Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
[GDR MultiPODE] CALL FOR COMMUNICATIONS : September 30 & October 1, 2025, Bordeaux – Two scientific days dedicated to bio-based materials & eco-design, organized by the GPR PPM and GDR MultiPODE
Le Grand Programme de Recherche bordelais « Matériaux post-pétrole » (GPR PPM) et le GDR Multipode « Multifunctional nanostructured POlymer systems by DEsign » s’associent pour proposer deux journées thématiques dédiées aux matériaux bio-sourcés & à l’éco-conception le mardi 30 septembre et le mercredi 1 octobre à Talence. lire plus…
Construire et déconstruire les plastiques avec la lumière
Des chercheurs de l’Université de technologie d’Eindhoven viennent de démontrer qu’il est possible de créer et de recycler un polymère uniquement avec de la lumière LED. Cette nouvelle génération de matériaux repose sur une conception « design for recycling » où les liaisons chimiques sont pensées pour être réversibles. Alors que le recyclage classique par fusion dégrade progressivement les chaînes macromoléculaires, la voie photchimique permet de les scinder sélectivement en leurs briques constitutives, puis de reformer le polymère avec une qualité identique. Le groupe de recherche mené par Fabian Eisenreich a ainsi obtenu en laboratoire les premiers polymères capables d’entrer dans une boucle fermée de recyclage chimique, déclenchée par irradiation lumineuse. Au-delà d’un simple prototype, cette approche ouvre des perspectives pour des applications spécialisées comme des adhésifs recyclables ou la fabrication additive par photopolymérisation. L’ambition est d’élargir ces procédés à des polymères plus conventionnels, jusqu’à imaginer un jour un recyclage activé directement par la lumière solaire.
https://phys.org/news/2025-08-plastics-chemists-rethink-plastic-recycling.html
L’imagerie moléculaire révèle des défauts cachés dans les polymères électroniques
Des chercheurs ont utilisé la microscopie à effet tunnel (STM) couplée à l’électrospray deposition (ESD) pour observer au niveau moléculaire des polymères conducteurs issus de la condensation aldolique, une méthode de synthèse réputée verte et sans métaux. Cette analyse a mis en évidence deux types de défauts : des défauts de couplage, liés à des liaisons mal orientées créant des “coudes” dans la chaîne, et des défauts de séquence, perturbant l’ordre des motifs répétés. Ces irrégularités freinent le transport des électrons et peuvent limiter les performances en électronique flexible ou en dispositifs thermoélectriques. En optimisant la purification des monomères ou en combinant la condensation aldolique avec d’autres voies de polymérisation, l’équipe a démontré qu’il était possible de réduire fortement ces défauts et d’obtenir des polymères aux propriétés électroniques plus fiables, ouvrant la voie à des plastiques conducteurs à la fois performants et durables.
https://phys.org/news/2025-08-molecular-imaging-uncovers-hidden-flaws.html
Quand l’IA découvre des molécules qui rendent les plastiques plus résistants
Des chercheurs du MIT et de l’université Duke ont utilisé l’intelligence artificielle pour accélérer la recherche de nouvelles molécules capables de renforcer les polymères. Ils se sont intéressés aux ferrocenes, des composés organométalliques où un atome de fer est pris en sandwich entre deux cycles carbonés. Intégrés comme mécanophores — ces maillons moléculaires qui réagissent à une contrainte mécanique — certains ferrocenes agissent comme des points de rupture contrôlés. Au lieu de propager une fissure dans tout le matériau, ces liaisons plus faibles obligent la fracture à contourner les zones solides, ce qui augmente la résistance globale. Grâce à un réseau de neurones entraîné sur plus de 5 000 ferrocenes issus de bases de données, l’équipe a identifié une centaine de candidats prometteurs. Testé dans une matrice de polyacrylate, l’un d’eux, le m-TMS-Fc, a permis d’obtenir un plastique quatre fois plus résistant à la déchirure qu’un polymère classique. Cette stratégie ouvre la voie à des plastiques durables, dont la longévité accrue pourrait réduire la production et donc les déchets, tout en élargissant le champ des mécanophores utilisables, y compris pour des applications comme les capteurs de contrainte ou les catalyseurs activables mécaniquement.
https://phys.org/news/2025-08-ai-uncovers-molecules-stronger-longer.html
Un plastique intelligent auto-cicatrisant plus résistant que l’acier
Des chercheurs de Texas A&M University ont révélé les propriétés exceptionnelles d’un copolyester thermodurcissable aromatique (ATSP) renforcé de fibres de carbone. Ce vitrimer associe la stabilité des thermodurcissables et la flexibilité des thermoplastiques, donnant naissance à un matériau plus léger que l’aluminium et plusieurs fois plus résistant que l’acier. Sa particularité réside dans sa capacité à se réparer et à retrouver sa forme après un dommage, grâce à des échanges de liaisons activés par la chaleur. Lors de tests de fatigue cyclique, le matériau endommagé a retrouvé presque toute sa résistance après deux cycles de chauffage à 280 °C. ATSP est également recyclable : il peut être broyé, remodelé et réutilisé sans perte significative de performances, ce qui en fait un candidat prometteur pour l’aéronautique, la défense et l’automobile. Cette avancée ouvre la voie à une nouvelle génération de composites polymères adaptatifs, capables d’évoluer et de durer dans des environnements extrêmes.
https://www.specialchem.com/plastics/news/new-self-healing-smart-plastic-that-is-stronger-than-steel
Un revêtement anti-adhésif inspiré des plumes pourrait remplacer le Teflon
Des chercheurs de l’Université de Toronto ont mis au point un nouveau matériau anti-adhésif qui rivalise avec l’efficacité du Teflon tout en réduisant drastiquement l’usage des PFAS, ces « polluants éternels » connus pour leur persistance et leurs effets toxiques. La stratégie repose sur une chimie innovante baptisée nanoscale fletching, qui reproduit à l’échelle moléculaire l’organisation de plumes de flèches. De courtes chaînes de polydiméthylsiloxane (PDMS, un polymère silicone biocompatible) sont fixées en « brosses » et terminées par la plus petite molécule PFAS possible (un seul carbone avec trois fluorines). Cette architecture confère une forte répulsion à l’eau et aux graisses, avec des performances comparables aux revêtements fluorés classiques mais sans bioaccumulation. Testée sur des textiles, la surface atteint un grade 6 sur l’échelle de l’American Association of Textile Chemists and Colorists, au niveau des standards industriels actuels. Cette avancée ouvre la voie à des alternatives plus sûres pour les revêtements anti-adhésifs de la cuisine, des emballages ou encore des textiles techniques, avec l’objectif ultime de se passer totalement des PFAS tout en dépassant les performances du Teflon.
https://scitechdaily.com/bye-bye-teflon-this-slick-new-material-could-change-cookware-forever/
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.
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Les partenaires
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Logo-ChemSuD
http://www.ispa.asso.fr
arkema
http://www.coatex.com
cnrs
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Waters_logo_stacked_K_web-NEW
http://www.waters.com
logo-ispa_coul_fond-fonce
http://www.ispa.asso.fr
LPMC
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ICS
https://www-ics.u-strasbg.fr/
lrccp
http://www.ispa.asso.fr
hutchinson
http://www.hutchinson.com/fr
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