Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Une coopération franco-japonaise dynamique autour des polymères
Relancée après la pandémie, la collaboration entre le Groupe français des polymères (GFP) et la Société japonaise des sciences polymères (SPSJ) s’intensifie, avec un second colloque bilatéral organisé en juillet 2025 à Kitakyūshū. Portée par des chercheurs de Montpellier (ICGM) et d’universités japonaises, cette coopération met en avant des approches complémentaires et vise des thématiques d’avenir comme les vitrimères, le recyclage et la fin de vie des polymères. La France y est reconnue comme un acteur scientifique de premier plan.
Vers de nouveaux polymères biodégradables grâce aux cétones cycliques acétales
Des chercheurs de l’Université Doshisha ont étudié des cétones cycliques acétales (CKA), monomères capables de subir une polymérisation radicalaire par ouverture de cycle (RROP), afin de concevoir des polyesters dégradables. En caractérisant un monomère substitué (5a) par RMN et tests de biodégradabilité (OCDE 301F), ils ont montré un taux de dégradation de 20 % (contre 40 % pour la cellulose) et une faible rétention de cycle (<10 %). L’introduction d’un modèle cinétique basé sur la DFT a permis de relier structure, réactivité et dégradabilité. Ces résultats ouvrent la voie à la conception rationnelle de polymères biodégradables pour l’emballage, l’agriculture et le biomédical.
https://phys.org/news/2025-09-explore-strategies-environmentally-safe-polymer.html
Des déchets plastiques au captage du CO₂ : une avancée prometteuse avec le matériau BAETA
Des chimistes de l’Université de Copenhague ont développé un procédé d’upcycling du PET (bouteilles, textiles) en un nouveau matériau baptisé BAETA, capable de capturer efficacement le CO₂. Ce MOF organique modifié, issu de PET dégradé et fonctionnalisé par de l’éthylènediamine, présente une forte affinité pour le CO₂ et une bonne régénérabilité thermique. Stable de la température ambiante jusqu’à 150 °C, il est parfaitement adapté aux flux chauds des usines industrielles. Ce procédé doux, peu énergivore, cible les déchets plastiques non recyclables, et ouvre la voie à une double valorisation environnementale : dépollution plastique et atténuation climatique.
https://www.sciencedaily.com/releases/2025/09/250905180736.htm
Un catalyseur au cuivre transforme le CO₂ en polymères fonctionnels sous conditions douces
Au Songshan Lake Materials Laboratory, des chercheurs ont développé une méthode de polymérisation multicomposant catalysée par CuCl/PPh₃ permettant d’incorporer efficacement le CO₂ dans des poly(alkynoates) à température ambiante et pression atmosphérique. Les polymères obtenus présentent des masses molaires élevées (jusqu’à 94 000 g·mol⁻¹), une large compatibilité de monomères et des rendements proches de 99 %. Ces matériaux, solubles et facilement post-fonctionnalisables, offrent des applications variées (capteurs fluorescents, sondes biomédicales, emballages durables). Cette approche associe séquestration du carbone et chimie verte, ouvrant la voie à une valorisation industrielle du CO₂ dans une logique d’économie circulaire du carbone.
Des microplastiques identifiés pour la première fois dans des tissus cérébraux humains
La neuropathologiste Elaine Bearer (Université du Nouveau-Mexique) a mis au point une méthode de microscopie confocale permettant de visualiser des micro- et nanoplastiques dans des cerveaux humains, notamment de patients atteints de démence. Ses analyses montrent que les tissus associés à la démence contiennent environ cinq fois plus de microplastiques que les échantillons témoins. Les particules observées, de taille nanométrique, échappaient jusqu’ici aux techniques classiques d’imagerie. Prochaine étape : tenter de les détecter in vivo par IRM et spectroscopie RMN, afin de corréler charge plastique cérébrale et pathologies neurodégénératives.
Vers des plastiques durables grâce à des briques moléculaires soufrées prédictives
Une équipe internationale menée par l’Université de Bayreuth a établi une règle prédictive permettant d’identifier quels monomères soufrés conduisent à des polymères propres et bien structurés. Le soufre introduit dans la chaîne polymère fragilise les liaisons C–S, facilitant la dégradabilité sous conditions douces. L’étude, publiée dans Angewandte Chemie, met en avant le sulfure de carbonyle (COS) comme brique idéale : il polymérise de façon fiable avec peu de catalyseur et génère peu de sous-produits. Ces travaux ouvrent la voie à la synthèse standardisée de polymères soufrés durables et recyclables.
https://phys.org/news/2025-09-reveals-sulfur-based-blocks-sustainable.html
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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https://www-ics.u-strasbg.fr/
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