Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Réseau PVA–SPPESK à volume libre optimisé et photothermie sélective pour des revêtements anti-buée durables et transparents
Les auteurs proposent une architecture polymère qui combine une matrice hydrophile à liaisons hydrogène (polyvinylalcool) et des segments sulfonés à géométrie torsadée non coplanaire (SPPESK) afin d’augmenter le volume libre interne sans épaissir le film, stabiliser l’adhésion interfaciale et maintenir la transparence; cette conformation favorise un maillage dense de liaisons H et engendre une distribution bimodale de cavités, couplant des pores « piégeurs » nanométriques (rétention d’eau non givrante) et des canaux de diffusion (apport rapide), ce qui supprime la nucléation de microgouttes au profit d’un film continu même sous cycles humidité/séchage; l’intégration de nanocristaux de bronze tungstate césium (CTB) ajoute une photothermie sélective UV/NIR tout en préservant la transmission visible, convertissant une part significative du spectre solaire en élévation locale de température pour prévenir ou résorber la buée sans alimentation électrique; la formulation, mise en œuvre par trempage, essorage ou racle, montre une forte robustesse mécanique (adhésion, anti-abrasion, anti-encrassement) et une compatibilité substrats rigides/flexibles, avec des essais en conditions réelles (verres correcteurs, pare-brise, serres) confirmant la constance d’optique et l’anti-buée prolongée; en reliant conception moléculaire (torsion, sulfonation) et ingénierie d’interface (brosses H, volume libre hiérarchisé, photothermie transparente), cette stratégie dépasse les limites des hydrophiles gonflants et des hydrophobes cassie-baxteriens, ouvrant la voie à des revêtements anti-buée pérennes, recyclables en service par la lumière ambiante et industrialisables à grande échelle.
Nature Syensqo met au point une technologie de recyclage chimique pour des polymères sulfonés circulaires
Le groupe Syensqo annonce une avancée majeure dans le domaine des polymères techniques avec le développement d’une technologie exclusive de recyclage chimique capable de dépolymériser efficacement les polymères sulfonés (PAES) afin d’en extraire des monomères purifiés réutilisables à l’infini. Cette innovation, issue de la gamme durable ECHO™, permet de transformer aussi bien les rebuts de production que les produits en fin de vie en matières premières de haute pureté, sans dégradation des performances. Les monomères régénérés peuvent être réincorporés dans les grades emblématiques de Syensqo — Udel® PSU, Radel® PPSU et Veradel® PESU — ou dans d’autres polymères thermoplastiques et formulations d’époxy, garantissant une véritable circularité moléculaire. En ciblant les marchés exigeants tels que la filtration, la santé ou l’aéronautique, l’entreprise renforce son leadership en matière de polymères durables à haute performance. Selon Floryan De Campo, vice-président Life Solutions, cette technologie marque une étape décisive vers la décarbonation et l’intégration accrue de matières recyclées dans les chaînes de valeur. En s’appuyant sur la coopération entre acteurs du tri, de la collecte et de la transformation, Syensqo trace la voie d’un modèle circulaire pour les polymères sulfonés, conciliant innovation industrielle et responsabilité environnementale.
Quand les polymères fondus racontent le cosmos
Le chercheur John Spevacek établit un parallèle fascinant entre la physique des polymères fondus et celle de l’univers, où la matière plastique devient une métaphore de l’espace-temps. Comme un polymère viscoélastique capable à la fois de couler et de stocker de l’énergie, l’espace-temps se révèle lui aussi fluide et élastique : sa viscosité se manifeste dans l’expansion issue du Big Bang, tandis que son élasticité se dévoile à travers les ondes gravitationnelles nées des collisions de trous noirs. Ces infimes vibrations traduisent la capacité du cosmos à se déformer puis se détendre, à la manière d’un plastique chauffé. Spevacek souligne ainsi que les mêmes outils mathématiques — tenseurs, équations de déformation, élasticité — servent autant à décrire un polymère en fusion qu’à comprendre la relativité d’Einstein, reliant de façon poétique la matière fondue aux profondeurs du temps et de l’espace.
