Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Du marc de café et du plastique pour capter le CO₂ : une innovation brevetée à l’Université de Sharjah
Des chercheurs de l’Université de Sharjah ont mis au point et breveté une technologie de capture du dioxyde de carbone (CO₂) fondée sur la valorisation simultanée de deux déchets abondants : le marc de café usagé et le polyéthylène téréphtalate (PET). Le procédé repose sur une co-pyrolyse à 600 °C en présence d’hydroxyde de potassium (KOH), qui active la formation d’un charbon poreux hautement performant capable d’adsorber le CO₂ émis par les procédés industriels. Cette approche, à la fois sobre en énergie et circulaire, convertit des flux polluants en ressource fonctionnelle : le marc de café — dont huit millions de tonnes sont jetées chaque année — et le PET des emballages plastiques deviennent ainsi les précurseurs d’un charbon activé à grande surface spécifique, optimisé pour la capture de gaz et la purification de l’air ou de l’eau. Selon la chercheuse Haif Aljomard, cette technologie « transforme une tasse de café et une bouteille d’eau en outil contre le changement climatique ». Outre la séquestration du CO₂, le matériau obtenu pourrait être déployé dans des filtres industriels, systèmes d’épuration, traitements d’effluents ou procédés énergétiques, offrant une solution polyvalente et économique pour réduire les émissions et limiter la mise en décharge des déchets. Cette innovation illustre parfaitement la logique de l’économie circulaire appliquée à la chimie des matériaux, conciliant gestion des déchets, transition énergétique et ingénierie du carbone.
https://phys.org/news/2025-10-coffee-plastic-climate-solution.html
DopeBot : une IA pour concevoir les polymères conducteurs de la bioélectronique du futur
Des chercheurs de l’Université d’État de Caroline du Nord et d’Iowa State University ont développé DopeBot, un système expérimental piloté par intelligence artificielle capable d’explorer systématiquement la manière dont la dopage moléculaire modifie les propriétés électroniques des polymères conjugués. L’objectif est d’optimiser des matériaux polymères destinés à la bioélectronique et aux dispositifs hybrides organiques, où les matériaux doivent combiner conductivité, stabilité et compatibilité biologique. Le robot expérimental a réalisé plus de 200 essais de dopage sur le polymère semi-conducteur pBTTT avec l’agent F4TCNQ, en faisant varier des paramètres tels que le solvant et la température. L’algorithme a ensuite corrélé les structures moléculaires obtenues aux performances électroniques mesurées, avant de raffiner les expériences suivantes. Les analyses combinées, incluant des calculs quantiques menés à NC State, ont révélé que la position des dopants au sein de la matrice polymère et l’ordre local des chaînes jouent un rôle clé dans la conductivité obtenue. Ces résultats, publiés dans Matter, permettent de relier de manière causale les conditions de traitement à la structure électronique des polymères, ouvrant la voie à une ingénierie prédictive des matériaux organiques. L’équipe travaille déjà à la conception de nouveaux polymères destinés à des applications biomédicales et neurosensorielles, démontrant comment l’intelligence artificielle peut accélérer la découverte de matériaux polymères fonctionnels adaptés aux technologies émergentes de l’électronique douce.
https://phys.org/news/2025-10-ai-based-insights-polymers-generation.html
K 2025 : le rendez-vous mondial de l’innovation plastique s’ouvre à Düsseldorf
Le salon international K 2025, plus grand événement mondial consacré aux plastiques et aux caoutchoucs, a ouvert ses portes à Düsseldorf pour huit jours dédiés à l’innovation, à la durabilité et à la transformation de l’industrie. Sous le slogan « The Power of Plastics! Green – Smart – Responsible », l’édition 2025 met en avant trois axes majeurs : l’économie circulaire, la numérisation et la responsabilité sociale. Avec 3 257 exposants issus de 66 pays, l’événement réunit toute la chaîne de valeur — des fabricants de machines aux producteurs de matières premières, en passant par la recherche et les services. Le pavillon spécial Plastics Shape the Future (hall 6) illustre la mutation du secteur vers une production plus durable, tandis que la Startup Zone (hall 7) met en lumière vingt jeunes entreprises explorant l’IA, les bioplastiques et les procédés numériques pour une économie circulaire. Les États-Unis y affichent une forte présence avec 84 exposants répartis sur deux pavillons, soutenus par le Département du commerce américain. Le salon intègre également des initiatives concrètes de durabilité, comme un système de gobelets réutilisables et une Career Day pour les jeunes talents. Véritable baromètre mondial du secteur, K 2025 confirme le rôle central des polymères dans la transition écologique et technologique de l’industrie.
