Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Stéréochimie du cyclohexanediméthanol et photostabilité des copolyesters PETG
Une série de copolyesters PETG contenant entre 67 et 99 % de la configuration trans du 1,4-cyclohexanediméthanol a été préparée par polycondensation en masse. L’étude relie directement la stéréochimie du comonomère à la température de transition vitreuse, à la stabilité thermique et au comportement sous irradiation ultraviolette. L’exposition aux UV provoque une isomérisation progressive des unités trans vers la configuration cis, accompagnée d’une évolution des propriétés mécaniques et de la viscosité intrinsèque. Le contrôle du taux d’isomère trans constitue ainsi un paramètre de formulation permettant d’accroître la résistance au vieillissement lumineux des copolyesters PETG.
Nature Structuration sous écoulement de suspensions de carbonate de calcium renforcées par des fibres de polyamide
Une équipe associant l’Université Côte d’Azur, le CNRS et le CEA étudie l’influence de fibres de polyamide sur l’épaississement discontinu sous cisaillement de suspensions concentrées de carbonate de calcium. Les chercheurs comparent une rhéométrie rotationnelle en géométrie de Couette à un écoulement capillaire piloté en pression. L’augmentation de la concentration en fibres modifie la réponse rhéologique et, aux concentrations les plus élevées étudiées, renforce la résistance à l’écoulement dans le capillaire. Les résultats mettent en évidence la formation de structures couplées entre particules minérales et fibres, apportant de nouvelles données pour la formulation et la mise en œuvre de suspensions composites concentrées.
SpringerLink Poly(ester amide)s biosourcés combinant propriétés mécaniques, auto-réparation et recyclage chimique
Les travaux publiés dans JACS décrivent une famille de poly(ester amide)s aliphatiques préparés à partir d’huiles végétales non alimentaires, d’acides aminés et de précurseurs issus de sucres. La synthèse repose sur une polymérisation par métathèse de diènes acycliques suivie d’une hydrogénation, conduisant à des matériaux de masse molaire élevée. Les films obtenus présentent une combinaison de résistance à la traction et d’allongement à la rupture, tandis qu’une composition intégrant de la phénylalanine possède une capacité d’auto-réparation à température ambiante. Les liaisons ester permettent également une dépolymérisation sélective par transestérification en présence d’alcools, ouvrant une voie de récupération des constituants moléculaires.
Emballage souple alimentaire contenant 75 % de matière issue du recyclage chimique
Une chaîne industrielle réunissant producteur de résines, fabricant de films, transformateur et utilisateur final a développé un emballage de tablette de chocolat contenant 75 % de matière recyclée. Les résines CirculenRevive sont produites à partir de déchets plastiques post-consommation mixtes convertis par recyclage chimique, avec attribution du contenu recyclé selon une méthode de bilan massique certifiée ISCC PLUS. La résine est transformée en film puis en emballage souple destiné au contact alimentaire, démontrant l’intégration de matières premières circulaires dans une structure d’emballage commerciale.
Accélération de l’hydrolyse du PLA via des anhydrides organiques cycliques
Une étude parue dans ACS Central Science présente une formulation du poly(acide lactique) (PLA) intégrant de faibles fractions d’anhydrides organiques agissant comme des acides masqués. L’additif s’hydrolyse de manière autocatalytique en conditions de compostage industriel, accélérant la scission des liaisons ester de la matrice sans altérer sa clarté optique originelle.
Insertion d’unités alkoxycarbonylméthylène pour la déconstruction des chaînes carbonées
L’Université d’Ehime a publié des travaux sur l’insertion contrôlée d’unités alkoxycarbonylméthylène au sein de polymères issus de polymérisation radicalaire (PS, PMMA). Ces motifs agissent comme des points de rupture activables par clivage basique via une réaction de type rétro-Michael, fragmentant des chaînes persistantes en oligomères hydrosolubles.
https://phys.org/news/2026-07-polymer-everyday-plastics-easier.html
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.
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Logo-ChemSuD
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ICS
https://www-ics.u-strasbg.fr/
LPMC
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arkema
http://www.coatex.com
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cnrs
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http://www.waters.com
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