des pièces soumises à des sollicitations tribologiques.
SpringerLink Protocole quantitatif pour évaluer l’hydrogénolyse des polyoléfines
La comparaison des procédés d’hydrogénolyse du polyéthylène et du polypropylène reste difficile en raison de la diversité des produits liquides, gazeux et solides formés. Le protocole proposé normalise la préparation des échantillons, la conduite des réactions, la séparation des fractions et leur quantification. Il met notamment l’accent sur l’établissement de bilans massiques complets et sur la distinction entre activité catalytique, sélectivité et distribution des masses moléculaires. Cette méthode doit faciliter la comparaison des catalyseurs et l’évaluation technico-économique des procédés de déconstruction des polyoléfines.
Nature Lorem ipsum dolor sit amet, consectetur adipiscing elit. Sed posuere tincidunt quam sit amet viverra. Nam in consequat nulla. Nunc rhoncus orci vitae arcu sagittis, in auctor nibh posuere. Donec ut nulla id enim tempor feugiat.
Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.
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Les partenaires
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arkema
http://www.coatex.com
LPMC
http://www.ispa.asso.fr
lrccp
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Logo-ChemSuD
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hutchinson
http://www.hutchinson.com/fr
cnrs
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ICS
https://www-ics.u-strasbg.fr/
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
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