Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Adhésif dégradable : une révolution pour le recyclage des emballages plastiques
Une équipe du Département de Chimie de l’Université de Reading a mis au point un nouvel adhésif polymère qui se décompose facilement lorsqu’il est traité avec des solutions basiques ou alcalines. Ce nouveau matériau, conçu pour coller fermement les étiquettes sur les bouteilles et autres emballages pendant leur utilisation, permet de retirer complètement les résidus d’adhésif lors du processus de recyclage. Publié dans Macromolecules (DOI: 10.1021/acs.macromol.4c02775), ce procédé innovant repose sur l’intégration d’unités sulfonyle éthyl uréthane dans une polyuréthane, agissant comme un interrupteur chimique déclenché par un environnement basique, réduisant jusqu’à 65 % la force d’adhérence. En facilitant l’élimination des étiquettes, cette technologie améliore la qualité des plastiques recyclés et pourrait transformer la gestion des déchets dans de nombreux secteurs industriels, allant des emballages alimentaires aux appareils électroniques.
https://phys.org/news/2025-02-plastic-bottles-easier-recycle-degradable.html
Polymère 2D à conduction métallique : une percée en électroplasturgie
Une équipe internationale, regroupant notamment des chercheurs de la TU Dresden et du Max Planck Institute, a synthétisé une forme ordonnée de polyaniline bidimensionnelle (2DPANI) qui présente des propriétés conductrices exceptionnelles. Ce matériau innovant offre une conductivité anisotrope de 16 S/cm dans le plan et de 7 S/cm en travers des couches, avec des mesures en courant continu atteignant jusqu’à 200 S/cm. Ces résultats témoignent d’un comportement de transport de charge typiquement métallique, notamment par conduction tridimensionnelle, et ouvrent ainsi de nouvelles perspectives pour le développement d’électroniques organiques, le blindage électromagnétique et la technologie des capteurs. Selon Thomas Heine, responsable de la chimie théorique à la TU Dresden, cette avancée représente une percée fondamentale dans la recherche sur les polymères conducteurs, en permettant de remplacer les métaux par des alternatives organiques performantes.
https://omnexus.specialchem.com/news/industry-news/polymer-with-metal-like-conductivity-000236333
Zwitterions : la solution « Goldilocks » pour des implants sans caillots
Des chercheurs de l’Université de Sydney explorent l’utilisation de revêtements zwitterioniques pour prévenir la formation de caillots sanguins sur les implants médicaux, notamment les valves cardiaques et les stents. Ces molécules, naturellement présentes dans les membranes cellulaires, possèdent à la fois une charge positive et négative, ce qui leur confère une neutralité globale et une forte affinité pour l’eau. En créant un mince revêtement de quelques nanomètres, les scientifiques parviennent à générer une couche d’eau protectrice à la surface des implants. Cette « armure aqueuse » empêche l’adhérence des protéines du sang, réduisant ainsi le risque de thrombose, tout en améliorant la longévité des dispositifs implantables. Le défi, qualifié de « problème Goldilocks », consiste à déterminer la quantité idéale de zwitterions à appliquer, ni trop, ni trop peu, pour optimiser leur efficacité sans provoquer d’effets indésirables. Les travaux, publiés dans Cell Biomaterials (DOI : 10.1016/j.celbio.2024.100005), offrent un plan détaillé pour le développement de surfaces anti-caillots et ouvrent de nouvelles perspectives pour la conception d’implants plus sûrs et durables.
https://www.eurekalert.org/news-releases/1074179
Mycofluid : une alternative compostable aux plastiques grâce aux résidus de café et aux spores de Reishi
Des chercheurs de l’Université de Washington ont développé un procédé innovant permettant de transformer les marc de café usagés en une pâte biodégradable, baptisée « Mycofluid ». Cette pâte, obtenue en mélangeant marc de café, farine de riz complet, spores de champignon Reishi, gomme xanthane et eau, est utilisée pour l’impression 3D d’objets. Après impression, les pièces sont inoculées avec des spores de Reishi, qui forment une fine couche de mycélium – un réseau ressemblant à des racines – enveloppant les structures imprimées. Ce revêtement mycélien confère aux objets une résistance comparable à celle du polystyrène expansé, tout en étant entièrement compostable. Idéal pour remplacer des emballages tels que le Styrofoam, ce procédé offre une solution personnalisable et durable pour les petites productions, notamment pour des emballages sur mesure destinés aux petites entreprises.
Revêtement transparent superhydrophile pour séparation durable huile/eau
Des chercheurs ont développé un revêtement innovant, intégrant une interphase inspirée par les moules et une couche composite double constituée de nanofibres de cellulose rigides et de carbonate de calcium amorphe, permettant de créer une surface superhydrophile aux propriétés anti-encrassement par huile exceptionnellement persistantes sur divers substrats. Ce revêtement, grâce à l’interconnexion étroite entre l’intercouche adhésive et la couche externe hautement hydratée, empêche efficacement l’encrassement par divers types d’huile, que ce soit dans des environnements pré-humidifiés ou déjà contaminés, garantissant ainsi une séparation efficace et durable des émulsions huile/eau sans déclin significatif du flux, avec un taux de récupération du flux proche de 100 %. De plus, le revêtement présente des propriétés antifogging et une grande transparence, ouvrant la voie à des applications potentielles dans des dispositifs optiques, tout en répondant aux besoins d’une séparation à long terme dans des conditions industrielles sévères.
Hydrogels d’ADN innovants pour une libération prolongée de médicaments
Des chercheurs de l’Université de Tokyo ont développé des hydrogels d’ADN optimisés à partir de nanostructures en forme de Takumi, minimisées pour n’utiliser que deux oligonucléotides (ODN) par unité, soit seulement 68 nucléotides au total. Cette approche, détaillée dans le Journal of Controlled Release (DOI : 10.1016/j.jconrel.2024.11.052), permet de former des hydrogels biocompatibles et injectables présentant une rétention prolongée in vivo, comme démontré par des expériences chez la souris où le gel contenant de la doxorubicine a persisté au moins 168 heures et induit des effets antitumoraux significatifs. En réduisant les coûts de préparation et le risque d’effets hors cible par rapport aux méthodes antérieures (par exemple, les hydrogels à base de hexapodna), cette stratégie promet d’améliorer l’efficacité des systèmes de délivrance de médicaments et d’ouvrir la voie à des applications dans la libération ciblée d’antigènes et d’autres biomolécules.
https://www.eurekalert.org/news-releases/1073422
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.
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Les partenaires
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ICS
https://www-ics.u-strasbg.fr/
hutchinson
http://www.hutchinson.com/fr
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
lrccp
http://www.ispa.asso.fr
cnrs
http://www.ispa.asso.fr
LPMC
http://www.ispa.asso.fr
arkema
http://www.coatex.com
Logo-ChemSuD
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
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