https://www.plasticstoday.com/business/k-2025-opens-global-plastics-innovation-showcase
Conversion électro-biocatalytique du carbone océanique en précurseurs de bioplastiques pour une chimie circulaire du carbone
Cette étude présente une approche intégrée exploitant le carbone inorganique dissous dans l’eau de mer comme nouvelle ressource pour la production durable de monomères biosourcés. En combinant une étape électrochimique de capture et de réduction du CO₂ avec une conversion biologique réalisée par des micro-organismes, le système transforme directement le carbone océanique en acides organiques utiles à la synthèse de bioplastiques. L’utilisation d’un catalyseur au bismuth permet une réduction sélective du CO₂ en acide formique, ensuite métabolisé par Vibrio natriegens pour produire de l’acide succinique, un intermédiaire clé des polyesters biodégradables. Ce couplage entre électrochimie et biocatalyse contourne les contraintes énergétiques et les faibles concentrations de carbone typiques du milieu océanique tout en maintenant la compatibilité avec des procédés à grande échelle. En s’appuyant sur des sources d’électricité renouvelable, cette stratégie illustre la possibilité d’une valorisation directe du puits de carbone marin, ouvrant la voie à une filière circulaire reliant capture de CO₂, synthèse de monomères et production de polymères biosourcés à faible empreinte carbone.
Nature Dépolymérisation douce des polyamides par alcoolyse activée au tosylate de méthyle pour un recyclage en boucle fermée
L’étude introduit une voie de recyclage chimique des polyamides fondée sur l’alcoolyse sous conditions modérées, activée par le tosylate de méthyle (TsOMe) qui génère in situ l’acide p-toluenesulfonique (TsOH) pour cliver sélectivement la liaison C–N amide. Appliquée à des PA vierges et post-consommation (PA6, PA66, PA610, PA11/12, renforts verre), ainsi qu’à des flux mixtes, la méthode convertit efficacement les chaînes en précurseurs de haute valeur — esters d’acides aminés, diesters/diamines tosylés — et, pour PA6, en ε-caprolactame via une cyclisation basique en cascade, ouvrant la voie à une véritable boucle fermée (repolymérisation en PA « vierge »). Le criblage d’alcools montre que les primaires aliphatiques sont privilégiés, tandis que les alcools secondaires/benzyliques favorisent des voies concurrentes de déshydratation et d’hydrolyse, surmontées par un simple reconditionnement. Des essais sur déchets mélangés (PA avec PE/PP/PS ou textiles PET/PA) attestent d’une compatibilité élevée et d’une séparation aisée des produits par différences de solubilité, y compris après co-dépolymérisation PA6/PA66. Les calculs DFT et études cinétiques étayent un mécanisme d’activation acide avec formation d’un intermédiaire tétraédrique par attaque nucléophile de l’alcool, TsOH jouant un double rôle d’activateur d’amide et de piégeur de l’amine libérée. L’ensemble démontre une chimie de dépolymérisation sélective, tolérante aux additifs et transposable à l’échelle, avec possibilité de régénération du TsOMe, positionnant cette stratégie comme une alternative durable aux procédés hydrolytiques ou supercritiques pour la valorisation des polyamides.
Nature Le PEPR Recyclage amorce une nouvelle phase stratégique pour l’économie circulaire des plastiques
Le Programme et Équipements Prioritaires de Recherche (PEPR) Recyclage, lancé dans le cadre de France 2030, entame une nouvelle étape avec un changement de direction scientifique. Ce programme, piloté conjointement par le CNRS, le CEA et l’Ademe, vise à structurer la recherche française sur le recyclage des matériaux — plastiques, composites, métaux et textiles — autour d’approches disruptives alliant chimie, procédés, et intelligence artificielle. L’objectif est de faire émerger des technologies de rupture capables d’atteindre un recyclage véritablement circulaire et bas carbone, en particulier pour les polymères complexes et les flux hétérogènes. Cette transition marque un recentrage sur la valorisation chimique avancée, l’écoconception des matériaux et la modélisation multi-échelle des procédés. Le PEPR entend ainsi renforcer les synergies entre laboratoires académiques, centres techniques et industriels afin d’accélérer le passage des innovations de la recherche fondamentale à l’échelle pilote et industrielle.
PEPR Recyclage Lorem ipsum dolor sit amet, consectetur adipiscing elit. Sed posuere tincidunt quam sit amet viverra. Nam in consequat nulla. Nunc rhoncus orci vitae arcu sagittis, in auctor nibh posuere. Donec ut nulla id enim tempor feugiat.
Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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