Membranes sPEEK dopées aux liquides ioniques prototropes ouvrant la voie à des électrolytes polymères hautement conducteurs
Cette recherche explore une approche innovante pour concevoir des membranes électrolytes polymères capables de fonctionner au-delà de 100 °C dans les piles à combustible. En incorporant des liquides ioniques prototropes de différentes acidités dans une matrice de poly(éther-éther-cétone) sulfoné (sPEEK) réticulée, les chercheurs obtiennent des matériaux conjuguant stabilité thermique, conductivité protonique élevée et structure mécanique robuste. Le sPEEK, polymère fluorine-free à forte affinité hydrophile, assure une ancrage efficace des liquides ioniques tout en apportant ses propres sites donneurs de protons. Selon l’acidité du liquide ionique utilisé, le transport des protons s’opère par des mécanismes coopératifs impliquant H₃O⁺, améliorant la conduction même en conditions de faible humidité. Les observations morphologiques révèlent toutefois une microstructure hétérogène suggérant des pertes partielles d’électrolyte, un point clé à optimiser pour une meilleure durabilité. En combinant chimie des polymères et électrochimie des liquides ioniques, cette approche ouvre la voie à des électrolytes hybrides stables, efficaces et respectueux de l’environnement pour les PEMFC de nouvelle génération.
Nature Membrane réticulée à motifs 12-couronne-4 pour une capture sélective et régénérable du lithium en milieu aqueux
Un monomère diallylammonium portant un motif 12-couronne-4 a été synthétisé puis polymérisé par cyclopolymérisation radicalaire et réticulé, avec insertion contrôlée de SO₂, afin d’obtenir des résines insolubles dotées de cavités chélatantes accordées au Li⁺. Cette architecture conjugue reconnaissance hôte–invité des éthers couronne, sites ammonium répartis dans le réseau et segments sulfone qui rigidifient et polarisent la matrice, générant une texture mésoporeuse à grande surface favorable aux transferts. Les tests en solutions binaires confirment une forte sélectivité vis-à-vis de Na⁺ et K⁺ et un avantage sur Mg²⁺ à concentrations équivalentes, tandis que FTIR et XPS indiquent l’implication des liaisons éther dans la complexation. Régénérable par désorption acide, cette plateforme polymère offre une voie crédible pour la récupération durable du lithium et l’épuration d’effluents.
Nature Du marc de café et du plastique pour capter le CO₂ : une innovation brevetée à l’Université de Sharjah
Des chercheurs de l’Université de Sharjah ont mis au point et breveté une technologie de capture du dioxyde de carbone (CO₂) fondée sur la valorisation simultanée de deux déchets abondants : le marc de café usagé et le polyéthylène téréphtalate (PET). Le procédé repose sur une co-pyrolyse à 600 °C en présence d’hydroxyde de potassium (KOH), qui active la formation d’un charbon poreux hautement performant capable d’adsorber le CO₂ émis par les procédés industriels. Cette approche, à la fois sobre en énergie et circulaire, convertit des flux polluants en ressource fonctionnelle : le marc de café — dont huit millions de tonnes sont jetées chaque année — et le PET des emballages plastiques deviennent ainsi les précurseurs d’un charbon activé à grande surface spécifique, optimisé pour la capture de gaz et la purification de l’air ou de l’eau. Selon la chercheuse Haif Aljomard, cette technologie « transforme une tasse de café et une bouteille d’eau en outil contre le changement climatique ». Outre la séquestration du CO₂, le matériau obtenu pourrait être déployé dans des filtres industriels, systèmes d’épuration, traitements d’effluents ou procédés énergétiques, offrant une solution polyvalente et économique pour réduire les émissions et limiter la mise en décharge des déchets. Cette innovation illustre parfaitement la logique de l’économie circulaire appliquée à la chimie des matériaux, conciliant gestion des déchets, transition énergétique et ingénierie du carbone.
https://phys.org/news/2025-10-coffee-plastic-climate-solution.html
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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Les partenaires
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hutchinson
http://www.hutchinson.com/fr
cnrs
http://www.ispa.asso.fr
ICS
https://www-ics.u-strasbg.fr/
Logo-ChemSuD
http://www.ispa.asso.fr
lrccp
http://www.ispa.asso.fr
Waters_logo_stacked_K_web-NEW
http://www.waters.com
LPMC
http://www.ispa.asso.fr
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
arkema
http://www.coatex.com
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