Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Le CEA réussit l’imprégnation de mousses polymères imprimées en 3D par de l’hydrogène liquide
Les équipes du Département des Systèmes Basses Températures du CEA-Irig à Grenoble, unité associant le CEA et l’Université Grenoble Alpes, ont réalisé avec GenF une première imprégnation réussie de mousses micrométriques obtenues par polymérisation à deux photons avec de l’hydrogène liquide, suivie de sa solidification.
Ces architectures polymères tridimensionnelles sont produites par polymérisation à deux photons avec un contrôle précis de leur géométrie et de leur densité. Le dispositif expérimental CHIMERA permet désormais d’étudier comment la microstructure des mousses influence la progression du front d’imprégnation et l’homogénéité du remplissage.
Le développement constitue une étape importante vers la maîtrise de cibles cryogéniques structurées pour la fusion inertielle.
Source : CEA-Irig — First impregnation of 2PP foams with liquid hydrogen: a step toward inertial fusion
La morphologie des micelles de copolymères blocs pilote leurs cinétiques de fusion et de fragmentation
Une collaboration impliquant plusieurs équipes françaises, notamment Grenoble INP, l’Université Grenoble Alpes, le CNRS, le CERMAV et l’Institut des Sciences Chimiques de Rennes, étudie la dynamique d’échange au sein de micelles de copolymères triblocs de type Pluronic.
En combinant fluorescence résolue en temps et contrôle de la morphologie des agrégats, les auteurs montrent que le passage de micelles sphériques à des structures cylindriques modifie profondément les mécanismes de fusion et de fragmentation. La vitesse de fragmentation diminue lorsque la température augmente, tandis que la fusion évolue différemment selon la géométrie des micelles.
Le travail met en évidence le rôle conjoint de l’interface cœur-solvant et de l’encombrement stérique des couronnes de poly(oxyde d’éthylène) dans la dynamique des assemblages supramoléculaires.
Envalior et SECARA développent une boucle de recyclage chimique du PA6 automobile
Envalior et la société technologique SECARA travaillent à la transformation de plastiques issus de véhicules en fin de vie en nouvelles matières PA6 destinées à des applications automobiles.
Le procédé développé par SECARA repose sur une dépolymérisation catalytique visant à produire du caprolactame de haute pureté pouvant être réintroduit directement dans les installations existantes de polymérisation du PA6 d’Envalior. La technologie est étudiée sur des flux complexes pouvant contenir fibres de verre, retardateurs de flamme et différents additifs.
Les partenaires évaluent également la récupération des fibres. L’objectif est de produire des grades techniques comportant une fraction post-consommation tout en conservant les performances requises pour les applications automobiles.
Source : Envalior — Circular PA6 for automotive applications
Un réseau polymère adaptable permet de récupérer les constituants de circuits imprimés haute performance
Une équipe de l’Université du Zhejiang développe une matrice époxy à réseau covalent adaptable intégrant des motifs dithiokétal encombrés par des groupes gem-diméthyle.
Cette architecture maintient les performances thermiques, mécaniques et électriques nécessaires à un circuit imprimé tout en empêchant les réactions d’échange indésirables pendant son utilisation. En fin de vie, une oxydation sélective permet au contraire de dégrader volontairement le réseau.
Les chercheurs récupèrent ainsi le cuivre avec une pureté annoncée de 99,5 %, les fibres de verre et une fraction issue de la résine, cette dernière pouvant être réutilisée comme adhésif. L’approche illustre une stratégie de conception particulièrement intéressante : rendre un thermodurcissable chimiquement stable pendant son service mais sélectivement démontable lorsque le recyclage devient nécessaire.
Des triblocs polyesters biosourcés sont dépolymérisés en monomères puis repolymérisés
Kai Ma, Tie-Qi Xu et leurs coauteurs utilisent plusieurs δ-valérolactones biosourcées pour construire par polymérisation par ouverture de cycle des polyesters triblocs constitués de segments présentant des comportements thermomécaniques différents.
La polymérisation permet de contrôler l’enchaînement des blocs et de faire varier la composition afin d’obtenir, selon les formulations, des comportements allant de l’élastomère au thermoplastique.
Après usage, les polyesters étudiés peuvent être convertis en leurs monomères cycliques de départ, y compris à partir de mélanges de polymères, puis ces monomères sont réutilisés pour une nouvelle polymérisation.
Syensqo ajoute une ligne de compounding pour PPS, PEEK, PPA et PARA en Inde
Syensqo prévoit l’installation d’une nouvelle ligne de compounding sur son site de Panoli, en Inde, pour transformer localement plusieurs familles de polymères aromatiques : PPS, PEEK, PPA et PARA.
L’équipement doit doubler la capacité actuelle de compounding du site et constitue le premier élément d’un ensemble modulaire prévu pour permettre des extensions ultérieures.
Source : Syensqo — Syensqo brings aromatic compounding capability to India
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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hutchinson
http://www.hutchinson.com/fr
lrccp
http://www.ispa.asso.fr
cnrs
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ICS
https://www-ics.u-strasbg.fr/
Waters_logo_stacked_K_web-NEW
http://www.waters.com
Logo-ChemSuD
http://www.ispa.asso.fr
arkema
http://www.coatex.com
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
LPMC
http://www.ispa.asso.fr
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