Le réseau

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L'organisation

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La structure de veille et de réflexion prospective

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Actualités

 

Michelin quantifie les contraintes d’intégration des élastomères recyclés dans les enveloppes hautes performances

La restitution des travaux du consortium européen WhiteCycle, piloté par Michelin, formalise les verrous d’introduction des polymères recyclés (notamment le PET issu de textiles complexes et les élastomères dévulcanisés) au sein des structures de pneumatiques. Les corrélations mécaniques mettent en évidence une sensibilité accrue à la fatigue dynamique et une accélération de la dégradation thermo-oxydante dès lors que les seuils d’incorporation altèrent l’architecture macromoléculaire du réseau vulcanisé.

Une mousse à base de sciure et de cellulose explore une alternative au polystyrène expansé

La formulation étudiée associe de la sciure, des liants cellulosiques et de l’acide citrique comme agent de réticulation, avec des variantes utilisant carboxyméthylcellulose ou hydroxypropylcellulose pour ajuster la rigidité. Les mousses obtenues par congélation, lyophilisation puis traitement thermique présentent des réponses mécaniques modulables et une dispersion d’énergie encourageante lors d’essais d’impact, tandis qu’un revêtement à base de cire d’abeille améliore la résistance à l’eau. La portée est surtout exploratoire pour l’emballage ou certains usages du bâtiment : la mise à l’échelle, la tenue à l’humidité prolongée, la reproductibilité de la matière première et le bilan énergétique du procédé restent à établir.

https://www.acs.org/pressroom/presspacs/2026/june/sawdust-based-foam-alternative-to-polystyrene.html

L’IFPEN valide l’efficacité du screening pyrolytique rapide pour la caractérisation des flux complexes

Les récents benchmarks partagés par l’IFP Energies nouvelles valident l’utilisation de la pyrolyse flash couplée (technologie dérivée du Rock-Eval®) pour l’évaluation quantitative directe des microplastiques et polymères techniques au sein de matrices environnementales ou de flux de tri hétérogènes. L’apport par rapport aux cartographies micro-FTIR ou Raman réside dans la vitesse d’acquisition globale. Toutefois, la méthode étant destructive, sa fidélité analytique reste exposée aux artefacts générés par la pyrolyse concomitante de la matière organique naturelle ou des charges carbonées complexes, nécessitant des étapes amont de digestion chimique qui limitent pour le moment l’automatisation en continu sur les lignes de tri à haute cadence.

https://www.ifpenergiesnouvelles.fr/article/ifpen-au-congres-lastee-2026-comment-traiter-les-pfas

L’ICGM développe un contrôle cinétique pour bloquer la dépolymérisation des polysiloxanes fluorés techniques

Une étude peer-reviewed menée par l’Institut Charles Gerhardt de Montpellier (CNRS/ENSCM) décortique les mécanismes de transfert de chaîne intramoléculaire (« backbiting ») inhérents à la polymérisation par ouverture de cycle du (3,3,3-trifluoropropyl)méthylcyclotrisiloxane. L’introduction d’un co-monomère vinylique spécifique dès la phase d’amorçage permet de perturber la réversibilité thermodynamique du système, stabilisant le squelette macromoléculaire avant l’établissement de l’équilibre de cyclisation. Cette avancée affine la synthèse d’élastomères silicones à haute valeur ajoutée pour environnements extrêmes, bien que la sensibilité de la cinétique aux moindres gradients thermiques au sein du réacteur limite pour le moment sa transposition en dehors d’unités de production hautement instrumentées.

https://pubs.acs.org/doi/abs/10.1021/acs.macromol.6c00517

L’Institut Galien Paris-Saclay modélise les paramètres de diffusion lymphatique des promédicaments macromoléculaires

Les travaux publiés dans Advanced Healthcare Materials par l’Institut Galien Paris-Saclay (CNRS) établissent un cadre de modélisation mathématique prédictif destiné à optimiser le comportement pharmacocinétique de conjugués polymères-principes actifs administrés par voie sous-cutanée en oncologie. L’étude quantifie l’influence directe de la masse molaire moyenne et du rayon de gyration du squelette acrylique ou vinylique sur le temps de résidence local et le taux d’interception par le réseau lymphatique. Si la pertinence de la plateforme macromoléculaire est démontrée in vivo sur modèle animal, la transposition clinique reste conditionnée à la gestion de la variabilité histologique du tissu sous-cutané humain et aux contraintes de viscosité/seringabilité associées aux formulations hautement concentrées.

https://julien-nicolas.cnrs.fr/prodtoc.php

Des architectures D-A à niveau atomique étendent l’absorption optique au-delà de 2000 nm

Une étude publiée le 15 juin 2026 documente le développement de copolymères conjugués alternés donneur-accepteur (D-A) parvenant à repousser la limite d’absorption optique dans le domaine du proche infrarouge à ondes courtes (SWIR), au-delà de 2000 nm. La maîtrise de ces bandes interdites ultra-étroites repose sur une ingénierie moléculaire précise de la délocalisation électronique le long du squelette conjugué. L’intérêt applicatif cible directement les photodétecteurs organiques (OPD) et les capteurs d’imagerie avancés de nouvelle génération. Pour la physique des polymères, ce signal valide l’efficacité des approches de synthèse macromoléculaire pour concurrencer les semi-conducteurs minéraux traditionnels dans des domaines spectraux jusqu’ici techniquement inaccessibles aux matériaux souples.
https://doi.org/10.31635/ccschem.026.202607649

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Adhérez au GFP

Devenez un membre et découvrez les avantages d’un abonnement GFP.

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Sections locales GFP

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